scholarly journals A soil column study to evaluate treatment of trace elements from saline industrial wastewater

2017 ◽  
Vol 76 (10) ◽  
pp. 2698-2709 ◽  
Author(s):  
Jose M. Paredez ◽  
Natalie Mladenov ◽  
Madhubhashini B. Galkaduwa ◽  
Ganga M. Hettiarachchi ◽  
Gerard J. Kluitenberg ◽  
...  
Keyword(s):  
Trace Elements ◽  
Organic Carbon ◽  
Industrial Wastewater ◽  
High Salinity ◽  
Soil Column ◽  
Spectroscopic Properties ◽  
Flue Gas Desulfurization ◽  
Column Study ◽  
Reducing Conditions ◽  
Subsurface Treatment

Abstract Industrial wastewater from the flue gas desulfurization (FGD) process is characterized by the presence of trace elements of concern, such as selenium (Se) and boron (B) and relatively high salinity. To simulate treatment that FGD wastewater undergoes during transport through soils in subsurface treatment systems, a column study (140-d duration) was conducted with native Kansas soil and saline FGD wastewater, containing high Se and B concentrations (170 μg/L Se and 5.3 mg/L B) and negligible arsenic (As) concentration (∼1.2 μg/L As). Se, B, and As, and dissolved organic carbon concentrations and organic matter spectroscopic properties were measured in the influent and outflow. Influent Se concentrations were reduced by only ∼half in all treatments, and results suggest that Se sorption was inhibited by high salinity of the FGD wastewater. By contrast, relative concentrations (C/Co) of B in the outflow were typically <10%, suggesting that B sequestration may have been enhanced by higher salinity. Unexpected elevated As concentrations in the outflow (at >150 μg/L in the treatment with labile organic carbon addition) suggest that soils not previously known to be geogenic arsenic sources have the potential to release As to groundwater in the presence of high salinity wastewater and under reducing conditions.

Biological Treatment of a High Salinity Chemical Industrial Wastewater

1993 ◽  
Vol 27 (7-8) ◽  
pp. 105-112 ◽  
Author(s):  
Shimshon Belkin ◽  
Asher Brenner ◽  
Aharon Abeliovich
Keyword(s):  
Activated Carbon ◽  
Organic Carbon ◽  
Dissolved Organic Carbon ◽  
Salt Concentration ◽  
Industrial Wastewater ◽  
Biological Treatment ◽  
High Salinity ◽  
Laboratory Bench ◽  
Wastewater Stream ◽  
Scale Reactor

Various laboratory-scale process configurations were tested for the biological treatment of a combined wastewater stream of several chemical factories. The untreated wastewaters, rich in halogenated organics (1250±389 mg/l DOC), were also highly saline (32±11 g/liter TDS 550°C) and toxic (Microtox™ EC50 = 1.5±2.0%). Biphasic (anaerobic/aerobic) laboratory bench-scale reactor systems yielded reduction of dissolved organic carbon by 70 to 84%, in the absence and presence of powdered activated carbon, respectively. The anaerobic phase proved to be essential in all systems, both for dissolved organic carbon removal and for detoxification. Similar efficiencies were obtained in either activated sludge or aerated lagoon type reactors, but in the latter case, longer hydraulic retention times were required. DOC removal was found to decrease with increased salt concentration; however, a 50% efficiency was achieved even at 90 g/l TDS. Toxicity elimination as judged by the Microtox™ assay was highly variable in the absence of activated carbon but stable and efficient in its presence.

Enzymatic biodegradation of highly p-xylene contaminated soil using cold-active enzymes: A soil column study

2021 ◽  
pp. 127099
Author(s):  
Saba Miri ◽  
Seyyed Mohammadreza Davoodi ◽  
Thomas Robert ◽  
Satinder Kaur Brar ◽  
Richard Martel ◽  
...  
Keyword(s):  
Contaminated Soil ◽  
Soil Column ◽  
Column Study ◽  
Cold Active Enzymes ◽  
Cold Active

scholarly journals Chemical characterization of fine particular matter in Changzhou, China and source apportionment with offline aerosol mass spectrometry

2016 ◽  
Author(s):  
Zhaolian Ye ◽  
Jiashu Liu ◽  
Aijun Gu ◽  
Feifei Feng ◽  
Yuhai Liu ◽  
...  
Keyword(s):  
Trace Elements ◽  
Organic Matter ◽  
Organic Carbon ◽  
Source Apportionment ◽  
Major Ions ◽  
Chemical Properties ◽  
Chemical Characterization ◽  
Water Soluble ◽  
Traffic Emissions ◽  
Aerosol Mass

Abstract. Knowledge on aerosol chemistry in densely populated regions is critical for reduction of air pollution, while such studies haven't been conducted in Changzhou, an important manufacturing base and polluted city in the Yangtze River Delta (YRD), China. This work, for the first time, performed a thorough chemical characterization on the fine particular matter (PM2.5) samples, collected during July 2015 to April 2016 across four seasons in Changzhou city. A suite of analytical techniques were employed to characterize organic carbon / elemental carbon (OC / EC), water-soluble organic carbon (WSOC), water-soluble inorganic ions (WSIIs), trace elements, and polycyclic aromatic hydrocarbons (PAHs) in PM2.5; in particular, an Aerodyne soot particle aerosol mass spectrometer (SP-AMS) was deployed to probe the chemical properties of water-soluble organic aerosols (WSOA). The average PM2.5 concentrations were found to be 108.3 μg m−3, and all identified species were able to reconstruct ~ 80 % of the PM2.5 mass. The WSIIs occupied about half of the PM2.5 mass (~ 52.1 %), with SO42−, NO3− and NH4+ as the major ions. On average, nitrate concentrations dominated over sulfate (mass ratio of 1.21), indicating influences from traffic emissions. OC and EC correlated well with each other and the highest OC / EC ratio (5.16) occurred in winter, suggesting complex OC sources likely including both secondarily formed and primarily emitted OA. Concentrations of eight trace elements (Mn, Zn, Al, B, Cr, Cu, Fe, Pb) can contribute up to 6.0 % of PM2.5 during winter. PAHs concentrations were also high in winter (140.25 ng m−3), which were predominated by median/high molecular weight PAHs with 5- and 6-rings. The organic matter including both water-soluble and water-insoluble species occupied ~ 20 % PM2.5 mass. SP-AMS determined that the WSOA had an average atomic oxygen-to-carbon (O / C), hydrogen-to-carbon (H / C), nitrogen-to-carbon (N / C) and organic matter-to-organic carbon (OM / OC) ratios of 0.36, 1.54, 0.11, and 1.74, respectively. Source apportionment of WSOA further identified two secondary OA (SOA) factors (a less oxidized and a more oxidized OA) and two primary OA (POA) factors (a nitrogen enriched hydrocarbon-like traffic OA and a cooking-related OA). On average, the POA contribution overweighed SOA (55 % vs. 45 %), indicating the important role of local anthropogenic emissions to the aerosol pollution in Changzhou. Our measurement also shows the abundance of organic nitrogen species in WSOA, and the source analyses suggest these species likely associated with traffic emissions, which warrants more investigations on PM samples from other locations.

scholarly journals Influence of Bottom Sediments Physicochemical Characteristics on Distribution of Microelements in the Crimean Shelf Water Areas

2020 ◽  
Author(s):  
E. A. Kotelyanets ◽  
K. I. Gurov ◽  
◽  
Keyword(s):  
Heavy Metals ◽  
Trace Elements ◽  
Spatial Distribution ◽  
Organic Carbon ◽  
Bottom Sediments ◽  
Clay Fraction ◽  
Zinc Content ◽  
Physicochemical Characteristics ◽  
Water Area ◽  
Pollution Level

The paper presents the results of studies of the Kalamitsky Bay bottom sediments pollution level with microelements and heavy metals (Pb, Zn, Cu, Ni, Co, Cr, V, As, Sr, Ti, Fe, Mn) in comparison with the content of these microelements and heavy metals in the Balaklava Bay sediments. The paper analyzes data obtained during expeditions on the R/V Professor Vodyanitsky in the Kalamitsky Gulf in August 2011 (seaward part) and on the R/V Rioni in September 2012 (coastal area) as well as in the Balaklava Bay in October 2018. Content of microelements and heavy metals in bottom sediments of the studied water areas was determined by the X-ray fluorescence method using Spectroscan MAX-G device. For the water area of the Kalamitsky Gulf, the features of the studied trace element spatial distribution are considered, groups of trace elements with different spatial distribution patterns are identified. The correlation analysis determined influence of physicochemical characteristics of the sediments on distribution and accumulation of trace elements. In the water area of the Kalamitsky Gulf, a statistically significant correlation was observed of nickel, iron and zinc content with the clay fraction; dependance of increased concentrations of zinc, nickel and chrome on the content of organic carbon and predominance of lead in highcarbonate sediments. For the Balaklava Bay, the maximum positive values of correlations with the pelitic-silty fraction were noted for iron, manganese, vanadium and chrome; organic carbon correlates with chrome, iron, nickel and copper, whereas carbonates correlate with strontium. Similar patterns were observed earlier in the Sevastopol region bays, Feodosiya Gulf and Kerch Strait.

scholarly journals Contents, distribution, and fractionation of soil organic carbon and trace elements in soils under a green manure application

2020 ◽  
Vol 16 (No. 1) ◽  
pp. 50-58
Author(s):  
Yana Timofeeva ◽  
Lyudmila Purtova ◽  
Alexey Emelyanov ◽  
Maxim Burdukovskii ◽  
Irina Kiseleva ◽  
...  
Keyword(s):  
Trace Elements ◽  
Organic Carbon ◽  
Soil Organic Carbon ◽  
Green Manure ◽  
Mineral Soil ◽  
Water Soluble ◽  
Household Waste ◽  
Nickel Ions ◽  
Low Degree ◽  
Soluble Components

We quantified the soluble fractions of the soil organic carbon (SOC) concentrations and the total and water-soluble trace elements in soils contaminated by household waste and remediated via the addition of green manure over 13 years and identified the main factors controlling the vertical distribution and accumulation of the trace elements. Green manure favoured the active formation of soil organic matter. The SOC of the examined soils was characterised by the active stabilisation by mineral soil compounds, but by a low degree of humification. The soils showed increased concentrations of Cr and Ni ions. The SOC and different soil compounds enriched by Si, Ca, and Mn ions were the important determinant for the distribution of Sr, V and Cu ions, as well as for the distribution of Pb and Cr ions bound to the water-soluble components of the soils. The low degree of SOC humification may be one of the main reasons of the high concentrations of Cu and Pb ions in the composition of the water-soluble soil compounds. The nickel ions were mainly associated with compounds enriched by the Al and Fe ions. The extremely high percentage concentration of the Ni ions in the water-soluble components of the soils may be result of the absence of the Ni ions adsorption by humic substances.

scholarly journals Characterization of Iron and Organic Carbon Colloids in Boreal Rivers and Their Fate at High Salinity

2020 ◽  
Vol 125 (4) ◽  
Author(s):  
Simon David Herzog ◽  
Luigi Gentile ◽  
Ulf Olsson ◽  
Per Persson ◽  
Emma Sofia Kritzberg
Keyword(s):  
Organic Carbon ◽  
High Salinity ◽  
Boreal Rivers

scholarly journals Total content of macroelements and trace elements in Holocene calcareous gyttja from the post-bog area of north-western Poland

2019 ◽  
Vol 14 (No. 1) ◽  
pp. 40-46
Author(s):  
Grzegorz Jarnuszewski ◽  
Edward Meller
Keyword(s):  
Trace Elements ◽  
Organic Carbon ◽  
Total Organic Carbon ◽  
Total Content ◽  
Major And Trace Elements ◽  
Carbonate Mineral ◽  
Minor Components ◽  
Ignition Loss ◽  
Calcareous Deposits ◽  
North Western

The study covered 6 sites located in the Vistula glaciation area in north-western Poland, where the Holocene calcareous (gyttja) deposits occur. Three types of such calcareous deposits were isolated: marly (groundwater calcretes) (CaCO<sub>3</sub> &gt; 80%, loss of ignition &lt; 20%, non-carbonate fractions &lt; 20%), calcareous gyttja (CaCO<sub>3</sub> 50–80%, loss of ignition &lt; 40%, non-carbonate fractions &lt; 40%), and clay calcareous gyttja (CaCO<sub>3</sub> 20–50%, loss of ignition &lt; 30%, non-carbonate fractions &lt; 60%). The content of major and trace elements was determined in different horizons. Several parameters of Holocene calcareous deposits were determined, namely carbonate status, total organic carbon, non-carbonate mineral fractions and several major and minor components. Close correlations between CaCO<sub>3</sub> and Ca, Mg contents, between non-carbonate fraction and K, Zn and Cu contents, as well as between ignition loss and Zn and Cu contents were observed in the sediments. The sediments exhibit vertical variability which relates to the genesis of sediments and soils. The highest content of macroelements was recorded in the uppermost layers for Ca, Mg, Na, and Mn and for microelements (trace elements) in bottom layers for S, P, K, Fe, Zn, Cu, Pb, and Ni.  

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