scholarly journals Economic comparison of hydrogen production using sulfuric acid electrolysis and sulfur cycle water decomposition. Final report

1978 ◽  
Author(s):  
G.H. Farbman ◽  
B.R. Krasicki ◽  
C.C. Hardman ◽  
S.S. Lin ◽  
G.H. Parker
Keyword(s):  
Sulfuric Acid ◽  
Hydrogen Production ◽  
Sulfur Cycle ◽  
Final Report ◽  
Water Decomposition ◽  
Economic Comparison

scholarly journals Comparative studies of Cu-Cl Thermochemical Water Decomposition Cyles for Hydrogen Production

2018 ◽  
Vol 61 ◽  
pp. 00009
Author(s):  
Funmilayo Osuolale ◽  
Oladipupo Ogunleye ◽  
Mary Fakunle ◽  
Abdulfataah Busari ◽  
Yetunde Abolanle
Keyword(s):  
Hydrogen Production ◽  
Exergy Analysis ◽  
Energy Analysis ◽  
Chemical Species ◽  
Efficiency Improvement ◽  
Water Decomposition ◽  
Step Cycle ◽  
Efficiency Increase ◽  
Production Stages ◽  
Parametric Studies

This research focuses on thermodynamic analysis of the copper chlorine cycles. The cycles were simulated using Aspen Plus software. All thermodynamic data for all the chemical species were defined from literature and the reliability of other compounds in the simulation were ascertained. The 5-step Cu–Cl cycle consist of five steps; hydrolysis, decomposition, electrolysis, drying and hydrogen production. The 4-step cycle combines the hydrolysis and the drying stage of the 5-step cycle to eliminate the intermediate production and handling of copper solids. The 3-step cycle has hydrolysis, electrolysis and hydrogen production stages. Exergy and energy analysis of the cycles were conducted. The results of the exergy analysis were 59.64%, 44.74% and 78.21% while that of the energy analysis were 50%, 49% and 35% for the 5-step cycle, 4-step cycle and 3-step cycle respectively. Parametric studies were conducted and possible exergy efficiency improvement of the cycles were found to be between 59.57-59.67%, 44.32-45.67% and 23.50-82.10% for the 5-step, 4-step and 3-step respectively. The results from the parametric analysis of the simulated process could assist ongoing efforts to understand the thermodynamic losses in the cycle, to improve efficiency, increase the economic viability of the process and to facilitate eventual commercialization of the process.

Corrosion of the Materials in Sulfuric Acid

2008 ◽  
Author(s):  
Hong Pyo Kim ◽  
Dong-Jin Kim ◽  
Hyuk Chul Kwon ◽  
Ji Yeon Park ◽  
Yong Wan Kim
Keyword(s):  
Corrosion Resistance ◽  
Sulfuric Acid ◽  
Hydrogen Production ◽  
Immersion Time ◽  
Cross Sectional ◽  
Corrosion Morphology ◽  
Nuclear Heat ◽  
Corrosion Behaviors ◽  
Materials Used ◽  
Surface Morphologies

The program for hydrogen production with high temperature nuclear heat has been launched in Korea since 2004. Iodine sulfur (IS) process is one of the promising processes for a hydrogen production because it does not generate a carbon dioxide and massive hydrogen production may be possible. However, the highly corrosive environment of the process is barrier to the application in the industry. Therefore, corrosion behaviors of various materials were evaluated in sulfuric acid to select appropriate materials compatible with the IS process. The materials used in this work were Ni base alloys, Fe-Si alloys, Ta, Au, Pt, Zr, SiC and so on. The test environments were boiling 50wt% sulfuric acid without/with HI as an impurity and 98wt% sulfuric acid. The surface morphologies and cross sectional areas of the corroded materials were examined by using SEM equipped with EDS. From the results of the weight loss and potentiodynamic experiments, it was found that a Si enriched oxide is attributable to a corrosion resistance for materials including Si in boiling 98wt% sulfuric acid. Moreover the passive Si enriched film thickness increased with the immersion time leading to an enhancement of the corrosion resistance. Corrosion behaviours of the material tested are discussed in terms of the chemical composition of the materials, a corrosion morphology and the surface layer’s composition.

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