scholarly journals Oxidative dissolution of chromium from Hanford Tank sludges under alkaline conditions

1996 ◽  
Author(s):  
B.M. Rapko ◽  
G.J. Lumetta ◽  
M.J. Wagner
Keyword(s):  
Oxidative Dissolution ◽  
Alkaline Conditions

Mechanism of birnessite-promoted oxidative dissolution of antimony trioxide

2020 ◽  
Vol 17 (4) ◽  
pp. 345 ◽  
Author(s):  
Jun Shan ◽  
Xintong Ding ◽  
Mengchang He ◽  
Wei Ouyang ◽  
Chunye Lin ◽  
...  
Keyword(s):  
Release Rate ◽  
Dissolution Mechanism ◽  
Antimony Trioxide ◽  
Oxidative Dissolution ◽  
Reaction Solution ◽  
Initial Stage ◽  
Geochemical Cycle ◽  
Alkaline Conditions ◽  
Toxic Hazard ◽  
Neutral Conditions

Environmental contextThe release of antimony and its compounds to the environment can present a toxic hazard for humans. We evaluated the use of birnessite to dissolve antimony trioxide and found that birnessite accelerated the dissolution process, and ~50% of the oxidised antimony was absorbed. The results can help evaluate the bioavailability of antimony in the environment. AbstractThe most important naturally occurring forms of antimony (Sb) are the ore mineral stibnite (Sb2S3) and its principal weathering product antimony trioxide (Sb2O3). Moreover, most Sb is released into the environment as Sb2O3 from manufacturing, formulations, processing, and the use and disposal of Sb products. In this study, birnessite (δ-MnO2) was employed to promote Sb2O3 dissolution. The Sb2O3 dissolution rate accelerated from ~2% to >99% after 9 days of reaction, and more than 98% of the dissolved SbIII was oxidised into SbV in the presence of birnessite. The birnessite-promoted oxidative dissolution mechanism of Sb2O3 was studied through experiments on the effects of the reaction time and pH. The release rate of Sb in the aqueous phase at the initial stage (335.4 μmol L−1 day−1, pH 6.5) was much higher than that at the late stage (13.28 μmol L−1 day−1, pH 6.5), and when the pH increased from 4.7 to 8.0, the Sb release rate decreased from 351.2 μmol L−1 day−1 to 257.7 μmol L−1 day−1. The dissolution promotion effects of birnessite on Sb2O3 were the most evident under acidic and neutral conditions (the percentages of dissolved Sb2O3 under acidic and neutral conditions were 98.3% and 100.0% after 9 days of reaction). Not all of the produced SbV was released in the reaction solution because ~50% of it was adsorbed by birnessite, and the amount of Sb adsorbed increased with increasing pH. Therefore, alkaline conditions are shown to reduce the release of SbV by inhibiting Sb2O3 dissolution (86.7%) and enhancing SbV adsorption. These results could help clarify the geochemical cycle and fate of Sb in the environment.

A crystalline–amorphous Ni–Ni(OH)2 core–shell catalyst for the alkaline hydrogen evolution reaction

2020 ◽  
Vol 8 (44) ◽  
pp. 23323-23329
Author(s):  
Jing Hu ◽  
Siwei Li ◽  
Yuzhi Li ◽  
Jing Wang ◽  
Yunchen Du ◽  
...  
Keyword(s):  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Electrocatalytic Activity ◽  
Core Shell ◽  
Alkaline Conditions

Crystalline–amorphous Ni–Ni(OH)2 core–shell assembled nanosheets exhibit outstanding electrocatalytic activity and stability for hydrogen evolution under alkaline conditions.

Germination of leucaena and Rhodes grass seeds in saline and alkaline conditions

2016 ◽  
Vol 44 (3) ◽  
pp. 461-474 ◽  
Author(s):  
J.B. Wehr ◽  
P.M. Kopittke ◽  
S.A. Dalzell ◽  
N.W. Menzies
Keyword(s):  
Rhodes Grass ◽  
Alkaline Conditions

PHENOLIC METABOLITES OF DL-NORGESTREL: A METHOD FOR THE REMOVAL OF 1-HYDROXYLATED METABOLITES, POTENTIAL SOURCES OF PHENOLIC ARTIFACTS

1974 ◽  
Vol 76 (4) ◽  
pp. 789-800 ◽  
Author(s):  
Samuel F. Sisenwine ◽  
Ann L. Liu ◽  
Hazel B. Kimmel ◽  
Hans W. Ruelius
Keyword(s):  
Urinary Metabolites ◽  
Ion Exchange Resin ◽  
Gas Chromatography Mass Spectrometry ◽  
Phenolic Metabolites ◽  
Hydroxylated Metabolites ◽  
Analytical Work ◽  
Potential Sources ◽  
Alkaline Conditions ◽  
Artifact Formation ◽  
Work Up

ABSTRACT The identification of 1β-hydroxynorgestrel among the urinary metabolites of dl-norgestrel and the facile transformation of this compound under mild alkaline conditions to a potentially oestrogenic phenol provide an experimental basis for the conclusion advanced by others that the oestrogens present in the urine of subjects treated with synthetic progestens are artifacts formed during analytical work-up. A method has been devised which eliminates 1-hydroxylated metabolites as potential sources of phenolic artifacts. This method is based on the reduction by NaBH4 of the 1-hydroxy-4-en-3-one grouping in the A ring thereby excluding the possibility of aromatization during later fractionation on a basic ion exchange resin that separates neutral from phenolic metabolites. In the urines of women treated with 14C-dl-nogestrel, only 0.17–0.27% of the dose is found to have phenolic properties when this method is used. Two of the phenolic metabolites, 18-homoethynyloestradiol and 16β-hydroxy-18-homoethynyloestradiol, are present in amounts smaller than 0.01 % of the dose. Without the reduction steps the percentages are noticeably higher, indicating artifact formation under alkaline conditions. Similar results were obtained with urines from African Green Monkeys (Cercopithecus Aethiops) that had been dosed with 14C-dl-norgestrel. Radiolabelled 18-homoethynyloestradiol and 16β-hydroxy-18-homoethynyloestradiol were isolated from monkey urine and their identity confirmed by gas chromatography-mass spectrometry.

Screening of an Alkaline CMCase-Producing Strain and the Optimization of its Fermentation Condition

2020 ◽  
Vol 21 (13) ◽  
pp. 1304-1315
Author(s):  
Junmei Zhou ◽  
Lianghong Yin ◽  
Chenbin Wu ◽  
Sijia Wu ◽  
Jidong Lu ◽  
...  
Keyword(s):  
Bacterial Isolate ◽  
Ammonium Oxalate ◽  
Fermentation Condition ◽  
Bivalent Cations ◽  
Rdna Sequencing ◽  
Optimum Ph ◽  
Alkaline Conditions ◽  
Fermentation Parameters ◽  
Pulp And Paper Industries ◽  
Central Composite

Objective: Alkaline Carboxymethyl Cellulase (CMCase) is an attractive enzyme for the textile, laundry, pulp, and paper industries; however, commercial preparations with sufficient activity at alkaline conditions are scarce. Methods: High CMCase-producing bacterial isolate, SX9-4, was screened out from soil bacteria, which was identified as Flavobacterium sp. on the basis of 16S rDNA sequencing. Results: The optimum pH and temperature for CMCase reaction were 8.0 and 55°C, respectively. Alkaline CMCase was stable over wide pH (3.0-10.6) and temperature (25-55°C) ranges. Enzyme activity was significantly inhibited by the bivalent cations Mn2+ and Cu2+, and was activated by Fe2+. To improve the alkaline CMCase production of SX9-4, fermentation parameters were selected through onefactor- at-a-time and further carried out by response surface methodologies based on a central composite design. Conclusion: High CMCase production (57.18 U/mL) was achieved under the optimal conditions: 10.53 g/L carboxymethylcellulose sodium, 7.74 g/L glucose, 13.71 g/L peptone, and 5.27 g/L ammonium oxalate.

Kinetic Behaviour of Amylase According to pH: A New Perspective for Starch Hydrolysis Process

2020 ◽  
Vol 16 (2) ◽  
pp. 135-144
Author(s):  
Ravneet K. Grewal ◽  
Baldeep Kaur ◽  
Gagandeep Kaur
Keyword(s):  
Metal Ions ◽  
Competitive Inhibition ◽  
Deae Cellulose ◽  
Kinetic Studies ◽  
Cost Effective ◽  
Starch Hydrolysis ◽  
Divalent Metal Ions ◽  
Activity Data ◽  
Time Saving ◽  
Alkaline Conditions

Background: Amylases are the most widely used biocatalysts in starch saccharification and detergent industries. However, commercially available amylases have few limitations viz. limited activity at low or high pH and Ca2+ dependency. Objective: The quest for exploiting amylase for diverse applications to improve the industrial processes in terms of efficiency and feasibility led us to investigate the kinetics of amylase in the presence of metal ions as a function of pH. Methods: The crude extract from soil fungal isolate cultures is subjected to salt precipitation, dialysis and DEAE cellulose chromatography followed by amylase extraction and is incubated with divalent metal ions (i.e., Ca2+, Fe2+, Cu2+, and Hg2+); Michaelis-Menton constant (Km), and maximum reaction velocity (Vmax) are calculated by plotting the activity data obtained in the absence and presence of ions, as a function of substrate concentration in Lineweaver-Burk Plot. Results: Kinetic studies reveal that amylase is inhibited un-competitively at 5mM Cu2+ at pH 4.5 and 7.5, but non-competitively at pH 9.5. Non-competitive inhibition of amylase catalyzed starch hydrolysis is observed with 5mM Hg2+ at pH 9.5, which changes to mixed inhibition at pH 4.5 and 7.5. At pH 4.5, Ca2+ induces K- and V-type activation of amylase catalyzed starch hydrolysis; however, the enzyme has V-type activation at 7mM Ca2+ under alkaline conditions. Also, K- and V-type of activation of amylase is observed in the presence of 7mM Fe2+ at pH 4.5 and 9.5. Conclusion: These findings suggest that divalent ions modulation of amylase is pH dependent. Furthermore, a time-saving and cost-effective solution is proposed to overcome the challenges of the existing methodology of starch hydrolysis in starch and detergent industries.

scholarly journals Robust Carbon-Stabilization of Few-Layer Black Phosphorus for Superior Oxygen Evolution Reaction

Coatings ◽  
2020 ◽  
Vol 10 (7) ◽  
pp. 695 ◽  
Author(s):  
Mengjie Zhang ◽  
Wenchang Zhu ◽  
Xingzhe Yang ◽  
Meng Feng ◽  
Hongbin Feng
Keyword(s):  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Black Phosphorus ◽  
Carbon Stabilization ◽  
High Durability ◽  
Carbon Coated ◽  
Alkaline Conditions ◽  
Doped Graphene ◽  
A Current

Few-layer exfoliated black phosphorus (Ex-BP) has attracted tremendous attention owing to its promising applications, including in electrocatalysis. However, it remains a challenge to directly use few-layer Ex-BP as oxygen-involved electrocatalyst because it is quite difficult to restrain structural degradation caused by spontaneous oxidation and keep it stable. Here, a robust carbon-stabilization strategy has been implemented to prepare carbon-coated Ex-BP/N-doped graphene nanosheet (Ex-BP/NGS@C) nanostructures at room temperature, which exhibit superior oxygen evolution reaction (OER) activity under alkaline conditions. Specifically, the as-synthesized Ex-BP/NGS@C hybrid presents a low overpotential of 257 mV at a current density of 10 mA cm−2 with a small Tafel slope of 52 mV dec−1 and shows high durability after long-term testing.

Degradation of Organic Cations under Alkaline Conditions

2020 ◽  
Vol 86 (1) ◽  
pp. 254-263
Author(s):  
Wei You ◽  
Kristina M. Hugar ◽  
Ryan C. Selhorst ◽  
Megan Treichel ◽  
Cheyenne R. Peltier ◽  
...  
Keyword(s):  
Organic Cations ◽  
Alkaline Conditions
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