scholarly journals Line width and line shape analysis in the inductively coupled plasma by high resolution Fourier transform spectrometry

1984 ◽  
Author(s):  
L.M. Faires ◽  
B.A. Palmer ◽  
J.W. Brault
Keyword(s):  
Fourier Transform ◽  
High Resolution ◽  
Line Width ◽  
Shape Analysis ◽  
Line Shape ◽  
Inductively Coupled Plasma ◽  
Inductively Coupled ◽  
Fourier Transform Spectrometry ◽  
Line Shape Analysis

Hindered Rotation in Carbamates: A Kinetic Anomaly

1972 ◽  
Vol 50 (10) ◽  
pp. 1594-1596 ◽  
Author(s):  
P. T. Inglefield ◽  
S. Kaplan
Keyword(s):  
High Resolution ◽  
Transition State ◽  
Shape Analysis ◽  
Line Shape ◽  
Energy Barriers ◽  
Hindered Rotation ◽  
Line Shape Analysis ◽  
Influence Of Solvent

The energy barriers to hindered rotation in two carbamate structures have been measured by total line-shape analysis of the high resolution n.m.r. spectrum. Conclusions are presented concerning the influence of solvent on the nature of the transition state in such processes and the existence of frequency factors outside the normal expected range for a unimolecular transformation.

Zeeman-Effekt im Rotationsspektrum von Perdeuterodimethylsulfid / Rotational zeeman-effect of perdeuterodimethylsulfid

1972 ◽  
Vol 27 (7) ◽  
pp. 1159-1164 ◽  
Author(s):  
E. Hamer ◽  
D. H. Sutter ◽  
H. Dreizler
Keyword(s):  
Dipole Moment ◽  
High Resolution ◽  
Shape Analysis ◽  
Electric Dipole Moment ◽  
Sulfur Atom ◽  
Electric Dipole ◽  
Line Shape ◽  
Zeeman Effect ◽  
Line Shape Analysis

Abstract The rotational Zeeman effect of (CH3)2S and (CD3)2S has been observed under high resolution. Earlier measurements of BENSON and FLYGARE 2 on (CH3)2S were supplemented by the recording of two additional transitions. A line shape analysis was used to evaluate the data which led to the determination of the diagonal elements of the g-tensor and of the susceptibility anisotropies [in 10-6 erg/(G2 mole)] :From the change of the g-values upon deuteration it was possible to determine the sign of the electric dipole moment (negative end at the sulfur atom)

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