The adsorption and mass-transfer process of cationic red X-GRL dye on natural zeolite

2016 ◽  
Vol 73 (9) ◽  
pp. 2119-2131 ◽  
Author(s):  
Jingjing Tian ◽  
Junfang Guan ◽  
Huimin Gao ◽  
Yafei Wen ◽  
Zijie Ren

The adsorption behavior of natural zeolite was studied in order to determine the adsorption capacity and mass-transfer process of cationic red X-GRL (C18H21BrN6) onto the adsorbent. The adsorption tests to determine both the uptake capacity and the mass-transfer process at equilibrium were performed under batch conditions, which showed rapid uptake in general for the initial 5 min, corresponding to 92% total removal. The equilibrium adsorption capacity value (qe,cal) in pseudo-second-order kinetics was 13.51 mg/g at 293 K and the whole adsorption process was governed by physical adsorption with an endothermic, endothermic spontaneous nature. Adsorption tests indicated that the zeolite has great potential as an alternative low-cost material in the treatment of X-GRL drainage. However, the mass-transfer process to determine the rate-controlling steps showed that both film diffusion and pore diffusion were important in controlling the adsorption rate. The adsorption process was governed by film diffusion while pore diffusion was poor because the X-GRL molecules could not penetrate into the zeolite easily. The X-GRL molecules were only adsorbed on the external surface of the zeolite. Hence, to improve the adsorption capacity of natural zeolite further, modification to expand its micropores is necessary.

2012 ◽  
Vol 9 (1) ◽  
pp. 91-93
Author(s):  
U.R. Ilyasov ◽  
A.V. Dolgushev

The problem of volumetric thermal action on a moist porous medium is considered. Numerical solution, the influence of fluid mobility on the dynamics of the heat and mass transfer process is analyzed. It is established that fluid mobility leads to a softer drying regime. It is shown that in low-permeability media, the fluid can be assumed to be stationary.


Author(s):  
Qing-Qing Duan ◽  
Zhi-Guo Yuan ◽  
You-Zhi Liu ◽  
Shan-Shan Duan ◽  
Xi-Fan Duan

2019 ◽  
Vol 36 (1) ◽  
pp. 187-214
Author(s):  
Chao Yang ◽  
Guangsheng Luo ◽  
Xigang Yuan ◽  
Jie Chen ◽  
Yangcheng Lu ◽  
...  

Abstract This paper presents a comprehensive review of the remarkable achievements by Chinese scientists and engineers who have contributed to the multiscale process design, with emphasis on the transport mechanisms in stirred reactors, extractors, and rectification columns. After a brief review of the classical theory of transport phenomena, this paper summarizes the domestic developments regarding the relevant experiments and numerical techniques for the interphase mass transfer on the drop/bubble scale and the micromixing in the single-phase or multiphase stirred tanks in China. To improve the design and scale-up of liquid-liquid extraction columns, new measurement techniques with the combination of both particle image velocimetry and computational fluid dynamics have been developed and advanced modeling methods have been used to determine the axial mixing and mass transfer performance in extraction columns. Detailed investigations on the mass transfer process in distillation columns are also summarized. The numerical and experimental approaches modeling transport phenomena at the vicinity of the vapor-liquid interface, the point efficiency for trays/packings regarding the mixing behavior of fluids, and the computational mass transfer approach for the simulation of distillation columns are thoroughly analyzed. Recent industrial applications of mathematical models, numerical simulation, and experimental methods for the design and analysis of multiphase stirred reactors/crystallizers, extractors, and distillation columns are seen to garnish economic benefits. The current problems and future prospects are pinpointed at last.


2017 ◽  
Vol 54 (2) ◽  
pp. 463-471
Author(s):  
Guilherme Luiz Dotto ◽  
Lucas Meili ◽  
Eduardo Hiromitsu Tanabe ◽  
Daniel Padoin Chielle ◽  
Marcos Flávio Pinto Moreira

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