Unstable Miscible Flow in Heterogeneous Systems

1966 ◽  
Vol 6 (03) ◽  
pp. 228-238 ◽  
Author(s):  
R.L. Perrine ◽  
G.M. Gay

Abstract This paper describes a method of numerical computation for three-dimensional, unstable, miscible displacement behavior useful for heterogeneous systems, as well as for more ideal conditions. In the method, flow equations are first linearized by a perturbation approach. The basic flow process is separated and a solution for its behavior readily obtained. The remaining problem of deviations from the basic flow caused by non-ideal conditions is then subjected to numerical analysis. Results obtained from use of the method are also presented. Although conditions assumed in the test calculations were severe, results show the type of dispersing flow expected and appear quite satisfactory. The method has eliminated or reduced in importance problems of oscillating values near steep fronts, excessive computer smoothing, etc. A unique advantage of the method is that the source of variations from ideal behavior can be observed. The one serious drawback results from the algebraic complexity of the perturbation approach, and the need for second-order terms to be retained in calculations of interest, Fewer array points are available and more computer time is required than would be desired. However, these difficulties are also experienced with other approaches to the solution of three-dimensional displacement problems. INTRODUCTION Prediction of behavior of the miscible displacement process within a porous medium for any system of engineering importance is plagued by a number of difficulties. With typical fluid properties the displacing fluid has the lower viscosity, and there is a natural tendency toward flow instability. The problem of predicting instability is compounded by the fact that every real system is heterogeneous. Permeability will vary from point to point - not entirely systematically, and yet not in a random fashion leading to a readily defined average. Furthermore, permeability is unlikely to be isotropic. These permeability properties, which are characteristic of any real porous medium, accentuate the effects of flow instability. Another factor to be considered is that flow dispersion accompanies the displacement process in a porous medium. Mechanistically, dispersion is due to the fact that flow between any two points in the medium follows multiple tortuous paths, each characterized by slightly different flow properties. The fact that the coefficient characterizing dispersive properties of the real medium is a tensor with variable elements complicates matters. Further difficulties arise because the parabolic influence, while not negligible, is small. Thus, there is a tendency toward steep and uneven displacement fronts along which dispersion smoothing must be represented accurately. Yet frequently used numerical analysis schemes may tend toward either instability, oscillation or excessive smoothing, none of which gives the desired accurate picture of flow behavior. Thus, while many experimental and analytical studies of the process have been made, predictions of actual performance are still subject to considerable uncertainty and possible improvement. This paper reports on part of a study which attempts to develop improved methods for solution of the flow equations describing the miscible displacement process. Of necessity, the calculations were performed on a large digital computer. A three-dimensional system is represented, and the coefficients defining dispersion and permeability can be varied in a manner representative of a real system.

1963 ◽  
Vol 3 (02) ◽  
pp. 145-154 ◽  
Author(s):  
E.J. Koval

KOVAL, E.J., CALIFORNIA RESEARCH CORP., LA HABRA, CALIF. Abstract Practical miscible displacement processes will be characterized by fingering of the solvent into the oil. The fingering process is brought on by viscosity differences, and can be accentuated by channeling and longitudinal dispersion. The effects of these factors on the efficiency of unstable completely miscible displacements are combined in what is called the K-factor method. This method, analogous to the Buckley-Leverett method, predicts recovery and solvent cut as a function of pore volumes of solvent injected. Experimental data are included and show excellent agreement with theory for a wide variety of sandstone cores and viscosity ratios. Introduction Theoretical considerations, laboratory experiments, and pilot tests lead to the conclusion that miscible displacements in the field will be unstable. In an unstable miscible displacement, the solvent fingers through the oil. This fingering leads to early breakthrough of the solvent and an extended period during which both oil and solvent are produced.For such a system, there appear to be four principal factors which bring about or accentuate the effects of instability: longitudinal dispersion (including geometrical effects), channeling, viscosity differences and gravity differences. Other factors, such as diffusion and flooding rate, can also influence the effects of instability, but at the flooding rates considered in this report, circa 15 ft/D, they are unimportant. Longitudinal dispersion can be thought of as a spreading of the solvent front caused by the presence of microscopic inhomogeneities. Channeling of the solvent occurs when a porous medium has macroscopic inhomogeneities; i.e., gross permeability variations. Viscosity differences lead to fingering of the less viscous solvent. This difference in viscosity accelerates the growth of fingers along paths previously developed because of permeability variations. Gravity differences lead to overriding of the usually less dense solvent. Although gravity effects are generally small at a flooding rate of 15 ft/D, they would, nevertheless, unnecessarily complicate the interpretation of flooding experiments. For this reason, all the experiments reported herein were done with matched density fluids.Fingering and the resultant poor areal sweep were recognized early as the dominant influences on the efficiency and the economics of miscible displacement processes. Much research effort has been spent on ways to minimize fingering and increase areal sweep such as the use of graded viscosity slugs or water slugs. Some researchers attempted to work out ways to prevent fingering completely; i.e., to achieve a stable displacement through gravity or latitudinal dispersion stabilization. Others did not attempt to control fingering but obtained an economic process by merely recycling the solvent and sweeping pattern by pattern.During this period, all aspects of fingering came under close scrutiny. Some researchers reported on how fingering looks and how it is affected by viscosity ratio, geometry, and slug size. Peaceman and Rachford suggested a mathematical approach to the prediction of unstable miscible displacements in relatively homogeneous sand packs, but their work cannot be extended conveniently to heterogeneous systems. Hence for a heterogeneous system, no method is presently available for predicting solvent cut and recovery as functions of pore volumes of solvent injected.The purpose of this investigation was to attempt to fill in the gap in our knowledge concerning the prediction of performance of unstable miscible displacements. Necessarily, the system selected for study was a relatively simple one. The restrictions placed on the system were:The system was linear;The solvent was miscible in all proportions with the oil in place;The solvent was continuously injected into the porous medium;Gravitational effects were eliminated by matching densities andAll the flood rates were high and constant at 15 ft/D to avoid any small rate effect and to minimize any diffusion effects. To simplify and to indicate that both longitudinal dispersion and channeling arise from permeability variations, the effects which they cause or influence have been termed heterogeneity effects. SPEJ P. 145^


2015 ◽  
Vol 741 ◽  
pp. 531-535
Author(s):  
Hong Ming Zhang ◽  
Li Xiang Zhang

The paper presents the numerical analysis of erosive wear on the guide vanes of a Francis turbine using CFD code. The 3-D turbulent particulate-liquid two-phase flow equations are employed in this study. The computing domain is discretized with a full three-dimensional mesh system of unstructured tetrahedral shapes. The finite volume method is used to solve the governing equations and the pressure-velocity coupling is handled via a Pressure Implicit with Splitting of Operators (PISO) procedure. Simulation results have shown that the volume fraction of sand at the top of the guide vanes is higher than others and the maximum of volume fraction of sand is at same location with the maximum of sand erosion rate density. The erosive wear is more serious at the top of the guide vanes.


2019 ◽  
Vol 34 (02) ◽  
pp. 1950021
Author(s):  
Z. Péli ◽  
S. Nagy ◽  
K. Sailer

We have treated the Euclidean three-dimensional O(1) ghost model with a modified version of the effective average action (EAA) renormalization group (RG) method, developed by us. We call it Fourier–Wetterich RG approach and it is used to investigate the occurrence of a periodic condensate in terms of the functional RG. The modification involves additional terms in the ansatz of the EAA, corresponding to the Fourier-modes of the periodic condensate. The RG flow equations are derived keeping the terms up to the fourth order of the gradient expansion (GE), however the numerical calculations are conducted in the second order (or next-to-leading order, NLO) of the GE. The expansion of the flow equations around the nontrivial minimum of the local potential takes into account properly the vertices induced by the periodic condensate even if the wave function renormalization is set to be field-independent. The numerical analysis reveals several different phases with three multicritical points.


Author(s):  
Yasuyuki Takata ◽  
K. Fukuda ◽  
Shu Hasegawa ◽  
Kengo Iwashige ◽  
H. Shimomura ◽  
...  

2019 ◽  
Author(s):  
Sayan Mondal ◽  
Gary Tresadern ◽  
Jeremy Greenwood ◽  
Byungchan Kim ◽  
Joe Kaus ◽  
...  

<p>Optimizing the solubility of small molecules is important in a wide variety of contexts, including in drug discovery where the optimization of aqueous solubility is often crucial to achieve oral bioavailability. In such a context, solubility optimization cannot be successfully pursued by indiscriminate increases in polarity, which would likely reduce permeability and potency. Moreover, increasing polarity may not even improve solubility itself in many cases, if it stabilizes the solid-state form. Here we present a novel physics-based approach to predict the solubility of small molecules, that takes into account three-dimensional solid-state characteristics in addition to polarity. The calculated solubilities are in good agreement with experimental solubilities taken both from the literature as well as from several active pharmaceutical discovery projects. This computational approach enables strategies to optimize solubility by disrupting the three-dimensional solid-state packing of novel chemical matter, illustrated here for an active medicinal chemistry campaign.</p>


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