scholarly journals Kinetics of lignite pyrolysis in fixed bed and entrained flow reactors. Technical report No. 17

1979 ◽  
Author(s):  
A. W. Scaroni ◽  
Jr., P. L. Walker
2013 ◽  
Vol 58 (2) ◽  
pp. 375-393
Author(s):  
Radosław Pomykała

Most of the coal gasification plants based of one of the three main types of reactors: fixed bed, fluidized bed or entrained flow. In recent years, the last ones, which works as „slagging“ reactors (due to the form of generated waste), are very popular among commercial installations. The article discusses the characteristics of the waste from coal gasification in entrained flow reactors, obtained from three foreign installations. The studies was conducted in terms of the possibilities of use these wastes in mining technologies, characteristic for Polish underground coal mines. The results were compared with the requirements of Polish Standards for the materials used in hydraulic backfill as well as suspension technology: solidification backfill and mixtures for gob caulking.


2020 ◽  
Vol 10 (1-2) ◽  
pp. 58-72
Author(s):  
D. A. Sladkovskiy ◽  
K. V. Semikin ◽  
A. V. Utemov ◽  
S. P. Fedorov ◽  
E. V. Sladkovskaya ◽  
...  

Author(s):  
Zheyong Li ◽  
Yajun Yuan ◽  
Lin Ma ◽  
Yihui Zhang ◽  
Hongwei Jiang ◽  
...  

Selenium (Se) is an essential and crucial micronutrient for humans and animals, but excessive Se brings negativity and toxicity. The adsorption and oxidation of Se(IV) on Mn-oxide surfaces are important processes for understanding the geochemical fate of Se and developing engineered remediation strategies. In this study, the characterization of simultaneous adsorption, oxidation, and desorption of Se(IV) on δ-MnO2 mineral was carried out using stirred-flow reactors. About 9.5% to 25.3% of Se(IV) was oxidized to Se(VI) in the stirred-flow system in a continuous and slow process, with the kinetic rate constant k of 0.032 h−1, which was significantly higher than the apparent rate constant of 0.0014 h−1 obtained by the quasi-level kinetic fit of the batch method. The oxidation reaction was driven by proton concentration, and its rate also depended on the Se(IV) influent concentration, flow rate, and δ-MnO2 dosage. During the reaction of Se(IV) and δ-MnO2, Mn(II) was produced and adsorbed strongly on Mn oxide surfaces, which was evidenced by the total reflectance Fourier transform infrared (ATR-FTIR) results. The X-ray photoelectron spectroscopy (XPS) data indicated that the reaction of Se(VI) on δ-MnO2 produced Mn(III) as the main product. These results contribute to a deeper understanding of the interface chemical process of Se(IV) with δ-MnO2 in the environment.


1996 ◽  
Vol 14 (3) ◽  
pp. 145-150 ◽  
Author(s):  
E. S�nchez ◽  
R. Borja ◽  
L. Travieso

RSC Advances ◽  
2015 ◽  
Vol 5 (115) ◽  
pp. 95287-95299 ◽  
Author(s):  
A. A. Mirzaei ◽  
E. Rezazadeh ◽  
M. Arsalanfar ◽  
M. Abdouss ◽  
M. Fatemi ◽  
...  

The kinetics of the CO hydrogenation reaction over a Fe–Mn fused catalyst was investigated in a fixed-bed micro-reactor.


2020 ◽  
Vol 10 (24) ◽  
pp. 8962
Author(s):  
Mohammad Reza Ghaani ◽  
Satoshi Takeya ◽  
Niall J. English

There have been studies on gas-phase promoter facilitation of H2-containing clathrates. In the present study, non-equilibrium molecular dynamics (NEMD) simulations were conducted to analyse hydrogen release and uptake from/into propane planar clathrate surfaces at 180–273 K. The kinetics of the formation of propane hydrate as the host for hydrogen as well as hydrogen uptake into this framework was investigated experimentally using a fixed-bed reactor. The experimental hydrogen storage capacity propane hydrate was found to be around 1.04 wt% in compare with the theoretical expected 1.13 wt% storage capacity of propane hydrate. As a result, we advocate some limitation of gas-dispersion (fixed-bed) reactors such as the possibility of having un-reacted water as well as limited diffusion of hydrogen in the bulk hydrate.


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