scholarly journals Corrosion Inhibition of Carbon Steel Using Palm Oil Leaves Extract

2019 ◽  
Vol 19 (3) ◽  
pp. 747 ◽  
Author(s):  
Nor Insyirah Hairul Salleh ◽  
Arman Abdullah
Keyword(s):  
Carbon Steel ◽  
Corrosion Inhibition ◽  
Palm Oil ◽  
Inhibition Efficiency ◽  
Elaeis Guineensis ◽  
Steel Corrosion ◽  
Distilled Water ◽  
Effective Inhibitor ◽  
Inhibitor Concentration ◽  
Potentiodynamic Polarisation

Palm oil (Elaeis guineensis) leaves extract was investigated on its potential to inhibit carbon steel corrosion via weight loss and potentiodynamic polarisation methods. Corrosion inhibition of carbon steel using palm oil leaves extract was determined at various temperatures, salinities, and concentrations. The inhibition efficiency increased with the increasing of inhibitor concentration but decreased with the rise in temperature. The highest inhibitor efficiency was 83.70% with a corrosion rate of 0.44 mm/yr which was obtained at zero salinity (in distilled water) with 25% of inhibitor concentration at 303 K. The results obtained proved that the extract solution from palm oil leaves can be used as an effective inhibitor of carbon steel in seawater.

scholarly journals New Aromatic Azo-Schiff as Carbon Steel Corrosion Inhibitor in 1 M H2SO4

2018 ◽  
Vol 34 (5) ◽  
pp. 2471-2476 ◽  
Author(s):  
Hamida Edan Salman ◽  
Asim A. Balakit ◽  
Ali Ahmed Abdulridha
Keyword(s):  
Weight Loss ◽  
Carbon Steel ◽  
Corrosion Inhibitor ◽  
Corrosion Inhibition ◽  
Potentiodynamic Polarization ◽  
Inhibition Efficiency ◽  
Steel Corrosion ◽  
Spectroscopic Techniques ◽  
Different Temperatures ◽  
Corrosion Inhibition Efficiency

A new aromatic Schiff base with azo linkage (AS) has been synthesized and characterized by FT-IR, 1H NMR and 13C NMR spectroscopic techniques. The new compound (AS) has been evaluated as carbon steel corrosion inhibitor at different concentrations (0.005, 0.01, 0.02, 0.04 and 0.08 mM) and different temperatures (303 – 333 K). The corrosion inhibition efficiency was studied by potentiodynamic polarization and weight loss measurements. The effects of concentration and temperature on the inhibition efficiency were studied by potentiodynamic polarization studies, the results showed that increasing concentration of AS increases the inhibition efficiency while increasing the temperature decreases it, the highest corrosion inhibition efficiency, 93.9% was recorded with 0.08 mM of AS at 313 K in 1 M H2SO4. Weight loss measurements showed that the inhibition efficiency reached 97.1% in the presence of AS (0.08 mM) at 313 K. The adsorption process was found to obey Langmuir isotherm, and the adsorption thermodynamic parameters were studied. Scanning electron microscope (SEM) was used to confirm the results.

scholarly journals Corrosion inhibition and statistical data of low carbon steel in HCl media by admixed organic compounds

2021 ◽  
Vol 2070 (1) ◽  
pp. 012149
Author(s):  
Roland Tolulope Loto ◽  
Cleophas Akintoye Loto ◽  
Richard Leramo ◽  
Babatunde Oyebade
Keyword(s):  
Carbon Steel ◽  
Organic Compounds ◽  
Corrosion Inhibition ◽  
Exposure Time ◽  
Inhibition Efficiency ◽  
Low Carbon Steel ◽  
Calculated Data ◽  
Carbon Steels ◽  
Low Carbon ◽  
Inhibitor Concentration

Abstract Corrosion inhibition of carbon steels with organic compounds exhibiting effective corrosion inhibition is an on-going research. The corrosion inhibition of low carbon steel in 1M HCl solution by the combined admixture of vanillin and benzonitrile (VBN), and salvia officinalis with lavendulan officinalis (SLV) was studied by weight loss method. Results obtained show that VBN and SLV performed effectively with maximum inhibition efficiency 91.03% at 1.5% VBN concentration and 97.89% at 5% SLV concentration. The inhibition efficiency of VBN increased with concentration but decreased with exposure time compared to the values obtained for SLV which showed non-dependence on concentration and exposure time after 1% SLV concentration. Correlation plots of inhibition efficiency versus inhibitor concentration show VBN to be more concentration dependent in performance. Calculated data for standard deviation shows the degree of variation from mean values for both compounds is significant at low inhibitor concentration due to time dependence action. Statistical analysis through ANOVA shows inhibitor concentration overwhelmingly influences the inhibition performance of the despite even though exposure time is statistically relevant to minimal degree.

scholarly journals LINSEED OIL AS A NOVEL ECO-FRIENDLY CORROSION INHIBITOR OF CARBON STEEL IN 1 M HCl

2019 ◽  
Vol 26 (02) ◽  
pp. 1850148
Author(s):  
N. GHARDA ◽  
M. GALAI ◽  
L. SAQALLI ◽  
N. HABBADI ◽  
R. GHAILANE ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Carbon Steel ◽  
Corrosion Inhibitor ◽  
Inhibition Efficiency ◽  
Linseed Oil ◽  
Steel Corrosion ◽  
Effective Inhibitor ◽  
Chromatography Method ◽  
Green Corrosion Inhibitor ◽  
Hcl Solution

The extraction of linseed oil (LO) was realized by refluxing method. The extracted oil was identified by gas chromatography method coupled with mass spectrometry (GC-MS). In order to contribute to the protection of the environment, one contemplates to try on LO as a green corrosion inhibitor. The corrosion inhibition of LO was studied by weight loss and electrochemical methods. The obtained results showed that the LO is an effective inhibitor of the carbon steel corrosion in 1[Formula: see text]M HCl solution, the inhibition efficiency increased with concentration to reach 88% at 200[Formula: see text]ppm. Furthermore, the adsorption of the inhibitor on the surface of metal in 1[Formula: see text]M HCl solution was found to obey Langmuir’s adsorption isotherm. The influences of temperature were also studied in the range from 298[Formula: see text]K to 328[Formula: see text]K. The kinetic and thermodynamic data of activation dissolution process were determined and discussed.

scholarly journals Experimental and surface morphological studies of corrosion inhibition on carbon steel in HCl solution using some new hydrazide derivatives

RSC Advances ◽  
2021 ◽  
Vol 11 (22) ◽  
pp. 13497-13512
Author(s):  
Abd El-Aziz S. Fouda ◽  
Samir A. Abd El-Maksoud ◽  
Elsherbiny H. El-Sayed ◽  
Hazem A. Elbaz ◽  
Ashraf S. Abousalem
Keyword(s):  
Carbon Steel ◽  
Hydrochloric Acid ◽  
Corrosion Inhibition ◽  
Inhibition Efficiency ◽  
Steel Corrosion ◽  
Inhibitory Effect ◽  
Inhibition Mechanism ◽  
Morphological Studies ◽  
Hcl Solution

The inhibitory effect of three newly synthesized hydrazide derivatives on carbon steel corrosion in hydrochloric acid showed better inhibition efficiency (97.5%) and their inhibition mechanism is presented.

Comparative Study of Palm Oil and Corn Oil as Corrosion Inhibitor for Low Carbon Steel

2016 ◽  
Vol 706 ◽  
pp. 9-15 ◽  
Author(s):  
Nadhirah A. Khalim ◽  
Esah Hamzah
Keyword(s):  
Carbon Steel ◽  
Corrosion Inhibitor ◽  
Palm Oil ◽  
Inhibition Efficiency ◽  
Corn Oil ◽  
Low Carbon Steel ◽  
Immersion Test ◽  
Distilled Water ◽  
Low Carbon ◽  
Green Inhibitor

Corrosion can lead to failures in plant infrastructure and machines which are usually costly to repair, contaminating the product and causes environmental damage. Green inhibitor is a corrosion inhibitor which normally comes from the extract of plants and can inhibit corrosion by using chemisorption and/or physisorption mechanism on the metal surface or reacting with metal ions and forming a barrier-type precipitate on its surface. This paper discusses the corrosion inhibition of low carbon steel by addition of palm oil and corn oil as green inhibitors. We also compared the effect of these inhibitors in water and salt water environment. The corrosion behaviour of the low carbon steel was determined by immersion and electrochemical tests. The immersion test was carried out by immersing the samples in distilled water and 3.5% NaCl solution with and without the inhibitors for 1,2,4,6 and 8 weeks. The concentration of the inhibitors used was 100 g/L for both corn oil and palm oil. Scanning Electron Microscopy, Energy Dispersive Spectroscopy and X-Ray diffractometer were used to analyse the results. Immersion test results show that there is a slight weight gain for low carbon steel immersed in the presence of inhibitors suggesting that there is a thin protective layer formed which act as a barrier towards corrosion. Corn oil inhibitor in distilled water shows the highest inhibition efficiency. Its inhibition efficiency is 93.9%, which is slightly higher than palm oil (91.5%) in similar environment.

Inhibition of pipeline steel corrosion in acidic environment using sulphadoxine and pyrimethamine

2019 ◽  
Author(s):  
Chem Int
Keyword(s):  
Inhibition Efficiency ◽  
Pipeline Steel ◽  
Electrochemical Techniques ◽  
Steel Corrosion ◽  
Acidic Environment ◽  
Inhibitor Concentration ◽  
Adsorption Data ◽  
Corrosion Inhibition Efficiency ◽  
Inhibitive Action ◽  
Sulphadoxine Pyrimethamine

The anti-corrosive properties of sulphadoxine + pyrimethamine (S+P) on the corrosion of pipeline steel in acidic environment were investigated using electrochemical techniques. The results obtained showed an excellent inhibition efficiency which increased with increase in inhibitor concentration. The corrosion inhibition efficiency increased up to 99.04 % at 0.01M S+P and decreased with rise in temperature down to 85.93 % at 333 K and 0.01 M S+P, suggesting a physiosorptive mechanism of adsorption. Also the adsorption data was fitted into Langmuir and Temkin adsorption isotherms, while the inhibitive action was shown to proceed by mixed inhibition mode.

Investigation of corrosion inhibition of C38 steel in 5.5 M H3PO4 solution using Ziziphus lotus oil extract: an application model

2019 ◽  
Vol 66 (1) ◽  
pp. 121-126 ◽  
Author(s):  
Walid Belmaghraoui ◽  
Aimad Mazkour ◽  
Hicham Harhar ◽  
Mourad Harir ◽  
Souad El Hajjaji
Keyword(s):  
Carbon Steel ◽  
Corrosion Inhibition ◽  
Inhibition Efficiency ◽  
Electrochemical Impedance ◽  
Electric Circuit ◽  
Oil Composition ◽  
Content Type ◽  
Tafel Polarization ◽  
Chemical Content ◽  
Oil Extract

Purpose This study aims to investigate the corrosion inhibition effect of extracted oil from Ziziphus lotus fruit on corrosion of C38 carbon steel in 5.5 M H3PO4 solution using potentiodynamic polarization and impedance techniques. Design/methodology/approach Oil composition was determined using gas chromatography, and the results showed that oleic and palmitic acids present approximately 84.0 per cent of its total chemical content. Electrochemical impedance spectroscopy (EIS) data were analyzed by adapting it to a well-developed electric circuit model. The inhibition efficiency of Z. lotus oil was calculated and compared using Tafel polarization and EIS. Findings Accordingly, the oil extract was found to act as an anodic type inhibitor. Furthermore, inhibition efficiency of Z. lotus oil extract increase with oil concentrations and achieve approximately 70.5 per cent at 3 g/L solution of Z. lotus oil. Originality/value The results obtained from different tested methods were in line, and the oil was able to reduce significantly the kinetics of the corrosion process of C38 carbon steel.

scholarly journals Electrochemical and Surface Morphological Studies of Carbon Steel Corrosion by a Novel Polynuclear Schiff Base in HCl Solution

2013 ◽  
Vol 2013 ◽  
pp. 1-8 ◽  
Author(s):  
K. S. Shaju ◽  
K. Joby Thomas ◽  
Vinod P. Raphael ◽  
Aby Paul
Keyword(s):  
Weight Loss ◽  
Schiff Base ◽  
Carbon Steel ◽  
Hydrochloric Acid ◽  
Adsorption Isotherm ◽  
Acid Solution ◽  
Corrosion Inhibition ◽  
Hydrochloric Acid Solution ◽  
Inhibition Efficiency ◽  
Morphological Studies

The corrosion inhibition efficiency of a potential polynuclear Schiff base, (s)-2-(anthracene-9 (10H)-ylidene amino)-5-guanidinopentanoic acid (A9Y5GPA), on carbon steel (CS) in 1 M hydrochloric acid solution has been investigated using weight loss measurements, electrochemical impedance spectroscopy (EIS), and potentiodynamic polarization studies. The corrosion inhibition efficiencies of parent amine [(s)-2-amino-5-guanidinopentanoic acid] and parent ketone (anthracene-9 (10H)-one) on carbon steel in 1.0 M hydrochloric acid solution have also been investigated using weight loss studies. The electrochemical and weight loss data established that the inhibition efficiency on CS increases with the increase in the concentration of inhibitor, A9Y5GPA. The adsorption of A9Y5GPA obeys the Langmuir adsorption isotherm. Thermodynamic parameters (Kads, ΔGads0) were calculated using the adsorption isotherm. Activation parameters of the corrosion process (Ea, ΔH* and ΔS*) were also calculated from the corrosion rates obtained from temperature studies. Tafel plot analysis revealed that A9Y5GPA acts as a mixed-type inhibitor. A probable inhibition mechanism was also proposed. Surface morphology of the carbon steel specimens in the presence and absence of the inhibitor was evaluated by SEM analysis.

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