Treatment of hazardous landfill leachate using Fenton process followed by a combined (UASB/DHS) system

2015 ◽  
Vol 73 (7) ◽  
pp. 1700-1708 ◽  
Author(s):  
Sherif Ismail ◽  
Ahmed Tawfik
Keyword(s):  
Catalytic Oxidation ◽  
Removal Efficiency ◽  
Landfill Leachate ◽  
Oxidation Process ◽  
Uasb Reactor ◽  
Anaerobic Sludge ◽  
Combined Processes ◽  
Fenton Process ◽  
Removal Efficiencies ◽  
Pre Treatment

Fenton process for pre-treatment of hazardous landfill leachate (HLL) was investigated. Total, particulate and soluble chemical oxygen demand (CODt, CODp and CODs) removal efficiency amounted to 67%, 47% and 64%, respectively, at pH value of 3.5, molar ratio (H2O2/Fe2+) of 5, H2O2 dosage of 25 ml/L and contact time of 15 min. Various treatment scenarios were attempted and focused on studying the effect of pre-catalytic oxidation process on the performance of up-flow anaerobic sludge blanket (UASB), UASB/down-flow hanging sponge (DHS) and DHS system. The results obtained indicated that pre-catalytic oxidation process improved the CODt removal efficiency in the UASB reactor by a value of 51.4%. Overall removal efficiencies of CODt, CODs and CODp were 80 ± 6%, 80 ± 7% and 78 ± 16% for UASB/DHS treating pre-catalytic oxidation effluent, respectively. The removal efficiencies of CODt, CODs and CODp were, respectively, decreased to 54 ± 2%, 49 ± 2% and 71 ± 16% for UASB/DHS system without pre-treatment. However, the results for the combined process (UASB/DHS) system is almost similar to those obtained for UASB reactor treating pre-catalytic oxidation effluent. The DHS system achieved average removal efficiencies of 52 ± 4% for CODt, 51 ± 4% for CODs and 52 ± 15% for CODp. A higher COD fractions removal was obtained when HLL was pre-treated by Fenton reagent. The combined processes provided a removal efficiency of 85 ± 1% for CODt, 85 ± 1% for CODs and 83 ± 8% for CODp. The DHS system is not only effective for organics degradation but also for ammonia oxidation. Almost complete ammonia (NH4-N) removal (92 ± 3.6%) was occurred and the nitrate production amounted to 37 ± 6 mg/L in the treated effluent. This study strongly recommends applying Fenton process followed by DHS system for treatment of HLL.

scholarly journals Removal and Survival of Fecal Indicators in a Constructed Wetland after UASB Pre-Treatment

2021 ◽  
Vol 13 (16) ◽  
pp. 9302
Author(s):  
Fabio Conti ◽  
Elena Cristina Rada ◽  
Paolo Viotti ◽  
Massimo Raboni
Keyword(s):  
Removal Efficiency ◽  
Fecal Coliforms ◽  
Upflow Anaerobic Sludge Blanket ◽  
Uasb Reactor ◽  
Anaerobic Sludge ◽  
Experimental Plant ◽  
Fecal Indicators ◽  
Increased Risk ◽  
North Brazil ◽  
Pre Treatment

The experimentation plant, based on a sub-surface horizontal flow phytodepuration (SSHFP) unit with a pre-treatment by an upflow anaerobic sludge blanket (UASB) reactor, proved valuable in treating the sewage of a small rural community located in north Brazil. During a six-month trial, the plant achieved an average removal efficiency of 98.2% (1.74 log removal) for fecal coliforms (FC) and 96.0% (1.40 log removal) for Enterococci (EN), as well as 95.6% for BOD5, 91.0% for COD,00 and 95.4% for suspended solids (SS). The contribution of the UASB reactor to this overall performance was very significant as, alone, it achieved a yield of 62.7% for FC and 60% for EN, in addition to 65.2% for BOD5 and 65.0% for SS. EN was chosen, in addition to FC, because of its higher specificity and strong environmental persistence, leading to an increased risk to human health. In fact, the experimental results confirmed its lower removal efficiency compared to FC. The mechanical and biological mechanisms that led to such a removal efficiency of the two fecal indicators (FIs) are outlined in the article. The same mechanisms led to a good level of equivalence between the removal efficiency of the two FIs with the removal efficiency of SS and BOD5, for both the whole plant and the UASB reactor alone. The research demonstrated the close correlation between the concentrations of EN and FC for the plant effluent. This correlation can be explained by the following mathematical expression of the regression line Log EN = 0.2571 Log FC + 3.5301, with a coefficient of determination R2 = 0.912. This implies that the concentration of the more specific indicator EN could be calculated, with acceptable approximation, from the simple analysis of FC and vice versa. The experimental plant brought important health benefits to the local population. In particular, there were no significant odor emissions; moreover, the risk of fecal pathogenic diseases was drastically reduced; finally, there was no proliferation of insects and other disease vectors, due to the absence of stagnant or semi-stagnant water exposed to the atmosphere.

Impact of microaeration bioreactor on dissolved sulfide and methane removal from real UASB effluent for sewage treatment

2020 ◽  
Vol 81 (9) ◽  
pp. 1951-1960 ◽  
Author(s):  
C. S. Cabral ◽  
A. L. Sanson ◽  
R. J. C. F. Afonso ◽  
C. A. L. Chernicharo ◽  
J. C. Araújo
Keyword(s):  
Sewage Treatment ◽  
Oxygen Demand ◽  
Post Treatment ◽  
Upflow Anaerobic Sludge Blanket ◽  
Uasb Reactor ◽  
Anaerobic Sludge ◽  
Sulfide Removal ◽  
Dissolved Sulfide ◽  
Removal Efficiencies ◽  
Anaerobic Sludge Blanket

Abstract Two bioreactors were investigated as an alternative for the post-treatment of effluent from an upflow anaerobic sludge blanket (UASB) reactor treating domestic sewage, aiming at dissolved sulfide and methane removal. The bioreactors (R-control and R-air) were operated at different hydraulic retention times (HRT; 6 and 3 h) with or without aeration. Large sulfide and methane removal efficiencies were achieved by the microaerated reactor at HRT of 6 h. At this HRT, sulfide removal efficiencies were equal to 61% and 79%, and methane removal efficiencies were 31% and 55% for R-control and R-air, respectively. At an HRT of 3 h, sulfide removal efficiencies were 22% (R-control) and 33% (R-air) and methane removal did not occur. The complete oxidation of sulfide, with sulfate formation, prevailed in both phases and bioreactors. However, elemental sulfur formation was more predominant at an HRT of 6 h than at an HRT of 3 h. Taken together, the results show that post-treatment improved the anaerobic effluent quality in terms of chemical oxygen demand and solids removal. However, ammoniacal nitrogen was not removed due to either the low concentration of air provided or the absence of microorganisms involved in the nitrogen cycle.

Anaerobic pre-treatment of petrochemical effluents: terephthalic acid wastewater

1997 ◽  
Vol 36 (2-3) ◽  
pp. 237-248 ◽  
Author(s):  
Robbert Kleerebezem ◽  
Joost Mortier ◽  
Look W. Hulshoff Pol ◽  
Gatze Lettinga
Keyword(s):  
Acetic Acid ◽  
Benzoic Acid ◽  
Terephthalic Acid ◽  
Anaerobic Degradation ◽  
Anaerobic Treatment ◽  
High Rate ◽  
Uasb Reactor ◽  
Anaerobic Sludge ◽  
Pre Treatment ◽  
Uasb Reactors

During petrochemical production of purified terephthalic acid (PTA, 1,4-benzene dicarboxylic acid), a large quantity of concentrated effluent is produced. Main polluting compounds in this wastewater are terephthalic acid, acetic acid and benzoic acid in decreasing order of concentration. Acetic acid and benzoic acid are known to be rapidly degraded in high rate anaerobic treatment systems, such as Upflow Anaerobic Sludge Bed (UASB) reactors. Concerning the kinetics of anaerobic mineralization of terephthalic acid, however, no information is available in literuature. Therefore our work focused on the anaerobic degradation of neutralized terephthalic acid (disodium terephthalate) in laboratory scale UASB-reactors and batch reactors. It was found that high rate anaerobic treatment of terephthalate was difficult to obtain due to the low growth rate (μ ≈ 0.04 day−1) of the terephthalate mineralizing mixed culture. The maximum removal capacity of a lab-scale UASB-reactor was found to be 3.9 g COD.1−1 .day−1 at a loading rate of 4.5 g COD.1−1 .day−1 and a hydraulic retention time of 24 hours. Terephthalate was used as sole carbon source during these experiments. Addition of small amounts of sucrose (co-substrate) to the influent, as a source of reducing equivalents, was found to have a negative influence on the anaerobic degradation of terephthalate. Also benzoate was found to inhibit the mineralization of terephthalate. Batch-toxicity experiments showed that terephthalate is not toxic to any of the species involved in its mineralization. Based on these observations, a staged anaerobic reactor system is suggested for the anaerobic pre-treatment of PTA-wastewater.

Degradation of xenobiotic substances using sulfate-reducing bacteria in a UASB reactor

2004 ◽  
Vol 48 (11-12) ◽  
pp. 227-234 ◽  
Author(s):  
S. Tsuneda ◽  
T. Shiono ◽  
K. Nakamura ◽  
T. Dogan ◽  
A. Hirata
Keyword(s):  
Removal Efficiency ◽  
Yeast Extract ◽  
Sulfate Reducing Bacteria ◽  
Upflow Anaerobic Sludge Blanket ◽  
Uasb Reactor ◽  
Ozone Treatment ◽  
Anaerobic Sludge ◽  
Equivalent Diameter ◽  
Sulfate Reducing ◽  
Reducing Bacteria

An upflow anaerobic sludge blanket (UASB) reactor was successfully applied to continuous degradation of ferric ethylene diamine tetraacetate (Fe-EDTA) as a typical xenobiotic substance contained in photo-processing wastewater. The sludge in the UASB reactor had an abundance of sulfate-reducing bacteria (SRB), which had been anaerobically cultivated in a sulfate-rich culture medium including Fe-EDTA and yeast-extract as the carbon sources. Since the prominent reductions of Fe-EDTA and sulfate ion were observed, the contribution of SRB to Fe-EDTA degradation in the UASB reactor was confirmed. The aggregated sludge in the UASB reactor became gradually large reaching steady state with an equivalent diameter of 60-90 μm after 124 days operation. An increase of the amount of yeast extract addition to feed solution improved the Fe-EDTA removal efficiency up to 90%. Moreover, the combination of ozone treatment with SRB treatment further improved removal efficiency of total organic carbon (TOC) in an actual photo-processing wastewater composed of fixing and developing wastes.

Study on Granulation of Anaerobic Sludge in UASB Reactor Adding Cationic Polymer Treating Low Strength Wastewater at Room Temperature

2011 ◽  
Vol 71-78 ◽  
pp. 2974-2977 ◽  
Author(s):  
Zong Lian She ◽  
Jian Wu ◽  
Xiao Hui Fu ◽  
En Shi ◽  
Bao Shi Li ◽  
...  
Keyword(s):  
Removal Efficiency ◽  
Room Temperature ◽  
Control Experiment ◽  
Cationic Polymer ◽  
Cod Removal ◽  
Uasb Reactor ◽  
Anaerobic Sludge ◽  
Cod Removal Efficiency ◽  
Low Strength ◽  
To Receive

Effect of cationic polymer on granulation and COD removal efficiency in lab scale UASB reactors was examined, treating low-strength wastewater (COD 300-500mg l-1) at room temperature. It was shown that cationic polymer was more effective for enhancing sludge granulation and COD removal efficiency as compared to the control experiment (without additives). After day 166 of operation, the amount of granules size above 0.5mm accounted for 32.1% of total sludge, higher than that of control experiment (19.3%). At 1.03 kg COD m-3 d-1 of OLR and 9.8 h of HRT, the effluent VFA had a maximum value of 168mg l-1 and 240mg l-1 in Reactor A and B respectively. The polymer-amended reactor took 36days to receive 1.44 kg COD m-3 d-1 of OLR at the 7.8 h of HRT, shorter than the control reactor (54days). The two reactors obtained above 80% in COD removal efficiency. It is shown that UASB reactor can also achieve higher COD removal treating low strength wastewater at room temperature.

scholarly journals Black water treatment by an upflow anaerobic sludge blanket (UASB) reactor: a pilot study

2019 ◽  
Vol 80 (8) ◽  
pp. 1505-1511 ◽  
Author(s):  
Nathalie Dyane Miranda Slompo ◽  
Larissa Quartaroli ◽  
Grietje Zeeman ◽  
Gustavo Henrique Ribeiro da Silva ◽  
Luiz Antonio Daniel
Keyword(s):  
Removal Efficiency ◽  
Phase 1 ◽  
Oxygen Demand ◽  
Upflow Anaerobic Sludge Blanket ◽  
Uasb Reactor ◽  
Organic Loading Rate ◽  
Anaerobic Sludge ◽  
Phase 3 ◽  
Black Water ◽  
Anaerobic Sludge Blanket

Abstract Decentralized sanitary wastewater treatment has become a viable and sustainable alternative, especially for developing countries and small communities. Besides, effluents may present variations in chemical oxygen demand (COD), biochemical oxygen demand (BOD) and total nitrogen values. This study describes the feasibility of using a pilot upflow anaerobic sludge blanket (UASB) reactor to treat wastewater with different organic loads (COD), using black water (BW) and sanitary wastewater, in addition to its potential for preserving nutrients for later recovery and/or reuse. The UASB reactor was operated continuously for 95 weeks, with a hydraulic retention time of 3 days. In Phase 1, the reactor treated simulated BW and achieved 77% CODtotal removal. In Phase 2, treating only sanitary wastewater, the CODtotal removal efficiency was 60%. Phase 3 treated simulated BW again, and CODtotal removal efficiency was somewhat higher than in Phase 1, reaching 81%. In Phase 3, the removal of pathogens was also evaluated: the efficiency was 1.96 log for Escherichia coli and 2.13 log for total coliforms. The UASB reactor was able to withstand large variations in the organic loading rate (0.09–1.49 kg COD m−3 d−1), in continuous operation mode, maintaining a stable organic matter removal.

Equalization characteristics of an upflow sludge blanket – aerated biofilter (USB-AF) system

2005 ◽  
Vol 51 (10) ◽  
pp. 301-310 ◽  
Author(s):  
H.-B. Jun ◽  
S.-M. Park ◽  
J.-K. Park ◽  
S.-H. Lee
Keyword(s):  
Organic Matter ◽  
Removal Efficiency ◽  
Particulate Organic Matter ◽  
Domestic Sewage ◽  
Organic Load ◽  
Major Constituent ◽  
Anaerobic Sludge ◽  
Recycle Ratio ◽  
Particle Counts ◽  
Removal Efficiencies

Equalization characteristics of the upflow sludge blanket – aerated bio-filter (USB-AF) were investigated with the fluctuated raw domestic sewage. Recycle of nitrified effluent from AF to USB triggered the equalization characteristics of the sludge blanket on both soluble and particulate organic matter. Increment of EPS in sludge blanket by nitrate recycle was detected and removal of turbidity and particulates increased at higher recycle ratios by bio-flocculation. Increased TCOD removal in the USB was due to both denitrification of recycled nitrate and entrapment of the particulate organic matter in sludge blanket. Capture of both soluble and particulate organic matter increased sludge blanket layer in the USB, which improved the reactor performances and reduced the organic load on the subsequent AF. Overall TCOD and SS removal efficiencies were about 98% and 96%, respectively in the USB-AF system. Turbidity in the USB effluent was about 44, 20 and 5.5 NTU, at recycle ratios of 0, 100 and 200%, respectively. Particle counts in the range 2–4 μm in the USB effluent were higher than those in influent without nitrate recycle, while particle counts in the range of 0.5–15 μm in the USB effluent decreased 70% at recycle ratio of 200%. The major constituent of EPS extracted from anaerobic sludge was protein and total EPS increased from 109.1 to 165.7 mg/g-VSS with nitrate recycle of 100%. Removal efficiency and concentration of T-N in the UBS-AF effluent was over 70% and below 16 mg/L, respectively.

Removal efficiency and methanogenic activity profiles in a pilot-scale UASB reactor treating settled sewage at moderate temperatures

2002 ◽  
Vol 45 (10) ◽  
pp. 243-248 ◽  
Author(s):  
L. Seghezzo ◽  
R.G. Guerra ◽  
S.M. González ◽  
A.P. Trupiano ◽  
M.E. Figueroa ◽  
...  
Keyword(s):  
Removal Efficiency ◽  
Retention Time ◽  
Sewage Treatment ◽  
Oxygen Demand ◽  
Granular Sludge ◽  
Pilot Scale ◽  
Cod Removal ◽  
Uasb Reactor ◽  
Anaerobic Sludge ◽  
Methanogenic Activity

The performance of a sewage treatment system consisting of a settler followed by an Upflow Anaerobic Sludge Bed (UASB) reactor is described. Mean ambient and sewage temperature were 16.5 and 21.6°C, respectively. Total Chemical Oxygen Demand (CODt) concentration averaged 224.2 and 152.6 mg/L, for raw and settled sewage, respectively. The effluent concentration was 68.5 mgCODt/L. Total and suspended COD removal efficiencies of approximately 70 and 80%, respectively, have been observed in the system at a mean Hydraulic Retention Time (HRT) of 2 + 5 h. Maximum COD removal efficiency was achieved in the UASB reactor when upflow velocity (Vup) was 0.43 m/h (HRT = 6 h). Mean Specific Methanogenic Activity (SMA) and Volatile Suspended Solids (VSS) concentration in the granular sludge bed were 0.11 gCOD-CH4/gVSS.d and 30.0 gVSS/Lsludge, respectively. SMA was inversely related to VSS concentration, and both parameters varied along the sludge bed height. The Solids Retention Time (SRT) in the reactor was 450 days. Sludge characteristics have not been affected by changes of up to one month in Vup in the range 0.28–0.85 m/h (HRT 3–9 h). This system or two UASB reactors in series could be an alternative for sewage treatment under moderate temperature conditions.

Low temperature treatment of domestic sewage in upflow anaerobic sludge blanket and anaerobic hybrid reactors

1999 ◽  
Vol 39 (5) ◽  
pp. 177-185 ◽  
Author(s):  
Tarek A. Elmitwalli ◽  
Marcel H. Zandvoort ◽  
Grietje Zeeman ◽  
Harry Bruning ◽  
Gatze Lettinga
Keyword(s):  
Low Temperature ◽  
Sewage Treatment ◽  
Average Diameter ◽  
Anaerobic Treatment ◽  
Domestic Sewage ◽  
Cod Removal ◽  
Upflow Anaerobic Sludge Blanket ◽  
Uasb Reactor ◽  
Anaerobic Sludge ◽  
Removal Efficiencies

The treatment of sewage at a temperature of 13°C was investigated in three reactors (each 3.84 litre) a UASB and two anaerobic hybrid (AH) reactors with small sludge granules with an average diameter of 0.73 mm. The media used in the AH reactors were vertical polyurethane foam sheets. The reactors were operated at a HRT of 8 h. The use of small sludge granules and operating the reactors at low upflow velocity (1.8 m/d) improved suspended COD removal efficiencies for the UASB reactor. Moreover, the use of sheets in the AH reactors significantly increased suspended COD removal efficiencies as compared to the UASB and reached to 87% for pre-settled sewage treatment. The treatment of pre-settled sewage instead of raw sewage in AH reactors significantly increased colloidal and dissolved COD removal efficiencies with 13% and 12% respectively and colloidal COD removal efficiency for the UASB reactor with 13%. At ‘steady state’ for pre-settled sewage treatment, the AH reactors removed 64% of the total COD which is significantly higher by 4% than the UASB reactor. Therefore, the anaerobic treatment of domestic sewage at low temperature can be improved by treating pre-settled sewage in shallow AH reactors containing small sludge granules.

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