scholarly journals Evaluation of Glass Density to Support the Estimation of Fissile Mass Loadings from Iron Concentrations in SB6 Glasses

2010 ◽  
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D. Peeler
2014 ◽  
Vol 13 (4) ◽  
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Sonila Llupo ◽  
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...  

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Arunee Jetsrisuparb

1998 ◽  
Vol 248 (1) ◽  
pp. 5-8 ◽  
Author(s):  
Majidah Shadid ◽  
Giuseppe Buonocore ◽  
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PLoS ONE ◽  
2014 ◽  
Vol 9 (3) ◽  
pp. e93549 ◽  
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1976 ◽  
Vol 29 (10) ◽  
pp. 2149 ◽  
Author(s):  
RJ Atkinson

FeC2O4,2H2O(s) suspensions in sodium hydroxide solutions were oxidized by a fast air-bubble flow at room temperature until complete reaction had occurred. With amounts of NaOH in the range OH/Fe initial mole ratio ≤1.0, the reaction is FeC2O4, 2H2(s)+ OH-(aq)+ �O2(g) → ⅔γFeOOH(s)+1/3Fe(C2O4)33-(aq)+13/6H2O With OH/Fe mole ratio ≥ 2.0 the reaction is FeC2O4, 2H2(s)+ 2OH-(aq)+ �O2(g) → αFeOOH(s)+(C2O4)33-(aq)+ 5/2 H2O Mixtures of goethite (α-FeOOH) and lepidocrocite (γ-FeOOH) form at intermediate OH/Fe mole ratio. The oxidation process occurs in a solid-phase intermediate product. Comparisons with similar oxidations of iron(11)sulphate solutions showed that γ-FeOOH formation was favoured and α-FeOOH formation inhibited in the iron(11) oxalate oxidation. These differences are related to pH and dissolved iron concentrations.


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