scholarly journals Mechanical and Thermal Properties of Geopolymers from Mixtures of Coal Ash and Rice Hull Ash using Water Glass Solution as Activator

2016 ◽  
Vol 15 (2) ◽  
pp. 51 ◽  
Author(s):  
Martin Ernesto L. Kalaw ◽  
Alvin B Culaba ◽  
Hoc Thang Nguyen ◽  
Khoi Nguyen ◽  
Hirofumi Hinode ◽  
...  
Keyword(s):  
Thermal Conductivity ◽  
Compressive Strength ◽  
High Temperature ◽  
Mass Loss ◽  
Water Absorption ◽  
Residential Buildings ◽  
Coal Ash ◽  
Rice Hull ◽  
Rice Hull Ash ◽  
Temperature Exposure

Geopolymers, from industrial wastes such as blast furnace slag, red mud, and coal ash, among others, have emerged as technically viable, economically competitive, and environmentally attractive supplements and even alternatives to ordinary Portland cement (OPC). Furthermore, while the most impact shall be achieved with large-scale use in the general building and structural sector, as replacement or supplement to OPC, the properties of these geopolymers may be optimized for special niche applications. One of these applications is for light weight, low thermal conductivity, heat resistant, and moderate strength cement binder for low rise residential buildings. In this study, compressive strength, heat resistance, volumetric weight, mass loss, water absorption and thermal conductivity of geopolymers formed from mixtures of coal bottom ash and rice hull ash (CBA-RHA) and coal fly ash and rice hull ash (CFA-RHA) with sodium silicate solution (modulus 2.5) as activator were evaluated. Using mixture design and the JMP statistical software, the CBA-RHA combination at a mass ratio of 46% CBA, 32% RHA with 22% WGS gave properties at maximum desirability of 17.6 MPa compressive strength, 1640 kg/m3 volumetric weight, 273 kg/m3 water absorption, 28 MPa compressive strength after high temperature exposure (1000oC for 2 hours) with 4.4% mass loss, and 0.578 W/m-K thermal conductivity. On a performance basis, even as the geopolymers are formed as paste, these properties fall within the standards for lightweight OPC based-concrete with strength requirements for residential buildings. The low thermal conductivity and higher strength after high temperature exposure vis-à-vis OPC are additional advantages for consideration.

scholarly journals GEOPOLYMERS SYNTHESIZED FROM PHILIPPINE COAL ASH AS SUSTAINABLE ALTERNATIVE LOW HEAT TRANSMISSION AND FIRE-RESISTANT MATERIAL FOR BUILDINGS

2021 ◽  
Vol 11 (3) ◽  
pp. 45-56
Author(s):  
Martin Ernesto Kalaw ◽  
Joshua Martin Kalaw ◽  
Michael Angelo Promentilla
Keyword(s):  
Thermal Conductivity ◽  
Compressive Strength ◽  
Fire Resistance ◽  
Coal Fly Ash ◽  
Rice Hull ◽  
Sodium Perborate ◽  
Rice Hull Ash ◽  
Type Specimens ◽  
Foaming Agents ◽  
Mix Proportion

Geopolymers are formed from alumina and silica rich materials by alkali dissolution and subsequent polycondensation into a polymeric network. Geopolymerization technology presents a great potential for positive environmental impact since many alumina- and silica- rich industrial waste materials, such as coal ashes, blast furnace slags, mine tailings, etc., can be used as its precursor materials in a process that requires less energy and gives up less emissions vis-à-vis the current conventional OPC (ordinary Portland cement) technology. In this study, geopolymer samples were prepared using an 85% coal fly ash (CFA) - 10% coal bottom ash (CBA) - 5% rice hull ash (RHA) wt/wt mix proportion and activated using an alkali solution of NaOH-Na2SiO3 at an 80%-20% wt/wt solid-to-liquid ratio. With this mix proportion, two types of specimens were used, a slab type with 50 mm thickness, and a cube type, 50 mm x 50 mm x 50 mm. The slab type specimens were used for evaluating fire resistance using ASTM E119, Standard Test Methods for Fire Tests of Building Construction and Materials, and the cube type specimens were used to study the effect of foaming agents on the strength and thermal conductivity of the geopolymers formed. Two types of foaming agents, hydrogen peroxide and sodium perborate, at an amount of 0.1% to 0.4% of dry mass mixture, were used. Results from the foamed geopolymers gave compressive strength values ranging from 0.37 to 0.71 MPa and densities of 1430-1560 kg/m3 at 0.3% to 0.4% peroxide added. Values of thermal conductivity of the foamed geopolymers were within 0.033-0.037 W/m-K for all foamed geopolymer samples tested which is a significant reduction compared to the thermal conductivity of the unfoamed geopolymer sample at 0.48 W/m-K. The fire resistance tests show that the unfoamed geopolymer samples perform better than OPC concrete. However, the foamed geopolymers have very low strength compared to the unfoamed sample compressive strength of 18.1 MPa and, thus, are suitable for non-load bearing, insulation applications.

Incorporation of Iraqi Rocks in the Production of Eco-Friendly Cement Mortar

2020 ◽  
Vol 38 (10A) ◽  
pp. 1522-1530
Author(s):  
Rawnaq S. Mahdi ◽  
Aseel B. AL-Zubidi ◽  
Hassan N. Hashim
Keyword(s):  
Mechanical Properties ◽  
Thermal Conductivity ◽  
Compressive Strength ◽  
Water Absorption ◽  
Structural Properties ◽  
Mechanical Milling ◽  
Cement Mortar ◽  
Cement Mortars

This work reports on the incorporation of Flint and Kaolin rocks powders in the cement mortar in an attempt to improve its mechanical properties and produce an eco-friendly mortar. Flint and Kaolin powders are prepared by dry mechanical milling. The two powders are added separately to the mortars substituting cement partially. The two powders are found to improve the mechanical properties of the mortars. Hardness and compressive strength are found to increase with the increase of powders constituents in the cement mortars. In addition, the two powders affect water absorption and thermal conductivity of the mortar specimens which are desirable for construction applications. Kaolin is found to have a greater effect on the mechanical properties, water absorption, and thermal conductivity of the mortars than Flint. This behavior is discussed and analyzed based on the compositional and structural properties of the rocks powders.

scholarly journals Biodegradable, Flame-Retardant, and Bio-Based Rigid Polyurethane/Polyisocyanurate Foams for Thermal Insulation Application

Polymers ◽  
2019 ◽  
Vol 11 (11) ◽  
pp. 1816 ◽  
Author(s):  
Marcin Borowicz ◽  
Joanna Paciorek-Sadowska ◽  
Jacek Lubczak ◽  
Bogusław Czupryński
Keyword(s):  
Thermal Conductivity ◽  
Compressive Strength ◽  
Water Absorption ◽  
Flame Retardant ◽  
Functional Properties ◽  
Apparent Density ◽  
Seed Oil ◽  
Mustard Seed ◽  
Hydroxyl Groups ◽  
Processing Times

This article raised the issue of studies on the use of new bio-polyol based on white mustard seed oil and 2,2’-thiodiethanol (3-thiapentane-1,5-diol) for the synthesis of rigid polyurethane/polyisocyanurate (RPU/PIR) foams. For this purpose, new formulations of polyurethane materials were prepared. Formulations contained bio-polyol content from 0 to 0.4 chemical equivalents of hydroxyl groups. An industrial flame retardant, tri(2-chloro-1-methylethyl) phosphate (Antiblaze TCMP), was added to half of the formulations. Basic foaming process parameters and functional properties, such as apparent density, compressive strength, brittleness, absorbability and water absorption, aging resistance, thermal conductivity coefficient λ, structure of materials, and flammability were examined. The susceptibility of the foams to biodegradation in soil was also examined. The increase in the bio-polyol content caused a slight increase in processing times. Also, it was noted that the use of bio-polyol had a positive effect on the functional properties of obtained RPU/PIR foams. Foams modified by bio-polyol based on mustard seed oil showed lower apparent density, brittleness, compressive strength, and absorbability and water absorption, as well as thermal conductivity, compared to the reference (unmodified) foams. Furthermore, the obtained materials were more resistant to aging and more susceptible to biodegradation.

scholarly journals Mechanical Properties of Concrete with Various Water-Cement Ratio After High Temperature Exposure

2019 ◽  
Vol 2 (2) ◽  
pp. 126-136
Author(s):  
M.I Retno Susilorini ◽  
Budi Eko Afrianto ◽  
Ary Suryo Wibowo
Keyword(s):  
Mechanical Properties ◽  
Compressive Strength ◽  
High Temperature ◽  
Modulus Of Elasticity ◽  
Building Materials ◽  
Heating Process ◽  
High Temperature Exposure ◽  
Cement Ratio ◽  
Water Cement Ratio ◽  
Temperature Exposure

Concrete building safety of fire is better than other building materials such as wood, plastic, and steel,because it is incombustible and emitting no toxic fumes during high temperature exposure. However,the deterioration of concrete because of high temperature exposure will reduce the concrete strength.Mechanical properties such as compressive strength and modulus of elasticity are absolutely corruptedduring and after the heating process. This paper aims to investigate mechanical properties of concrete(especially compressive strength and modulus of elasticity) with various water-cement ratio afterconcrete suffered by high temperature exposure of 500oC.This research conducted experimental method and analytical method. The experimental methodproduced concrete specimens with specifications: (1) specimen’s dimension is 150 mm x 300 mmconcrete cylinder; (2) compressive strength design, f’c = 22.5 MPa; (3) water-cement ratio variation =0.4, 0.5, and 0.6. All specimens are cured in water for 28 days. Some specimens were heated for 1hour with high temperature of 500oC in huge furnace, and the others that become specimen-controlwere unheated. All specimens, heated and unheated, were evaluated by compressive test.Experimental data was analyzed to get compressive strength and modulus of elasticity values. Theanalytical method aims to calculate modulus of elasticity of concrete from some codes and to verifythe experimental results. The modulus elasticity of concrete is calculated by 3 expressions: (1) SNI03-2847-1992 (which is the same as ACI 318-99 section 8.5.1), (2) ACI 318-95 section 8.5.1, and (3)CEB-FIP Model Code 1990 Section 2.1.4.2.The experimental and analytical results found that: (1) The unheated specimens with water-cementratio of 0.4 have the greatest value of compressive strength, while the unheated specimens with watercementratio of 0.5 gets the greatest value of modulus of elasticity. The greatest value of compressivestrength of heated specimens provided by specimens with water-cement ratio of 0.5, while the heatedspecimens with water-cement ratio of 0.4 gets the greatest value of modulus of elasticity, (2) Allheated specimens lose their strength at high temperature of 500oC, (3) The analytical result shows thatmodulus of elasticity calculated by expression III has greater values compares to expression I and II,but there is only little difference value among those expressions, and (4)The variation of water-cementratio of 0.5 becomes the optimum value.

Preparation and Characterization of CCCW/Foamed Concrete Composite

2011 ◽  
Vol 261-263 ◽  
pp. 13-18
Author(s):  
Ke Qing Li ◽  
De Ping Chen ◽  
Shi Li Zhang ◽  
Bao Shun Liu
Keyword(s):  
Thermal Conductivity ◽  
Compressive Strength ◽  
Water Absorption ◽  
Heat Insulation ◽  
High Humidity ◽  
Underground Engineering ◽  
New Approach ◽  
Foamed Concrete ◽  
Insulation Performance

Aimed at improving the waterproofing property of foamed concrete, a heat-insulating and waterproofing composite applied in underground engineering was prepared by using cementitious capillary crystalline waterproofing material and foamed concrete. The properties of foamed concrete and composite such as compressive strength, water absorption and thermal conductivity were tested and contrasted, and the compounding reaction mechanism was analyzed. The results show that, compared with foamed concrete, the water absorption of composite has been significantly reduced while the heat-insulating property of foamed concrete is maintained and the overall waterproofing and heat-insulation performance has been significantly improved. A new approach solving underground heat-harm such as high temperature and high humidity is provided.

Mechanical Properties and Thermal Conductivity of Lightweight Clay Bricks Fabricated with a Powdered Marble Dust Additive

2018 ◽  
Vol 777 ◽  
pp. 465-470
Author(s):  
Sutas Janbuala ◽  
Mana Eambua ◽  
Arpapan Satayavibul ◽  
Watcharakhon Nethan
Keyword(s):  
Mechanical Properties ◽  
Thermal Conductivity ◽  
Compressive Strength ◽  
Water Absorption ◽  
Bulk Density ◽  
Firing Temperature ◽  
Apparent Porosity ◽  
Clay Brick ◽  
Clay Bricks ◽  
Marble Dust

The objective of this study was to recycle powdered marble dust to improve mechanical properties and thermal conductivity of lightweight clay bricks. Varying amounts of powdered marble dust (10, 20, 30, and 40 vol.%) were added to a lightweight clay brick at the firing temperatures of 900, 1000, and 1100 °C. When higher quantities of powdered marble dust were added, the values of porosity and water absorption increased while those of thermal conductivity and bulk density decreased. The decrease in apparent porosity and water absorption were also affected by the increase in firing temperature. The most desirable properties of the clay bricks were obtained for the powdered marble dust content of 40 vol.% and firing temperature 900 °C: bulk density of 1.20 g/cm3, compressive strength 9.2 MPa, thermal conductivity 0.32 W/m.K, and water absorption 22.5%.

Effect of Admixtures on the Thermo-Physical Properties of Non Autoclaved Light Weight Block Using Marble Dust

2019 ◽  
Vol 801 ◽  
pp. 365-370
Author(s):  
Vivek Sood ◽  
S.K. Negi ◽  
B.M. Suman
Keyword(s):  
Thermal Conductivity ◽  
Compressive Strength ◽  
Physical Properties ◽  
Water Absorption ◽  
Light Weight ◽  
Inert Filler ◽  
Standard Code ◽  
Super Plasticizer ◽  
Marble Dust ◽  
Thermo Physical Properties

In the present study, use of marble dust an inert filler produced by the marble cutting industries in the development of light weight block (LWB) of density 800 kg/m3 by non-auto clave method has been studied. Various mechanical and thermo-physical properties have been evaluated. It has been possible to replace cement by up to 20% when no additive is used. With the use of activator and super plasticizer at 50% replacement of cement by marble dust, compressive strength and water absorption are well within the Indian standard code 2185. With the use of accelerator and super plasticizer it is possible to reduce the de moulding time from 48 hrs to 6 hrs. Thermal conductivity of blocks varies from 1.16 to 2.30 [W/mK]. The variation in thermal conductivity depends upon its density which varies from 800 kg/m3 to 2400 kg/m3.

scholarly journals Exposing Sustainable Mortars with Nanosilica, Zinc Stearate, and Ethyl Silicate Coating to Sulfuric Acid Attack

2018 ◽  
Vol 10 (10) ◽  
pp. 3769 ◽  
Author(s):  
Victoria García-Vera ◽  
Antonio Tenza-Abril ◽  
Marcos Lanzón ◽  
José Saval
Keyword(s):  
Compressive Strength ◽  
Sulfuric Acid ◽  
Mass Loss ◽  
Water Absorption ◽  
Zinc Stearate ◽  
Acid Exposure ◽  
Ethyl Silicate ◽  
Acid Attack ◽  
Water Absorption Coefficient ◽  
Silicate Coating

Obtaining durable materials that lengthen the service life of constructions and thereby contribute to sustainability requires research into products that improve the durability of cementitious materials under aggressive conditions. This paper studies the effects of sulfuric acid exposure on four mortar types (control mortar, mortar with nanosilica, mortar with zinc stearate, and mortar with an ethyl silicate coating), and evaluates which of them have better performance against the acid attack. After 28 days of curing, the samples were exposed to a sulfuric acid attack by immersing them in a 3% w/w of H2SO4 solution. Physical changes (mass loss, ultrasonic pulse velocity, open porosity, and water absorption), and mechanical changes (compressive strength) were determined after the sulfuric acid exposure. A scanning electron microscope (SEM) was used to characterize the morphology of the surface mortars after the exposure. The control mortar had the highest compressive strength after the acid attack, although of the four types, the zinc stearate mortar showed the lowest percentage of strength loss. The zinc stearate mortar had the lowest mass loss after the acid exposure; moreover, it had the lowest capillary water absorption coefficient (demonstrating its hydrophobic effect) both in a non-aggressive environment and acid attack.

Investigation on Thermal Stability of Geopolymer Based Zeolite in Fire Case Study

2020 ◽  
Vol 1009 ◽  
pp. 31-36
Author(s):  
Kanokwan Kanyalert ◽  
Prinya Chindaprasirt ◽  
Duangkanok Tanangteerapong
Keyword(s):  
Weight Loss ◽  
Compressive Strength ◽  
High Temperature ◽  
Fly Ash ◽  
Alkali Activation ◽  
Different Types ◽  
Temperature Exposure ◽  
In Fire ◽  
Thermal Stability Of

This work aims to reveal the effects of zeolite on properties of fly ash based geopolymer under high temperature at 300 °C, 600 °C and 900 °C. The specimens were prepared by alkali activation of fly ash, which was partially replaced by two different types of zeolite at 10%, 20% and 30% by weight. The specimens were analyzed for the maximum compressive strength, weight loss percentage, XRD and SEM. The results highlighted that the percentage of weight loss increased with the ratio of zeolite replacement. The compressive strength of geopolymer with synthetic zeolite and natural zeolite at 7, 28, 60 days were similar. The high-temperature exposure resulted in the reduction in compressive strength in all proportions. At the same temperature, compressive strength of all specimens were not significantly different.

Freeze-Thaw Resistance of Concrete Modified by Rice Hull Ash and Gangue

2014 ◽  
Vol 488-489 ◽  
pp. 700-703
Author(s):  
Jing Yun Han ◽  
Liang Liang Zhang ◽  
Hai Yang Zhang
Keyword(s):  
Compressive Strength ◽  
Research Work ◽  
Environmental Problems ◽  
Rice Hull ◽  
Rice Hull Ash ◽  
Freeze Thaw ◽  
Concrete Production ◽  
The Cost ◽  
Control Samples

Currently, most rice hull is piled up or burned naturally, resulting in many environmental problems. It is a potentially good way to incinerate specially rice hull into the ash that is used as concrete admixture. The research work was done and results indicate that the compressive strength of the concrete with addition of 1%, 2% and 3% of rice hull ash increased by 6.8%16.7% and 15.1% respectively compared with control samples. And the compound addition of rice hull ash and gangue not only improved the mechanical and anti-freeze-thaw properties of concrete, but also decreased the cost of concrete production.

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