scholarly journals PORE STRUCTURE MODEL OF CEMENT HYDRATES BASED ON HYDRATION AND CHANGE OF PARTICLE SIZE OF CONSTITUENT PHASE

2010 ◽  
Vol 66 (1) ◽  
pp. 38-52
Author(s):  
Yusuke FUJIKURA ◽  
Hideki OSHITA
Keyword(s):  
Particle Size ◽  
Pore Structure ◽  
Structure Model ◽  
Constituent Phase

scholarly journals Physicochemical factors affecting the wettability of copper mine blasting dust

2021 ◽  
Author(s):  
Longzhe Jin ◽  
Jianguo Liu ◽  
Jingzhong Guo ◽  
Jiaying Wang ◽  
Tianyang Wang
Keyword(s):  
Particle Size ◽  
Physicochemical Properties ◽  
Pore Structure ◽  
Total Pore Volume ◽  
Open Pit ◽  
X Rays ◽  
Factors Affecting ◽  
Copper Mine ◽  
Mineral Components ◽  
Hydrophobic Component

AbstractTo investigate the factors affecting the wettability of copper mine blasting dust, the primary blasting dust was collected from an open-pit copper mine and separated into hydrophilic blasting dust (HLBD) and hydrophobic blasting dust (HBBD) using water flotation method. The physicochemical properties of HLBD and HBBD were measured and compared with each other. The properties included particle size distributions (PSDs), micromorphologies, pore structures, mineral components and surface organic carbon functional groups. The results show that particle size and pore structure of the blasting dust are the main factors affecting its wettability. Specifically, particle size of HBBD is smaller than that of HLBD, and their respiratory dust (less than 10 µm) accounts for 61.74 vol% and 53.00 vol%, respectively. The pore structure of HBBD is more developed, and the total pore volume of HBBD is 1.66 times larger than that of HLBD. The identical mineral compositions were detected in HLBD and HBBD by X-rays diffraction (XRD); however, the surface organic hydrophobic component of HBBD is slightly larger than that of HLBD, this may be the reason for the poor wettability of HBBD. This study is significant to understand the effects of physicochemical properties of copper mine blasting dust on its wettability.

Terahertz time-domain spectroscopy of a simulated pore structure to probe particle size and porosity of porous rock

2014 ◽  
Vol 23 (12) ◽  
pp. 127802 ◽  
Author(s):  
Chen Dong ◽  
Ri-Ma Bao ◽  
Kun Zhao ◽  
Chang-Hong Xu ◽  
Wu-Jun Jin ◽  
...  
Keyword(s):  
Particle Size ◽  
Pore Structure ◽  
Time Domain ◽  
Probe Particle ◽  
Terahertz Time Domain Spectroscopy ◽  
Porous Rock ◽  
Time Domain Spectroscopy

Pore Structure Modeling of Flow in Gas Diffusion Layers of Proton Exchange Membrane Fuel Cells

2010 ◽  
Author(s):  
Zhongying Shi ◽  
Xia Wang
Keyword(s):  
Fuel Cell ◽  
Pore Structure ◽  
Proton Exchange Membrane ◽  
Cell Model ◽  
Transport Phenomena ◽  
Pem Fuel Cell ◽  
Gas Diffusion ◽  
Proton Exchange ◽  
Structure Model ◽  
Exchange Membrane

The gas diffusion layer (GDL) in a proton exchange membrane (PEM) fuel cell has a porous structure with anisotropic and non-homogenous properties. The objective of this research is to develop a PEM fuel cell model where transport phenomena in the GDL are simulated based on GDL’s pore structure. The GDL pore structure was obtained by using a scanning electron microscope (SEM). GDL’s cross-section view instead of surface view was scanned under the SEM. The SEM image was then processed using an image processing tool to obtain a two dimensional computational domain. This pore structure model was then coupled with an electrochemical model to predict the overall fuel cell performance. The transport phenomena in the GDL were simulated by solving the Navier-Stokes equation directly in the GDL pore structure. By comparing with the testing data, the fuel cell model predicted a reasonable fuel cell polarization curve. The pore structure model was further used to calculate the GDL permeability. The numerically predicted permeability was close to the value published in the literature. A future application of the current pore structure model is to predict GDL thermal and electric related properties.

FRACTAL PORE STRUCTURE MODEL AND MULTILAYER FRACTAL ADSORPTION IN SHALE

Fractals ◽  
2014 ◽  
Vol 22 (03) ◽  
pp. 1440010 ◽  
Author(s):  
LIEHUI ZHANG ◽  
JIANCHAO LI ◽  
HONGMING TANG ◽  
JINGJING GUO
Keyword(s):  
Fractal Dimension ◽  
Pore Structure ◽  
Saturated Vapor ◽  
Adsorption Property ◽  
Fractal Theory ◽  
Complex Structure ◽  
Structure Model ◽  
Adsorption Model ◽  
Adsorption Volume ◽  
Isothermal Adsorption

The complex structure and surface property of porous media have significant impact on its accumulation and adsorption capacity. Based on the fractal theory, this paper presents a fractal pore structure model for shales. The effect of different pore structures on fractal dimension is discussed, and the influence of fractal dimension and pore size distribution on porosity is also analyzed. It is shown that the fractal dimension D decreases with the increase of structure parameter q/m for a certain pore diameter ratio, and porosity has positive relationship with fractal dimension. This paper also presents a multilayer fractal adsorption model which takes into account the roughness of adsorption surface by using fractal theory. With the introduction of pseudo-saturated vapor pressure in the supercritical temperature condition, the proposed adsorption model can be applied into a wider range of temperature. Based on the low-pressure nitrogen adsorption and methane isothermal adsorption experiments, the effect of fractal dimension on the adsorption behavior of shales is discussed. Fractal dimension has significant impact on the surface adsorption property and adsorption layer number n. The monolayer saturated adsorption volume Vm increases with the increase of D, while parameter C has the opposite variation trend. Finally, the optimal combination of fractal parameters for describing pore structure of shale samples is selected.

Pore Structure Modeling of Flow in Gas Diffusion Layers of Proton Exchange Membrane Fuel Cells

2012 ◽  
Vol 9 (2) ◽  
Author(s):  
Z. Shi ◽  
X. Wang
Keyword(s):  
Fuel Cell ◽  
Pore Structure ◽  
Proton Exchange Membrane ◽  
Cell Model ◽  
Transport Phenomena ◽  
Pem Fuel Cell ◽  
Gas Diffusion ◽  
Proton Exchange ◽  
Structure Model ◽  
Exchange Membrane

The gas diffusion layer (GDL) in a proton exchange membrane (PEM) fuel cell has a porous structure with anisotropic and non-homogenous properties. The objective of this research is to develop a PEM fuel cell model where transport phenomena in the GDL are simulated based on GDL’s pore structure. The GDL pore structure was obtained by using a scanning electron microscope (SEM). GDL’s cross-section view instead of surface view was scanned under the SEM. The SEM image was then processed using an image processing tool to obtain a two-dimensional computational domain. This pore structure model was then coupled with an electrochemical model to predict the overall fuel cell performance. The transport phenomena in the GDL were simulated by solving the Navier-Stokes equation directly in the GDL pore structure. By comparing with the testing data, the fuel cell model predicted a reasonable fuel cell polarization curve. The pore structure model was further used to calculate the GDL permeability. The numerically predicted permeability was close to the value published in the literature. A future application of the current pore structure model is to predict GDL thermal and electric related properties.

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