Effects of sludge retention time and biosurfactant on the treatment of polyaromatic hydrocarbon (PAH) in a petrochemical industry wastewater

2011 ◽  
Vol 64 (11) ◽  
pp. 2282-2292 ◽  
Author(s):  
D. T. Sponza ◽  
O. Gok

A laboratory-scale aerobic activated sludge reactor (AASR) system was employed to investigate the effects of sludge retention time (SRT) on the removal of three polyaromatic hydrocarbons (PAHs) with low benzene rings [(acenaphthene (ACT), fluorene (FLN) and phenanthrene (PHE)] and six PAHs with high benzene rings [(benzo[b]fluoranthene (BbF), benzo[k]fluoranthene (BkF), benzo[a]pyrene (BaP), indeno[1,2,3-cd]pyrene, dibenz[a,h]anthracene (DahA), benzo[g,h,i]perylene (BghiP)] in the presence of rhamnolipid (RD), emulsan (EM) and surfactine (SR) biosurfactants. This study showed that biosurfactants enhance the PAH biodegradation by increasing the biomass growth. RD exhibits a better performance than the other biosurfactants in the removal of the chemical oxygen demand (COD) and PAHs. At a RD concentration of 15 mg/L aerobic treatment for 25 days, SRT was enough to remove over 95% of total PAHs, and CODdis. Under the same conditions 75% of COD originating from the inert organics (CODinert) and 96% of COD originating from the inert soluble microbial products (CODimp) were removed. At 25 days SRT and 15 mg/L RD concentration, about 88% of PAHs were biodegraded by the AASR system, 4% were accumulated in the system, 3% were released in the effluent, and 5% remained in the waste sludge.

2013 ◽  
Vol 67 (3) ◽  
pp. 604-611 ◽  
Author(s):  
Nadir Dizge ◽  
Derya Y. Koseoglu-Imer ◽  
Ahmet Karagunduz ◽  
Bulent Keskinler

The objective of this study was to investigate the influence of sludge retention time (SRT) on membrane bio-fouling. An activated sludge reactor was operated at three different SRTs (10, 30, and 50 days). Submerged membrane experiments were performed when the mixed liquor suspended solids (MLSS) concentration reached the steady state conditions. MLSS concentrations reached the steady state at 3,109 ± 194, 6,209 ± 123 and 6,609 ± 280 mg/L for SRTs of 10, 30 and 50 days, respectively. The total soluble microbial products (SMP) were 20.1 ± 3.7, 16.2 ± 7.2 and 28.2 ± 8.4 mg/L at SRTs of 10, 30, and 50 days, respectively. The carbohydrate concentration in the supernatant was about two times more for SRT of 10 days than that for 50 days. The total amount of extracellular polymeric substances (EPS) extracted from the flocs were approximately 74.9 ± 11.9, 67.8 ± 15.0 and 67.5 ± 17.4 mg/g MLSS at three SRTs (10, 30, and 50 days) under the same organic loading rate. The viscosity of the biomass increased with the increasing SRT. The results of flux stepping tests showed that the membrane fouling at SRT 10 days was always higher than that of 30 and 50 days. Four different microfiltration membranes (cellulose acetate, polyethersulfone, mixed ester, and polycarbonate) with three different pore sizes (0.45, 0.22, 0.10 μm) were tested. Filtration resistances were determined for each membrane. Cake resistance was observed to be the most significant fouling mechanism for all membranes.


2010 ◽  
Vol 113-116 ◽  
pp. 1424-1428
Author(s):  
Yu Tian ◽  
Lin Chen ◽  
Xin Ying Su ◽  
Chu Qing Cao

Recent trend for membrane bioreactor (MBR) operation was to apply a low sludge retention time (SRT) to decrease the fouling propensity and simplify the overall maintenance. However, the correct control and operation of MBRs under low SRT conditions were not well-established. In this study, modeling of MBR system for municipal wastewater treatment was evaluated using hybrid Activated Sludge Models 3 (ASM3), which helped in determining the control and operating strategies. The experiment-based, manual trial-and-error approach used to calibrate the hybrid ASM3 was verified to be useful for MBR modeling at 30 d sludge retention time (SRT). Furthermore, the consistency relationships among carbon oxygen demanded (COD), soluble microbial products (SMP) and mixed liquor suspended solids (MLSS) were established in the process of modeling, implying that the accurate simulation of MLSS were the prerequisites for the COD and SMP prediction.


2011 ◽  
Vol 63 (10) ◽  
pp. 2250-2254 ◽  
Author(s):  
Yuchun Su ◽  
Jill Ruhsing Pan ◽  
Chihpin Huang ◽  
Chialing Chang

In this study, the impact of sludge retention time (SRT) on sludge characteristics and microbial community and the effect on membrane fouling in membrane bioreactor (MBR) was investigated. The results show that MBR with longer SRT has less fouling propensity, in agreement with other studies, despite the fact that the MBR with longer SRT contained higher MLSS and smaller particle size. However, much more soluble microbial products (SMPs) were released in MBR with shorter SRT. More slime on the membrane surface was observed in MBR with shorter SRT while sludge cakes formed on the membrane surface in MBR with longer SRT. The results show that SMP contributes to the severe fouling observed in MBR with shorter SRT, which is in agreement with other studies showing that SMPs were the major foulants in MBR. Under different SRTs of operation, the bacterial community structures of the sludge obtained by use of polymerase chain reaction-denaturing gradient gel electrophoresis (PCR-DGGE) were almost identical, but those on the membrane surface differed substantially. It suggests that, although SRT has impact on sludge characteristics, it doesn't affect the microbial community in the suspension.


Author(s):  
Mariana Matos ◽  
Rafaela A.P. Cruz ◽  
Pedro Cardoso ◽  
Fernando Silva ◽  
Elisabete B. Freitas ◽  
...  

2006 ◽  
Vol 53 (11) ◽  
pp. 269-276 ◽  
Author(s):  
C.T. Hay ◽  
D.D. Sun ◽  
S.L. Khor ◽  
J.O. Leckie

A high strength industrial wastewater was treated using a pilot scale submerged membrane bioreactor (MBR) at a sludge retention time (SRT) of 200 d. The MBR was operated at a high sludge concentration of 20 g/L and a low F/M ratio of 0.11 during 300 d of operation. It was found that the MBR could achieve COD and TOC overall removal efficiencies at more than 99 and 98% TN removal. The turbidity of the permeate was consistently in the range of 0.123 to 0.136 NTU and colour254 absorbance readings varied from 0.0912 to 0.0962 a.u. cm−1. The sludge concentration was inversely proportional to the hydraulic retention time (HRT), yielded excellent organic removal and extremely low sludge production (0.0016 kgVSS/day).


1994 ◽  
Vol 30 (8) ◽  
pp. 45-54 ◽  
Author(s):  
O. Mizuno ◽  
Y. Y. Li ◽  
T. Noike

The effects of sulfate concentration and COD/S ratio on the anaerobic degradation of butyrate were investigated by using 2.0 L anaerobic chemostat-type reactor at 35°C. The study was conducted over a wide range of the COD/S ratio (1.5 to 148) by varying COD concentrations (2500–10000 mg/L) and sulfate concentrations (68–1667 mg-S/L) in the substrate. The sludge retention time at each COD/S ratio was changed from 5 to 20 days. The interaction between methane producing bacteria (MPB) and sulfate-reducing bacteria (SRB) was evidently influenced by COD/S ratio in the substrate. When COD/S ratio was 6.0 or more, methane production was the predominate reaction and over 80% of the total electron flow was used by MPB. At the COD/S ratio of 1.5, SRB utilzed over 50% of the total electron flow. A large amount of sulfate reduction resulted in not only the decrease of methane production, but also the rapid increase of the bacterial growth. The degradation pathway of butyrate and the composition of bacterial populations in the reactor were also dominated by COD/S ratio. In sulfate depleted condition, butyrate was degraded to methane via acetate and hydrogen by MPB. On the other hand, butyrate was firstly degraded into sulfide and acetate in sulfate rich conditions by SRB, and the produced acetate was then degraded by acetate consuming MPB and SRB. The methanogenesis from acetate was inhibited by the high concentration of sulfide.


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