scholarly journals CHEMICAL DECOMPOSITION OF HIGH-LEVEL NUCLEAR WASTE STORAGE/DISPOSAL GLASSES UNDER IRRADIATION

1999 ◽  
Author(s):  
Daavid L Griscom ◽  
Celia I Merzbacher
1983 ◽  
Vol 26 ◽  
Author(s):  
E. W. yyRussell ◽  
R. D. McCright ◽  
W. C. O'Neal

ABSTRACTThe Nevada Nuclear Waste Storage Investigations (NNWSI) project under the Civilian Radioactive Waste Management Program is planning a repository at Yucca Mountain at the Nevada Test Site for isolation of high-level nuclear waste. Lawrence Livermore National Laboratory is developing designs for an engineered barrier system containing several barriers such as the waste form, a canister and/or an overpack, packing, and near field host rock. In this paper we address the selection of metal containment barriers.


1999 ◽  
Vol 556 ◽  
Author(s):  
David A. McKeown ◽  
Isabelle S. Muller ◽  
Andrew C. Buechele ◽  
Ian L. Pegg ◽  
Christopher A. Kendziora ◽  
...  

AbstractA range of compositions of high-zirconia borosilicate glasses were formulated and their structures investigated by a combination of techniques. These compositions have potential applications for high-level nuclear waste storage in combination with advanced reprocessing methods. Raman and Zr EXAFS data were collected for a series of glasses spanning a range of zirconia concentrations. The Raman spectra indicate that Zr acts as a silicate network modifier, where the silicate tetrahedral network depolymerizes as the zirconia content increases. Zr EXAFS analysis indicates that Zr is found in octahedral sites, and to a minor extent, sevencoordinated sites. As the zirconia content increases, the fraction of seven-coordinated Zr-sites increases; this may be the cause of ZrO2 baddeleyite crystallization that was observed in some Zr-rich glasses investigated.


1987 ◽  
Vol 112 ◽  
Author(s):  
John K. Bates ◽  
Thomas J. Gerding

AbstractAs part of the effort by the Nevada Nuclear Waste Storage Investigations (NNWSI) Project to evaluate the volcanic tuff beds of Yucca Mountain, Nevada, as a repository for the permanent storage of high-level nuclear waste, the interaction of actinide-doped Savannah River Laboratory (SRL) 165 type glass with the unsaturated repository environment has been studied. The NNWSI Unsaturated Test method has been used, and the results from batch and continuous tests completed through 18 months demonstrate that several interactions are important for controlling both the reaction of the glass and the release of radionuclides. These interactions include (1) the reaction between the glass and moist air with interludes of liquid water contact, which results in the release of alkali metals from the glass; and (2) the reaction between standing water, glass, and presensitized 304 L type stainless steel which results in breakdown of the glass matrix and the release of radionuclides from the glass-metal assemblage. A comparison of the results of the Unsaturated Test with those of parametric experiments illustrates the importance of presensitized steel in enhancing the glass reaction, and demonstrates the applicability of the Unsaturated Test to those conditions anticipated to exist in the NNWSI repository horizon.


2021 ◽  
Author(s):  
Ronald Joseph Turner ◽  
Pieter Bots ◽  
Alan Richardson ◽  
Paul Bingham ◽  
Alex Scrimshire ◽  
...  

(Hydroxy)apatite [Ca10(PO4)6(OH)2], has emerging potential as a cement coating material, with applications in environmental remediation, nuclear waste storage and architectural preservation. In these low temperature environments and when precipitating from...


Energies ◽  
2021 ◽  
Vol 14 (12) ◽  
pp. 3709
Author(s):  
Bader Alshuraiaan ◽  
Sergey Pushkin ◽  
Anastasia Kurilova ◽  
Magdalena Mazur

Recently, issues related to the effects (benefit or harm) of processing nuclear waste and its further use as fuel have been increasingly often raised in the scientific discussion. In this regard, the research aims to investigate issues related to the assessment of the economic potential of nuclear waste use, as well as the cooperation between states in the context of the reduction of risks associated with nuclear waste storage and processing. The research methodology is based on an integrated approach, including statistical, factor analysis, and the proposed system of performance indicators for managing spent nuclear fuel use. The research was carried out on the basis of materials from Russia and the EU countries. In the course of the study, a model of cooperation between states has been developed (based on the example of technologies and methods of processing nuclear waste used in the EU and Russia) according to the nuclear waste (spent nuclear fuel) management algorithm. The model considers the risks and threats associated with ecology and safety. The developments and other results described in the study should be used in further research devoted to the use of nuclear waste as heat-producing elements.


Sign in / Sign up

Export Citation Format

Share Document