Characteristics of particle-associated PAHs in a first flush of a highway runoff

2006 ◽  
Vol 53 (2) ◽  
pp. 245-251 ◽  
Author(s):  
R.K. Aryal ◽  
H. Furumai ◽  
F. Nakajima ◽  
M. Boller
Keyword(s):  
Suspended Solids ◽  
Significant Contribution ◽  
Fine Fraction ◽  
Weighted Average ◽  
Coarse Fraction ◽  
First Flush ◽  
Highway Runoff ◽  
Rainfall Events ◽  
Runoff Event ◽  
Runoff Events

Runoff monitoring of six rainfall events was carried out in a highway, Winterthur, Switzerland focusing on first flush (runoff volume up to 2.88 mm). Six runoff events were used to investigate the characteristics of particle-associated PAHs in first flush. The fine fraction (<45 μm) had a relatively higher contribution than the coarse fraction. A significant contribution of the coarse fraction was observed at some periods when the runoff flow rapidly increased. Fluctuation of PAH content during a runoff event was significant in the coarse fraction and, in contrast, the PAH content in the fine fraction was less fluctuating. The weighted average PAH content in each event ranged from 17 to 62 μg/g in total SS, from 23 to 54 μg/g in the fine fraction and from 16 to 84 μg/g in the coarse fraction. The loading of particle-associated PAHs from the first flush of highway runoff ranged from 0.06 to 0.22 g/ha in a total of 12 PAH species. Keywords First flush; highway runoff; PAH content; PAH profiles; suspended solids

Dynamic behavior of suspended pollutants and particle size distribution in highway runoff

2002 ◽  
Vol 46 (11-12) ◽  
pp. 413-418 ◽  
Author(s):  
H. Furumai ◽  
H. Balmer ◽  
M. Boller
Keyword(s):  
Heavy Metals ◽  
Particle Size ◽  
Particle Size Distribution ◽  
Size Distribution ◽  
Suspended Solids ◽  
Dynamic Change ◽  
First Flush ◽  
Highway Runoff ◽  
Runoff Rate ◽  
Highway Drainage

Continuous runoff quality monitoring was conducted for one month at urban highway drainage with an area of 8.4 ha. Dynamic change of suspended solids and heavy metal concentrations were investigated during first flush periods, taking the particle size distribution into consideration. Except for Pb, the concentrations of TSS and heavy metals in runoff were within the range of the EMC reported in recent highway runoff research. Particle-bound heavy metals (Zn, Pb, and Cu) accounted for more significant pollutant loads than soluble fractions. Their content decreased with increasing total SS concentration in runoff samples. The results of particle size distribution (PSD) analysis of runoff samples indicate that high TSS concentration samples contained coarser particles. Based on the PSD results, a stepwise wash-off phenomenon of TSS under varying runoff rate conditions was explained by the different washoff behavior of fine (< 20 mm) and coarser particles.

scholarly journals Modelling of Highway Runoff Quantity and Quality

10.14311/236 ◽  
2001 ◽  
Vol 41 (3) ◽  
Author(s):  
Ashraf El-Shahat Elsayed ◽  
A. Grünwald ◽  
M. Synáčková ◽  
M. Slavíček
Keyword(s):  
Suspended Solids ◽  
Management Model ◽  
Distributed Model ◽  
Data Sets ◽  
First Flush ◽  
Runoff Simulation ◽  
Highway Runoff ◽  
Simulation Process ◽  
Spatially Distributed ◽  
Using Data

The stormwater Management Model (SWMM) is a well-known stormwater runoff-simulation model. It is a deterministic, spatially distributed model for calculation of runoff quantity and quality. The aim of this study was to predict highway runoff characteristics using data from different highway catchments. The SWMM was used in the simulation process and the predicted data was verified using monitoring data collected from Prague-Plzeň highway for both total suspended solids and organic compounds. The analyzed data indicated that the simulated TSS, BOD5 concentrations lie within the range of the measured data and both data sets are considered highly polluted with respect to the specification limits. The analyzed data also show that the first flush of runoff is the most polluted, and is responsible for contamination of retention and/or received waters.

Evaluation of factors influencing diffusion of pollutant loads in urban highway runoff

2003 ◽  
Vol 47 (7-8) ◽  
pp. 227-232 ◽  
Author(s):  
M. Shinya ◽  
K. Tsuruho ◽  
T. Konishi ◽  
M. Ishikawa
Keyword(s):  
Suspended Solids ◽  
The Other ◽  
First Flush ◽  
Flow Volume ◽  
Rainfall Condition ◽  
Pollutant Loads ◽  
Factors Influencing ◽  
Dissolved Load ◽  
Runoff Events ◽  
Cumulative Curves

Many studies have identified the first flush phenomenon and runoff characteristics. The purpose of this study is to elucidate which parameters influence the runoff pollutant loads. Eight runoff events during the period from May 1999 to September 2000 were investigated. From the dimensionless cumulative analysis, it was suggested that particulate substances such as suspended solids (SS), iron and total phosphorus (T-P) were inclined to be washed off in heavier rainfall condition. The cumulative curves of particulate constituents were appreciably variable in slope, while those of dissolved were approximately constant. Accordingly it was indicated that dissolved load was discharged regardless of rainfall conditions. Event mean runoff intensity and cumulative runoff height showed significant correlation with the cumulative runoff load of the constituents except for total nitrogen (T-N). On the other hand, antecedent dry weather period (ADWP) and traffic flow volume during ADWP did not show correlation with the cumulative runoff loads. Only T-N load showed correlation with those factors, consequently it was suggested that vehicular exhausts affected nitrogen load on the surface of urban highway.

scholarly journals First flush analysis of urban stormwater runoff from an urban catchment in Johor, Malaysia

2018 ◽  
Vol 250 ◽  
pp. 06014
Author(s):  
Noor Atiqah Zuraini ◽  
Noraliani Alias ◽  
Zainab Mohamed Yusof ◽  
Muhammad Nassir Hanapi ◽  
Sobri Harun
Keyword(s):  
Suspended Solids ◽  
Stormwater Runoff ◽  
First Flush ◽  
Storm Events ◽  
Urban Stormwater ◽  
Urban Catchment ◽  
Rainfall Events ◽  
Field Investigations ◽  
Initial Stage ◽  
Urban Stormwater Runoff

An increase of pollutants that are present in the initial stage of stormwater runoff hydrograph compared to a later stage of runoff is defined as a first flush phenomenon. This study aims to investigate the occurrence of first flush from samples of urban stormwater runoff obtained from the grounds of a University in Skudai, Johor, Malaysia. In order to achieve the study’s objective; field investigations, manual sampling of urban stormwater runoff, laboratory testing and data analysis were carried out and the evaluation of the first flush phenomenon was calculated using concentration-based first flush (CBFF) and mass-based first flush (MBFF. A total of 90 stormwater samples were collected from six (6) rainfall events and were tested for total suspended solids (TSS). For each rainfall event, the pollutographs and the dimensionless curves of the cumulative pollutant mass versus the cumulative discharged volume were plotted. The first flush coefficient was also determined in order to evaluate the occurrence of first flush. The results indicated that the storm events demonstrated a weak presence of first flush.

Characterization of suspended solids and particle-bound heavy metals in a first flush of highway runoff

2008 ◽  
Vol 9 (11) ◽  
pp. 1567-1575 ◽  
Author(s):  
Fa-hui Nie ◽  
Tian Li ◽  
Hai-feng Yao ◽  
Man Feng ◽  
Guang-kai Zhang
Keyword(s):  
Heavy Metals ◽  
Suspended Solids ◽  
First Flush ◽  
Highway Runoff

Long-term variations in individual particle types in the aerosol of Phoenix, Arizona, as determined using automated electron microprobe analysis and multivariate statistical techniques

1993 ◽  
Vol 51 ◽  
pp. 742-743
Author(s):  
Karen A. Katrinak ◽  
James R. Anderson ◽  
Peter R. Buseck
Keyword(s):  
Electron Microprobe ◽  
Fine Fraction ◽  
Coarse Fraction ◽  
Motor Vehicles ◽  
Multivariate Statistical Methods ◽  
Multivariate Statistical ◽  
X Ray ◽  
Mineral Particles ◽  
Anthropogenic Air Pollutants

Aerosol samples were collected in Phoenix, Arizona on eleven dates between July 1989 and April 1990. Elemental compositions were determined for approximately 1000 particles per sample using an electron microprobe with an energy-dispersive x-ray spectrometer. Fine-fraction samples (particle cut size of 1 to 2 μm) were analyzed for each date; coarse-fraction samples were also analyzed for four of the dates.The data were reduced using multivariate statistical methods. Cluster analysis was first used to define 35 particle types. 81% of all fine-fraction particles and 84% of the coarse-fraction particles were assigned to these types, which include mineral, metal-rich, sulfur-rich, and salt categories. "Zero-count" particles, consisting entirely of elements lighter than Na, constitute an additional category and dominate the fine fraction, reflecting the importance of anthropogenic air pollutants such as those emitted by motor vehicles. Si- and Ca-rich mineral particles dominate the coarse fraction and are also numerous in the fine fraction.

scholarly journals Aerosol characterisation including oxidative potential as a proxy of health impact

2019 ◽  
Vol 29 (2) ◽  
Author(s):  
Miroslav Josipovic ◽  
Catherine Leal-Liousse ◽  
Belinda Crobeddu ◽  
Armelle Baeza-Squiban ◽  
C. Keitumetse Segakweng ◽  
...  
Keyword(s):  
Organic Carbon ◽  
Black Carbon ◽  
Fine Fraction ◽  
Health Impact ◽  
Coarse Fraction ◽  
Dry Season ◽  
Wet Season ◽  
Oxidative Potential ◽  
Ionic Content ◽  
Vaal Triangle

This study aimed to characterise aerosols sampled in the vicinity of a major industrialised area, i.e. the Vaal Triangle. It included thedetermination of oxidative potential as a predictive indicator of particle toxicity. Aerosol samples were collated through the cascadefiltering during an eight-month period (12 h over three days in one week). Three size fractions were analysed for organic carbon(OC), black carbon (BC) and oxidative potential (OP), while ionic content was presented as monthly and seasonal concentrations. Thecontinuous measurement of black carbon by an optical attenuation instrument was collated concurrently with cascade filtering. Thecarbonaceous content was low compared to the ionic one. Within the carbonaceous concentrations, the organic carbon was higherthan concentrations of black carbon in both seasons in the ultra-fine fraction; the opposite was the case for the fine fraction, whilethe coarse fraction concentrations of organic carbon in the dry season had higher concentrations than black carbon in the wet seasonand organic carbon in the wet season. The OP tended to increase as the size was decreasing for wet season aerosols, whereas, forthe dry season, the highest OP was exerted by the fine fraction. The ultrafine fraction was the one showing the most contrasting OPbetween the two seasons. Continuous monitoring indicated that the higher BC concentrations were recorded in the dry/winter partof the year, with the daily pattern of concentrations being typically bimodal, having both the morning and evening peaks in bothseasons. Within the ionic content, the dominance of sulphate, nitrate and ammonium was evident. Multiple linear correlations wereperformed between all determined compounds. Strong correlations of carboxylic acids with other organic compounds were revealed.These acids point to emissions of VOC, both anthropogenic and biogenic. Since they were equally present in both seasons, a mixtureof sources was responsible, both present in the wider area and throughout the year.

scholarly journals ESTABLISHING THE ROTATION SPEED VARIATION RANGE LIMITS FOR AUTO-EXCITATION OF SELF-OSCILLATING GRINDING IN A TUMBLING MILL

2020 ◽  
Vol 4 ◽  
pp. 32-35
Author(s):  
Kateryna Deineka ◽  
Yurii Naumenko
Keyword(s):  
Visual Analysis ◽  
Rotation Speed ◽  
Relative Size ◽  
Fine Fraction ◽  
Coarse Fraction ◽  
The Self ◽  
Cement Clinker ◽  
Crushed Material ◽  
Degree Of Filling ◽  
Tumbling Mill

The influence of the structure of a two-fraction polygranular feed of the chamber on the value of the drum rotation speed at auto-excitation of self-excited oscillations with a maximum swing is considered. Such a pulsating mode of movement of the charge is used in the self-oscillating process of grinding in a tumbling mill. The coarse fraction simulated the grinding bodies was steel bullets with a relative size ψdb=0.026. The fine fraction, simulated the particles of the crushed material, was a cement clinker with a relative particle size ψdm=0.00013. Variable factors of experimental studies were: the degree of filling the chamber in the state of rest κbr=0.25; 0.29; 0.33 and the degree of filling the gaps between the particles of the coarse fraction with particles of the fine fraction κmbgr=0.0625; 0.375; 0.6875; 1. The method of visual analysis of transient processes of self-oscillating modes of feed behavior in the cross section of the rotating drum chamber is applied. Measurements of the speed limits of the drum rotation were carried out with auto-excitation of self-oscillations of the filling. The magnitude of the self-oscillation swing was estimated by the increase in the difference between the maximum and minimum values of the filling dilatancy for one period of pulsations. An increase in the upper limit of the speed range ψω2 with a decrease in κbr and κmbgr was established. The growth rate of ψω2 increases at low values of κbr and κmbgr. Some increase in the lower limit of the ψω1 range with a decrease in κbr and κmbgr was revealed. An increase in the range of speeds of rotation was recorded at the maximum range of self-oscillations ψω1–ψω2 with a decrease in the connected interaction of the intra-mill filling. This coherent interaction is due to an increase in κbr and κmbgr. The value of the ψω1–ψω2 range varies from 1.01–1.03 at κbr=0.33 and κmbg=1 to 1.22–1.66 at κbr=0.25 and κmbgr=0.0625. The range gets its maximum value with fine and superfine grinding

scholarly journals Investigating Subantarctic 14C Ages of Different Peat Components: Site and Sample Selection for Developing Robust Age Models in Dynamic Landscapes

Radiocarbon ◽  
2019 ◽  
Vol 61 (4) ◽  
pp. 1009-1027 ◽  
Author(s):  
Zoë A Thomas ◽  
Chris S M Turney ◽  
Alan Hogg ◽  
Alan N Williams ◽  
Chris J Fogwill
Keyword(s):  
Bulk Material ◽  
Sample Selection ◽  
Fine Fraction ◽  
Systematic Difference ◽  
Coarse Fraction ◽  
Sedimentary Sequences ◽  
Subantarctic Islands ◽  
Dynamic Landscapes ◽  
Age Model ◽  
Selection For

ABSTRACTPrecise radiocarbon (14C) dating of sedimentary sequences is important for developing robust chronologies of environmental change, but sampling of suitable components can be challenging in highly dynamic landscapes. Here we investigate radiocarbon determinations of different peat size fractions from six peat sites, representing a range of geomorphological contexts on the South Atlantic subantarctic islands of the Falklands and South Georgia. To investigate the most suitable fraction for dating, 112 measurements were obtained from three components within selected horizons: a fine fraction <0.2 mm, a coarse fraction >0.2 mm, and bulk material. We find site selection is critical, with locations surrounded by high-ground and/or relatively slowly accumulating sites more susceptible to the translocation of older carbon. Importantly, in locations with reduced potential for redeposition of material, our results show that there is no significant or systematic difference between ages derived from bulk material, fine or coarse (plant macrofossil) material, providing confidence in the resulting age model. Crucially, in areas comprising complex terrain with extreme relief, we recommend dating macrofossils or bulk carbon rather than a fine fraction, or employing comprehensive dating of multiple sedimentary fractions to determine the most reliable fraction(s) for developing a robust chronological framework.

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