Identifiability of kinetic models of isotope transient tracing in fixed bed plug flow reactors

1999 ◽  
Vol 68 (1) ◽  
pp. 77-94
Author(s):  
Masood Otarod ◽  
John Happel
2010 ◽  
Vol 35 (1) ◽  
pp. 283-287 ◽  
Author(s):  
Pengmei Lu ◽  
Zhenhong Yuan ◽  
Lianhua Li ◽  
Zhongming Wang ◽  
Wen Luo
Keyword(s):  

1987 ◽  
Vol 42 (5) ◽  
pp. 1095-1101 ◽  
Author(s):  
Jan Thullie ◽  
Leroy Chiao ◽  
Robert G. Rinker
Keyword(s):  

2020 ◽  
Vol 10 (1-2) ◽  
pp. 58-72
Author(s):  
D. A. Sladkovskiy ◽  
K. V. Semikin ◽  
A. V. Utemov ◽  
S. P. Fedorov ◽  
E. V. Sladkovskaya ◽  
...  

Author(s):  
Pablo Giunta ◽  
Norma Amadeo ◽  
Miguel Laborde

The aim of this work is to design an ethanol steam reformer to produce a hydrogen stream capable of feeding a 60 kW PEM fuel cell applying the plug flow model, considering the presence of the catalyst bed (heterogeneous model). The Dusty-Gas Model is employed for the catalyst, since it better predicts the fluxes of a multicomponent mixture. Moreover, this model has shown to be computationally more robust than the Fickian Model. A power law-type kinetics was used. Results showed that it is possible to carry out the ethanol steam reforming in a compact device (1.66 x 10 -5 to 5.27 x 10 -5 m3). It was also observed that this process is determined by heat transfer.


1995 ◽  
Vol 32 (8) ◽  
pp. 205-212 ◽  
Author(s):  
A. Wobus ◽  
S. Ulrich ◽  
I. Röske

Two identical fixed bed reactors containing gas-permeable tubings as carrier material were compared for the elimination of chlorophenols. Under plug flow conditions, the continuous flow operation resulted in a stratification of biomass due to concentration gradients. To achieve a homogeneous colonization, the sequencing batch mode has been applicated to one biofilm reactor (Sequencing Batch Biofilm Reactor - SBBR). Concentration gradients after filling, probably due to sorption phenomena, caused an uneven distribution of biomass in the SBBR. However, the colonization of the SBBR was more homogeneous as compared to the continuously operated reactor (CFBR). As to the elimination of a trichlorophenol (2,4,5-trichlorophenol - TCP), no significant differences between the SBBR and the CFBR were observed with regard to its sensitivity against load surges. It is to be supposed that sorption to the biofilm was included in the elimination of chlorophenols. A higher diversity of protozoan community and meiofauna is obviously to be attributed to continuous flow.


2018 ◽  
Vol 25 (31) ◽  
pp. 31062-31070 ◽  
Author(s):  
Katheem Kiyasudeen ◽  
Mahamad Hakimi Ibrahim ◽  
Syahidah Akmal Muhammad ◽  
Sultan Ahmed Ismail ◽  
Fadzil Noor Gonawan ◽  
...  

Author(s):  
Nakisa Yaghobi ◽  
Mir Hamid Reza Ghoreishy

The aim of this work is to develop and compare kinetic models for the oxidative coupling of methane (OCM) based on the gas hourly space velocity (GHSV) value and CH4/O2 ratio in two scales: laboratory and bench. The experiments were carried out in tubular fixed bed reactors at 1023 K, using 0.7-1.5 g and 30 g of perovskite titanate as the reaction catalyst for laboratory and bench scales, respectively. The various GHSVs (8000, 12000, 17000 h-1) and (3400, 4300, 5200 h-1) and methane to oxygen ratios (1, 2, 3, 4, 7.5) and (2, 2.5, 3) were selected for laboratory and bench scales, respectively. We have proposed a mechanism in which the consumption rate of methane is always twice of production rate of C2. A power law model was assumed for rate of reaction in terms of partial pressure of oxygen and methane. Using a linear regression analysis, the kinetic models were determined. Comparison of the calculated rate of reaction with the experimentally measured data confirmed the accuracy and applicability of the developed model for both scales.


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