scholarly journals Migration and Entrapment of DNAPLs in Heterogeneous Systems: Impact of Waste and Porous Medium Composition

2005 ◽  
Author(s):  
Linda M. Abriola ◽  
Avery H. Demond
1963 ◽  
Vol 3 (02) ◽  
pp. 145-154 ◽  
Author(s):  
E.J. Koval

KOVAL, E.J., CALIFORNIA RESEARCH CORP., LA HABRA, CALIF. Abstract Practical miscible displacement processes will be characterized by fingering of the solvent into the oil. The fingering process is brought on by viscosity differences, and can be accentuated by channeling and longitudinal dispersion. The effects of these factors on the efficiency of unstable completely miscible displacements are combined in what is called the K-factor method. This method, analogous to the Buckley-Leverett method, predicts recovery and solvent cut as a function of pore volumes of solvent injected. Experimental data are included and show excellent agreement with theory for a wide variety of sandstone cores and viscosity ratios. Introduction Theoretical considerations, laboratory experiments, and pilot tests lead to the conclusion that miscible displacements in the field will be unstable. In an unstable miscible displacement, the solvent fingers through the oil. This fingering leads to early breakthrough of the solvent and an extended period during which both oil and solvent are produced.For such a system, there appear to be four principal factors which bring about or accentuate the effects of instability: longitudinal dispersion (including geometrical effects), channeling, viscosity differences and gravity differences. Other factors, such as diffusion and flooding rate, can also influence the effects of instability, but at the flooding rates considered in this report, circa 15 ft/D, they are unimportant. Longitudinal dispersion can be thought of as a spreading of the solvent front caused by the presence of microscopic inhomogeneities. Channeling of the solvent occurs when a porous medium has macroscopic inhomogeneities; i.e., gross permeability variations. Viscosity differences lead to fingering of the less viscous solvent. This difference in viscosity accelerates the growth of fingers along paths previously developed because of permeability variations. Gravity differences lead to overriding of the usually less dense solvent. Although gravity effects are generally small at a flooding rate of 15 ft/D, they would, nevertheless, unnecessarily complicate the interpretation of flooding experiments. For this reason, all the experiments reported herein were done with matched density fluids.Fingering and the resultant poor areal sweep were recognized early as the dominant influences on the efficiency and the economics of miscible displacement processes. Much research effort has been spent on ways to minimize fingering and increase areal sweep such as the use of graded viscosity slugs or water slugs. Some researchers attempted to work out ways to prevent fingering completely; i.e., to achieve a stable displacement through gravity or latitudinal dispersion stabilization. Others did not attempt to control fingering but obtained an economic process by merely recycling the solvent and sweeping pattern by pattern.During this period, all aspects of fingering came under close scrutiny. Some researchers reported on how fingering looks and how it is affected by viscosity ratio, geometry, and slug size. Peaceman and Rachford suggested a mathematical approach to the prediction of unstable miscible displacements in relatively homogeneous sand packs, but their work cannot be extended conveniently to heterogeneous systems. Hence for a heterogeneous system, no method is presently available for predicting solvent cut and recovery as functions of pore volumes of solvent injected.The purpose of this investigation was to attempt to fill in the gap in our knowledge concerning the prediction of performance of unstable miscible displacements. Necessarily, the system selected for study was a relatively simple one. The restrictions placed on the system were:The system was linear;The solvent was miscible in all proportions with the oil in place;The solvent was continuously injected into the porous medium;Gravitational effects were eliminated by matching densities andAll the flood rates were high and constant at 15 ft/D to avoid any small rate effect and to minimize any diffusion effects. To simplify and to indicate that both longitudinal dispersion and channeling arise from permeability variations, the effects which they cause or influence have been termed heterogeneity effects. SPEJ P. 145^


1966 ◽  
Vol 6 (03) ◽  
pp. 228-238 ◽  
Author(s):  
R.L. Perrine ◽  
G.M. Gay

Abstract This paper describes a method of numerical computation for three-dimensional, unstable, miscible displacement behavior useful for heterogeneous systems, as well as for more ideal conditions. In the method, flow equations are first linearized by a perturbation approach. The basic flow process is separated and a solution for its behavior readily obtained. The remaining problem of deviations from the basic flow caused by non-ideal conditions is then subjected to numerical analysis. Results obtained from use of the method are also presented. Although conditions assumed in the test calculations were severe, results show the type of dispersing flow expected and appear quite satisfactory. The method has eliminated or reduced in importance problems of oscillating values near steep fronts, excessive computer smoothing, etc. A unique advantage of the method is that the source of variations from ideal behavior can be observed. The one serious drawback results from the algebraic complexity of the perturbation approach, and the need for second-order terms to be retained in calculations of interest, Fewer array points are available and more computer time is required than would be desired. However, these difficulties are also experienced with other approaches to the solution of three-dimensional displacement problems. INTRODUCTION Prediction of behavior of the miscible displacement process within a porous medium for any system of engineering importance is plagued by a number of difficulties. With typical fluid properties the displacing fluid has the lower viscosity, and there is a natural tendency toward flow instability. The problem of predicting instability is compounded by the fact that every real system is heterogeneous. Permeability will vary from point to point - not entirely systematically, and yet not in a random fashion leading to a readily defined average. Furthermore, permeability is unlikely to be isotropic. These permeability properties, which are characteristic of any real porous medium, accentuate the effects of flow instability. Another factor to be considered is that flow dispersion accompanies the displacement process in a porous medium. Mechanistically, dispersion is due to the fact that flow between any two points in the medium follows multiple tortuous paths, each characterized by slightly different flow properties. The fact that the coefficient characterizing dispersive properties of the real medium is a tensor with variable elements complicates matters. Further difficulties arise because the parabolic influence, while not negligible, is small. Thus, there is a tendency toward steep and uneven displacement fronts along which dispersion smoothing must be represented accurately. Yet frequently used numerical analysis schemes may tend toward either instability, oscillation or excessive smoothing, none of which gives the desired accurate picture of flow behavior. Thus, while many experimental and analytical studies of the process have been made, predictions of actual performance are still subject to considerable uncertainty and possible improvement. This paper reports on part of a study which attempts to develop improved methods for solution of the flow equations describing the miscible displacement process. Of necessity, the calculations were performed on a large digital computer. A three-dimensional system is represented, and the coefficients defining dispersion and permeability can be varied in a manner representative of a real system.


1998 ◽  
Vol 37 (04/05) ◽  
pp. 518-526 ◽  
Author(s):  
D. Sauquet ◽  
M.-C. Jaulent ◽  
E. Zapletal ◽  
M. Lavril ◽  
P. Degoulet

AbstractRapid development of community health information networks raises the issue of semantic interoperability between distributed and heterogeneous systems. Indeed, operational health information systems originate from heterogeneous teams of independent developers and have to cooperate in order to exchange data and services. A good cooperation is based on a good understanding of the messages exchanged between the systems. The main issue of semantic interoperability is to ensure that the exchange is not only possible but also meaningful. The main objective of this paper is to analyze semantic interoperability from a software engineering point of view. It describes the principles for the design of a semantic mediator (SM) in the framework of a distributed object manager (DOM). The mediator is itself a component that should allow the exchange of messages independently of languages and platforms. The functional architecture of such a SM is detailed. These principles have been partly applied in the context of the HEllOS object-oriented software engineering environment. The resulting service components are presented with their current state of achievement.


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