scholarly journals Thermochemical processes for hydrogen production by water decomposition. Final report

1980 ◽  
Author(s):  
D.D. Perlmutter
2018 ◽  
Vol 61 ◽  
pp. 00009
Author(s):  
Funmilayo Osuolale ◽  
Oladipupo Ogunleye ◽  
Mary Fakunle ◽  
Abdulfataah Busari ◽  
Yetunde Abolanle

This research focuses on thermodynamic analysis of the copper chlorine cycles. The cycles were simulated using Aspen Plus software. All thermodynamic data for all the chemical species were defined from literature and the reliability of other compounds in the simulation were ascertained. The 5-step Cu–Cl cycle consist of five steps; hydrolysis, decomposition, electrolysis, drying and hydrogen production. The 4-step cycle combines the hydrolysis and the drying stage of the 5-step cycle to eliminate the intermediate production and handling of copper solids. The 3-step cycle has hydrolysis, electrolysis and hydrogen production stages. Exergy and energy analysis of the cycles were conducted. The results of the exergy analysis were 59.64%, 44.74% and 78.21% while that of the energy analysis were 50%, 49% and 35% for the 5-step cycle, 4-step cycle and 3-step cycle respectively. Parametric studies were conducted and possible exergy efficiency improvement of the cycles were found to be between 59.57-59.67%, 44.32-45.67% and 23.50-82.10% for the 5-step, 4-step and 3-step respectively. The results from the parametric analysis of the simulated process could assist ongoing efforts to understand the thermodynamic losses in the cycle, to improve efficiency, increase the economic viability of the process and to facilitate eventual commercialization of the process.


2014 ◽  
Vol 699 ◽  
pp. 474-479 ◽  
Author(s):  
Abdul Hadi Abdol Rahim ◽  
Alhassan Salami Tijani ◽  
Wan Ahmad Najmi Wan Mohamed ◽  
Suhadiyana Hanapi ◽  
Khairul Imran Sainan

Hydrogen production through solar energy technology plays a very important role in the development of sustainable energy systems. Traditionally, a wide variety of methods are available for hydrogen production from conventional sources such as natural gas, coal and oil. Their application, however, contributes to emission of ozone depleting gases such as CO2. This paper reviews the recent developments of hydrogen production methods related to solar-hydrogen production for remote area application. The methods discussed are thermochemical, photoelectrochemical and electrochemical where water is the basic raw material. From this review, the low overall efficiency of photoelectrochemical and thermochemical processes make them non-attractive for remote areas application. This paper concludes that the most suitable method for hydrogen production for remote area application is electrochemical process where electrolyzer represents the most important process to obtain hydrogen without any emission of air pollutants or greenhouse gases. This paper will be useful for manufacturers, academicians and researchers who are involved and interested in solar hydrogen system.


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