scholarly journals Fabrication of Pd/Pd-Alloy Films by Surfactant Induced Electroless Plating for Hydrogen Separation from Advanced Coal Gasification Processes

2012 ◽  
Author(s):  
Shamsuddin Ilias ◽  
Dhananjay Kumar
Keyword(s):  
Electroless Plating ◽  
Coal Gasification ◽  
Hydrogen Separation ◽  
Alloy Films ◽  
Pd Alloy

scholarly journals Development of Pd Alloy Hydrogen Separation Membranes with Dense/Porous Hybrid Structure for High Hydrogen Perm-Selectivity

2014 ◽  
Vol 2014 ◽  
pp. 1-10 ◽  
Author(s):  
Jae-Yun Han ◽  
Chang-Hyun Kim ◽  
Sang-Ho Kim ◽  
Dong-Won Kim
Keyword(s):  
Composite Membranes ◽  
Hybrid Structure ◽  
Hydrogen Separation ◽  
Membrane Thickness ◽  
High Hydrogen ◽  
Alloy Films ◽  
Separation Membranes ◽  
Metal Support ◽  
Pd Alloy ◽  
Hydrogen Selectivity

For the commercial applications of hydrogen separation membranes, both high hydrogen selectivity and permeability (i.e., perm-selectivity) are required. However, it has been difficult to fabricate thin, dense Pd alloy composite membranes on porous metal support that have a pore-free surface and an open structure at the interface between the Pd alloy films and the metal support in order to obtain the required properties simultaneously. In this study, we fabricated Pd alloy hydrogen separation membranes with dense/porous hybrid structure for high hydrogen perm-selectivity. The hydrogen selectivity of this membrane increased owing to the dense and pore-free microstructure of the membrane surface. The hydrogen permeation flux also was remarkably improved by the formation of an open microstructure with numerous open voids at the interface and by an effective reduction in the membrane thickness as a result of the porous structure formed within the Pd alloy films.

XPS studies on the electronic structures of sputter-deposited and hydrogenated Ti-Pd alloy films

1990 ◽  
Vol 117-118 ◽  
pp. 429-432 ◽  
Author(s):  
Kazuhide Tanaka ◽  
Masanori Ushida ◽  
Kenji Sumiyama ◽  
Yoji Nakamura
Keyword(s):  
Electronic Structures ◽  
Alloy Films ◽  
Pd Alloy ◽  
Sputter Deposited

Pure Ni and Pd-Ni Alloy Membranes Prepared by Electroless Plating for Hydrogen Separation

2011 ◽  
Vol 179-180 ◽  
pp. 1309-1313 ◽  
Author(s):  
Xiao Liang Zhang ◽  
Xu Feng Xie ◽  
Yan Huang
Keyword(s):  
Electroless Plating ◽  
Hydrogen Permeation ◽  
Hydrogen Permeability ◽  
Composite Membranes ◽  
Hydrogen Separation ◽  
High Hydrogen ◽  
Ni Alloy ◽  
Plating Method ◽  
Fcc Phase ◽  
The Ideal

Pd-based composite membranes are the attractive membrane materials for hydrogen separation due to their high hydrogen permeability and infinite permselectivity. Thin pure Ni and Pd-Ni alloy membranes with high hydrogen permeation were prepared by the electroless plating method. It is difficult to prepare the dense pure Ni membranes with 1-2 μm thickness for hydrogen separation. However, Pd-Ni alloy membranes with several micrometers thickness showed good permeation performance. Hydrogen permeance of the Pd95Ni5 alloy membrane with fcc phase up to 3.1×10-6 mol/m2 s Pa and the ideal permselectivity over 600 were obtained at 773 K.

Pd-Alloy membranes for hydrogen separation

2014 ◽  
pp. 135-161 ◽  
Author(s):  
James B. Miller ◽  
Bryan D. Morreale ◽  
Mark W. Smith
Keyword(s):  
Hydrogen Separation ◽  
Pd Alloy

Evaluation and characterization of Pd-Ag composite membrane fabricated by surfactant induced electroless plating (SIEP) for hydrogen separation

2019 ◽  
Vol 54 (13) ◽  
pp. 2084-2097 ◽  
Author(s):  
M. M. Rahman ◽  
M. S. Islam ◽  
M. A. Rahman ◽  
H. Tun ◽  
V. Deshmane ◽  
...  
Keyword(s):  
Composite Membrane ◽  
Electroless Plating ◽  
Hydrogen Separation

Preparation of Pd-Cu-Ce Hydrogen Separation Membrane Alloys

2014 ◽  
Vol 672-674 ◽  
pp. 661-664
Author(s):  
Hai Zhao ◽  
Jun Qing Liu
Keyword(s):  
Composite Membrane ◽  
Electroless Plating ◽  
Hydrogen Separation ◽  
Exposure Level ◽  
Plating Technique ◽  
Separation Membrane ◽  
Effects Of Temperature ◽  
Temperature And Pressure ◽  
Hydrogen Separation Membrane

Pd-Cu-Ce composite membrane was prepared using an electroless plating technique. The effects of temperature and pressure on permeation were studied. The resistance to sulfidation was examined by exposing alloys to simulated syngas containing a combined gas of H2 and H2S. The alloys showed sings of slight sufidation at the 0.1% H2S exposure level.

Impact of Microstructure of Alternative Al-Si-V-Pd Alloy Films on Interconnect Reliability, Compared to Al-Si-Cu

1994 ◽  
Vol 337 ◽  
Author(s):  
A.G. Dirks ◽  
R.A. Augur ◽  
S. Kordić ◽  
R.A.M. Wolters
Keyword(s):  
Grain Boundaries ◽  
Integrated Circuit ◽  
Void Formation ◽  
Quaternary Alloy ◽  
Alloy Films ◽  
Cu Alloy ◽  
Transmission Electron ◽  
Pd Alloy ◽  
Interconnect Reliability ◽  
Key Issues

ABSTRACTDifficulty during plasma etching and post-etch corrosion are major drawbacks of Al-Si-Cu alloy films, when used for integrated circuit interconnect. Moreover, the relatively large solute mobility of Cu in Al may lead to void formation by precipitate coarsening. As integrated circuit dimensions decrease reliability issues, such as electromigration and mechanical stress voiding, are becoming increasingly important. At present several types of Al alloys are considered as possible alternatives for Al-Si-Cu: Al-Pd, Al-Sc, Al-Pd-Cu, Al-Si-Pd, Al-Si-V, Al-Si-Sc, Al-Si-Pd-Nb, and Al-Si-V-Pd. The latter quaternary alloy has been designed such as to combine the positive aspects of both Pd and V. In comparison with Cu in Al, a) the (low temperature) solid solubility is negligible for Pd and small for V, and b) the mobility is similar for Pd, but very small for V.With transmission-electron microscopy, passivated Al-Si-Cu alloy films have been studied after thermal stressing at 200 °C: ө-Al2Cu coarsening was observed together with void condensation. Lifetests on unpassivated Al-Si-V-Pd alloys at 180 °C and 2xl06A/cm2 have shown an extremely high resistance to electromigration. Electromigration and microstructural data on these quaternary alloys will be presented. These findings suggest how the microstructure is stabilized by the combined action of the V and Pd solute atoms, a) by nm-scale (A1,V) precipitates within the Al grains and b) by small (Al,Pd) particles at the Al grain boundaries. Furthermore, the key issues in terms of reliability related microstructural phenomena are both solute and solvent mobilities in grain interiors as well as along interfaces and grain boundaries. Arguments will be given showing that at low solute concentrations the metals (V and Pd) each by themselves are not effective enough to influence the solvent motion of aluminium along interfaces and grain boundaries significantly. The combination of the two metals, however, was found to be very effective.

Preparation of palladium membrane by bio-membrane assisted electroless plating for hydrogen separation

2014 ◽  
Vol 39 (13) ◽  
pp. 7069-7076 ◽  
Author(s):  
Yu Guo ◽  
Hongye Zou ◽  
Hongmei Wu ◽  
Lidai Zhou ◽  
Haiou Liu ◽  
...  
Keyword(s):  
Electroless Plating ◽  
Hydrogen Separation ◽  
Palladium Membrane
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