Pore Structure Modeling of Flow in Gas Diffusion Layers of Proton Exchange Membrane Fuel Cells

2012 ◽  
Vol 9 (2) ◽  
Author(s):  
Z. Shi ◽  
X. Wang
Keyword(s):  
Fuel Cell ◽  
Pore Structure ◽  
Proton Exchange Membrane ◽  
Cell Model ◽  
Transport Phenomena ◽  
Pem Fuel Cell ◽  
Gas Diffusion ◽  
Proton Exchange ◽  
Structure Model ◽  
Exchange Membrane

The gas diffusion layer (GDL) in a proton exchange membrane (PEM) fuel cell has a porous structure with anisotropic and non-homogenous properties. The objective of this research is to develop a PEM fuel cell model where transport phenomena in the GDL are simulated based on GDL’s pore structure. The GDL pore structure was obtained by using a scanning electron microscope (SEM). GDL’s cross-section view instead of surface view was scanned under the SEM. The SEM image was then processed using an image processing tool to obtain a two-dimensional computational domain. This pore structure model was then coupled with an electrochemical model to predict the overall fuel cell performance. The transport phenomena in the GDL were simulated by solving the Navier-Stokes equation directly in the GDL pore structure. By comparing with the testing data, the fuel cell model predicted a reasonable fuel cell polarization curve. The pore structure model was further used to calculate the GDL permeability. The numerically predicted permeability was close to the value published in the literature. A future application of the current pore structure model is to predict GDL thermal and electric related properties.

Pore Structure Modeling of Flow in Gas Diffusion Layers of Proton Exchange Membrane Fuel Cells

2010 ◽  
Author(s):  
Zhongying Shi ◽  
Xia Wang
Keyword(s):  
Fuel Cell ◽  
Pore Structure ◽  
Proton Exchange Membrane ◽  
Cell Model ◽  
Transport Phenomena ◽  
Pem Fuel Cell ◽  
Gas Diffusion ◽  
Proton Exchange ◽  
Structure Model ◽  
Exchange Membrane

The gas diffusion layer (GDL) in a proton exchange membrane (PEM) fuel cell has a porous structure with anisotropic and non-homogenous properties. The objective of this research is to develop a PEM fuel cell model where transport phenomena in the GDL are simulated based on GDL’s pore structure. The GDL pore structure was obtained by using a scanning electron microscope (SEM). GDL’s cross-section view instead of surface view was scanned under the SEM. The SEM image was then processed using an image processing tool to obtain a two dimensional computational domain. This pore structure model was then coupled with an electrochemical model to predict the overall fuel cell performance. The transport phenomena in the GDL were simulated by solving the Navier-Stokes equation directly in the GDL pore structure. By comparing with the testing data, the fuel cell model predicted a reasonable fuel cell polarization curve. The pore structure model was further used to calculate the GDL permeability. The numerically predicted permeability was close to the value published in the literature. A future application of the current pore structure model is to predict GDL thermal and electric related properties.

Experimental Investigation of Proton Exchange Membrane Fuel Cell With Platinum and Nafion Along the In-Plane Direction

2020 ◽  
Author(s):  
Peng Cheng ◽  
Chasen Tongsh ◽  
Jinqiao Liang ◽  
Zhi Liu ◽  
Qing Du ◽  
...  
Keyword(s):  
Fuel Cell ◽  
Flow Rate ◽  
Proton Exchange Membrane ◽  
Pem Fuel Cell ◽  
Gas Diffusion ◽  
Proton Exchange ◽  
Cell Performance ◽  
Gradient Distribution ◽  
Plane Direction ◽  
Exchange Membrane

Abstract In this study, an experimental study has been performed to investigate the effect of in-plane distribution of Pt and Nafion in membrane electrode assembly (MEA) on proton exchange membrane (PEM) fuel cell. Two types of MEAs, such as the gradient and uniform distributions of Pt catalyst and Nafion, are compared under various operating conditions including cathode flow rate, MEA preparation method, Pt loading and relative humidity (RH). The catalyst ink is sprayed onto Nafion membrane or gas diffusion layer (GDL) through a pneumatic automatic spraying device manufactured by ourselves. MEA is prepared by hot pressing. The results show that as flow rate decreases, the MEA with gradient distribution will show a higher voltage at a high current density for catalyst coated membrane (CCM) method. For CCM method, gradient distribution can optimize cell performance under low cathode flow rate, but the optimization effect is weakened when flow rate is too low. Compared with CCM method, the gas diffusion electrode (GDE) method makes the difference value of Ohmic resistance between gradient and uniform distribution very larger, resulting in poor performance improvement. For GDE method, gradient distribution shows no optimization for cell performance under different Pt loadings and RH, but a smaller average Pt loading and fully-humidified reactants can reduce the performance distinction between uniform and gradient distribution. The gradient design of Pt and Nafion along the in-plane direction is a promising strategy to improve the performance of PEM fuel cell. Reasonably controlling the gradient distribution of Pt in the plane direction of cathode can reduce the amount of Pt catalysts and improve efficiency.

scholarly journals Thermal and Electrical Parameter Identification of a Proton Exchange Membrane Fuel Cell Using Genetic Algorithm

Energies ◽  
2018 ◽  
Vol 11 (8) ◽  
pp. 2099 ◽  
Author(s):  
H. Ariza ◽  
Antonio Correcher ◽  
Carlos Sánchez ◽  
Ángel Pérez-Navarro ◽  
Emilio García
Keyword(s):  
Fuel Cell ◽  
Proton Exchange Membrane ◽  
Cell Model ◽  
Electrical Parameter ◽  
Real Data ◽  
Pem Fuel Cell ◽  
Proton Exchange ◽  
Physical Models ◽  
Real Behavior ◽  
Exchange Membrane

Proton Exchange Membrane Fuel Cell (PEMFC) fuel cells is a technology successfully used in the production of energy from hydrogen, allowing the use of hydrogen as an energy vector. It is scalable for stationary and mobile applications. However, the technology demands more research. An important research topic is fault diagnosis and condition monitoring to improve the life and the efficiency and to reduce the operation costs of PEMFC devices. Consequently, there is a need of physical models that allow deep analysis. These models must be accurate enough to represent the PEMFC behavior and to allow the identification of different internal signals of a PEM fuel cell. This work presents a PEM fuel cell model that uses the output temperature in a closed loop, so it can represent the thermal and the electrical behavior. The model is used to represent a Nexa Ballard 1.2 kW fuel cell; therefore, it is necessary to fit the coefficients to represent the real behavior. Five optimization algorithms were tested to fit the model, three of them taken from literature and two proposed in this work. Finally, the model with the identified parameters was validated with real data.

Computational Modelling and Simulation of Proton-Exchange Membrane Fuel Cells (Keynote)

2002 ◽  
Author(s):  
N. Djilali ◽  
T. Berning
Keyword(s):  
Fuel Cells ◽  
Fuel Cell ◽  
Proton Exchange Membrane ◽  
Transport Phenomena ◽  
Computational Modelling ◽  
Ambient Air ◽  
Gas Diffusion ◽  
Transport Processes ◽  
Proton Exchange ◽  
Exchange Membrane

Fuel cells (FC’s) are electrochemical devices that convert directly into electricity the chemical energy of reaction of a fuel (usually hydrogen) with an oxidant (usually oxygen from ambient air). The only by-products in a hydrogen fuel cell are heat and water, making this emerging technology the leading candidate for quiet, zero emission energy production. Several types of fuel cell are currently undergoing intense research and development for applications ranging from portable electronics and appliances to residential power generation and transportation. The focus of this lecture is Proton-Exchange Membrane Fuel Cells (PEMFC’s). An electrolyte consisting of a “solid” polymer membrane, low operating temperatures (typically below 90 °C) and a relatively simple design combine to make PEMFC’s particularly well suited to automotive and portable applications. The operation of a fuel cell relies on electrochemical reactions and an array of coupled transport phenomena, including multi-component gas flow, two phase-flow, heat and mass transfer, phase change and transport of charged species. The transport processes take place in variety of media, including porous gas diffusion electrodes and polymer membranes. The fuel cell environment makes it impossible to measure in-situ the quantities of interest to understand and quantify these phenomena, and computational modelling and simulations are therefore poised to play a central role in the development and optimization of fuel cell technology. We provide an overview of the role of various transport phenomena in fuel cell operation and some of the physical and computational modelling challenges they present. The processes will be illustrated through examples of multi-dimensional numerical simulations of Proton-Exchange Membrane Fuel Cells. We close with a perspective on some of the many remaining challenges and future development opportunities.

Two-Stage Design of Linear Feedback Controllers for a Proton Exchange Membrane Fuel Cell

2015 ◽  
Author(s):  
Verica Radisavljevic-Gajic ◽  
Patrick Rose ◽  
Garrett M. Clayton
Keyword(s):  
Fuel Cell ◽  
Time Scale ◽  
Proton Exchange Membrane ◽  
Cell Model ◽  
Pem Fuel Cell ◽  
Proton Exchange ◽  
Linear Feedback ◽  
Fast Time ◽  
State Variables ◽  
Exchange Membrane

The paper considers the eighth-order proton exchange membrane (PEM) fuel-cell mathematical model and shows that it has a multi-time scale property, indicating that the dynamics of three model state space variables operate in the slow time scale and the dynamics of five state variables operate in the fast time scale. This multi-scale nature allows independent controllers to be designed in slow and fast time scales using only corresponding reduced-order slow (of dimension three) and fast (of dimension five) sub-models. The presented design facilitates the design of hybrid controllers, for example, the linear-quadratic optimal controller for the slow subsystem and the eigenvalue assignment controller for the fast subsystem. The design efficiency and its high accuracy are demonstrated via simulation on the considered PEM fuel cell model.

An Analytical Model for Contact Pressure Prediction Considering Dimensional Error of Stamped Bipolar Plate and Gas Diffusion Layer in Proton Exchange Membrane Fuel Cell Stack Assembly

2016 ◽  
Vol 13 (2) ◽  
Author(s):  
Linfa Peng ◽  
Diankai Qiu ◽  
Peiyun Yi ◽  
Xinmin Lai
Keyword(s):  
Fuel Cell ◽  
Pressure Distribution ◽  
Contact Pressure ◽  
Proton Exchange Membrane ◽  
Pem Fuel Cell ◽  
Bipolar Plate ◽  
Gas Diffusion ◽  
Proton Exchange ◽  
Dimensional Errors ◽  
Exchange Membrane

Contact pressure distribution between bipolar plate (BPP) and gas diffusion layer (GDL) has significant impact on performance and life time of proton exchange membrane (PEM) fuel cell. Most current studies for contact pressure prediction are based on finite-element analysis (FEA), requiring huge computation for the whole fuel cell assembly. Comparatively speaking, the more generalized and well-developed analytical methods are deficient in this field. The objective of this study is to propose a full-scale continuous equivalent model to predict GDL contact pressure effectively in the PEM fuel cell. Using the model, the nonuniform pressure distribution resulted from dimensional errors of metallic BPP and GDL could be obtained. First, a parameterized theoretical model of BPP/GDL assembly is established based on equivalent stiffness analysis of components, and definition methods of dimensional errors are proposed according to actual measurements and Monte Carlo simulation (MCS). Then, experiments are carried out to obtain the actual GDL contact pressure and the model results show good agreement with experimental results. At last, effects of dimensional errors are investigated. Acceptable assembly pressure for a given fuel cell is suggested based on the model. This model is helpful to understand the effect of the dimensional errors, and it also could be adopted to guide the manufacturing of BPP, GDL, and the assembling of PEM fuel cell.

Numerical Simulation of Droplet Emergence and Growth From Gas Diffusion Layers (GDLs) in Proton Exchange Membrane (PEM) Fuel Cell Flow Channels

2018 ◽  
Author(s):  
Jingru Benner ◽  
Mehdi Mortazavi ◽  
Anthony D. Santamaria
Keyword(s):  
Fuel Cell ◽  
Proton Exchange Membrane ◽  
Pem Fuel Cell ◽  
Gas Diffusion ◽  
Proton Exchange ◽  
Gas Diffusion Layers ◽  
Diffusion Layers ◽  
Flow Channels ◽  
Exchange Membrane ◽  
Over Time

Liquid water management is critical for Proton Exchange Membrane (PEM) fuel cell operation, as excessive humidity can lead to flooding and cell performance degradation. Water is produced in the cathode catalyst layer during the electrochemical reaction. If reactant gas streams become saturated, liquid water forms and must travel through anode and cathode Gas Diffusion Layers (GDLs) to reach flow channels for removal. Understanding the dynamic behavior of the droplet is critical to improve water removal strategies for PEM fuel cells. In this study a 3D, transient, two-phase model based on the Volume of Fluid (VOF) method was developed to study a single droplet in the gas channel. The formation, growth, and breakup of the droplet is tracked numerically and analyzed. The pressure drop across the droplet is monitored over time and compared with theoretical analysis. The droplet size and shape change over time for two different pore sizes are compared. The impact of various gases including air, helium, and hydrogen on droplet dynamics is presented. The viscous force and pressure force on the droplet and the drag coefficient are calculated.

Accelerated Numerical Test of Liquid Behavior Across Gas Diffusion Layer in Proton Exchange Membrane Fuel Cell Cathode

2008 ◽  
Vol 5 (4) ◽  
Author(s):  
Kui Jiao ◽  
Biao Zhou
Keyword(s):  
Fuel Cell ◽  
Water Flow ◽  
Diffusion Layer ◽  
Proton Exchange Membrane ◽  
Gas Diffusion Layer ◽  
Pem Fuel Cell ◽  
Gas Diffusion ◽  
Proton Exchange ◽  
Fuel Cell Cathode ◽  
Exchange Membrane

Liquid water transport inside proton exchange membrane (PEM) fuel cells is one of the key challenges for water management in a PEM fuel cell. Investigation of the air-water flow patterns inside fuel cell gas flow channels with gas diffusion layer (GDL) would provide valuable information that could be used in fuel cell design and optimization. This paper presents an accelerated numerical investigation of air-water flow across a GDL with a serpentine channel on PEM fuel cell cathode by use of a commercial computational fluid dynamics software package FLUENT. Detailed flow patterns with air-water across the porous media were investigated and discussed.

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