Nitrate removal with low N2O emission by application of sulfur denitrification in actual agricultural field

2004 ◽  
Vol 50 (8) ◽  
pp. 145-151 ◽  
Author(s):  
K. Hasegawa ◽  
K. Shimizu ◽  
K. Hanaki

Sulfur denitrification was applied to the agricultural field and the characteristics of the treatment were evaluated from the viewpoints of nitrate removal efficiency and nitrous oxide (N2O) emission. Two actual sites where sulfur denitrification was performed were surveyed. One is a valley bottom field, where groundwater contaminated with nitrate is coming up as spring water. The nitrate concentration in influent was about 45 mgN/L. The other was wastewater from a plastic greenhouse. The nitrate concentration in inflow water was about 200 mgN/L. Nitrate was almost removed by the containers packed with sulfur (S0)- CaCO3 blocks in both sites. Increase of sulfate indicated that nitrate was removed by sulfur denitrification. This was also estimated stoichiometrically from the relationships between the removed nitrate and produced sulfate. The N2O was supersaturated in water at most sampling points and the highest concentration of dissolved N2O reached 900 μgN/L in Saitama in March. It seemed that insufficient nitrate removal caused accumulation of intermediates during denitrification, such as nitrite and N2O, in this month. However, the emission ratio of N2O to the removed nitrate during these processes was kept low, ranging from 0.01 to 0.19%, at both two sites throughout all surveys.

2017 ◽  
Vol 17 (6) ◽  
pp. 1703-1711 ◽  
Author(s):  
E. Karamati Niaragh ◽  
M. R. Alavi Moghaddam ◽  
M. M. Emamjomeh

Abstract This study aims to investigate the effect of the main parameters on the performance of a continuous flow electro-coagulation (EC) process for nitrate removal efficiency and its operating costs. For this purpose, the Taguchi experimental design with orthogonal array L27 (313) was applied to analyze the effects of selected parameters, namely initial nitrate concentration, inlet flow rate, current density and initial pH. According to the analysis of variance results, the inlet flow rate and the current density were recognized to be the most effective factors playing a pivotal role in nitrate removal efficiency by using an EC process. The optimum conditions of initial nitrate concentration, inlet flow rate, current density and initial pH were found to be 100 mg/L, 50 mL/min, 80 A/m2 and 8, respectively. As a result, the observed nitrate removal efficiency under these conditions was 61.70%. In addition, operating costs were evaluated as 1.278 US$/g NO3-removed. Finally, a high correlation was observed between the experimental and predicted results indicating an appropriate accuracy of the Taguchi model for nitrate removal efficiency and its operating costs in an EC system.


2015 ◽  
Vol 72 (3) ◽  
pp. 377-383 ◽  
Author(s):  
Jun Zhou ◽  
Hongyu Wang ◽  
Kai Yang ◽  
Yuchong Sun ◽  
Jun Tian

A continuous upflow biofilm reactor packed with ceramsite was constructed for nitrate removal under an anaerobic atmosphere without an organic carbon source. Denitrifying bacteria, Pseudomonas sp. W1, Pseudomonas sp. W2 and Microbacterium sp. W5, were added to the bioreactor as inocula. Nitrate concentration, nitrite accumulation and nitrogen removal efficiency in the effluent were investigated under various conditions set by several parameters including pH, hydraulic retention time (HRT), ratios of carbon to nitrogen (C/N) and temperature. The results illustrated that the maximum removal efficiency of nitrogen was 85.39%, under optimum reaction parameters, approximately pH 6.5–7, HRT = 48 hours and C/N = 13.1:1 at temperature of 30 °C, which were determined by experiment.


2006 ◽  
Vol 6 (2) ◽  
pp. 125-130
Author(s):  
C.-H. Hung ◽  
K.-H. Tsai ◽  
Y.-K. Su ◽  
C.-M. Liang ◽  
M.-H. Su ◽  
...  

Due to the extensive application of artificial nitrogen-based fertilizers on land, groundwater from the central part of Taiwan faces problems of increasing concentrations of nitrate, which were measured to be well above 30 mg/L all year round. For meeting the 10 mg/L nitrate standard, optimal operations for a heterotrophic denitrification pilot plant designed for drinking water treatment was investigated. Ethanol and phosphate were added for bacteria growing on anthracite to convert nitrate to nitrogen gas. Results showed that presence of high dissolved oxygen (around 4 mg/L) in the source water did not have a significantly negative effect on nitrogen removal. When operated under a C/N ratio of 1.88, which was recommended in the literature, nitrate removal efficiency was measured to be around 70%, sometimes up to 90%. However, the reactor often underwent severe clogging problems. When operated under C/N ratio of 1.0, denitrification efficiency decreased significantly to 30%. Finally, when operated under C/N ratio of 1.5, the nitrate content of the influent was almost completely reduced at the first one-third part of the bioreactor with an overall removal efficiency of 89–91%. Another advantage for operating with a C/N ratio of 1.5 is that only one-third of the biosolids was produced compared to a C/N value of 1.88.


2021 ◽  
Vol 13 (9) ◽  
pp. 4928
Author(s):  
Alicia Vanessa Jeffary ◽  
Osumanu Haruna Ahmed ◽  
Roland Kueh Jui Heng ◽  
Liza Nuriati Lim Kim Choo ◽  
Latifah Omar ◽  
...  

Farming systems on peat soils are novel, considering the complexities of these organic soil. Since peat soils effectively capture greenhouse gases in their natural state, cultivating peat soils with annual or perennial crops such as pineapples necessitates the monitoring of nitrous oxide (N2O) emissions, especially from cultivated peat lands, due to a lack of data on N2O emissions. An on-farm experiment was carried out to determine the movement of N2O in pineapple production on peat soil. Additionally, the experiment was carried out to determine if the peat soil temperature and the N2O emissions were related. The chamber method was used to capture the N2O fluxes daily (for dry and wet seasons) after which gas chromatography was used to determine N2O followed by expressing the emission of this gas in t ha−1 yr−1. The movement of N2O horizontally (832 t N2O ha−1 yr−1) during the dry period was higher than in the wet period (599 t N2O ha−1 yr−1) because of C and N substrate in the peat soil, in addition to the fertilizer used in fertilizing the pineapple plants. The vertical movement of N2O (44 t N2O ha−1 yr−1) was higher in the dry season relative to N2O emission (38 t N2O ha−1 yr−1) during the wet season because of nitrification and denitrification of N fertilizer. The peat soil temperature did not affect the direction (horizontal and vertical) of the N2O emission, suggesting that these factors are not related. Therefore, it can be concluded that N2O movement in peat soils under pineapple cultivation on peat lands occurs horizontally and vertically, regardless of season, and there is a need to ensure minimum tilling of the cultivated peat soils to prevent them from being an N2O source instead of an N2O sink.


2016 ◽  
Vol 13 (11) ◽  
pp. 3503-3517 ◽  
Author(s):  
Mianhai Zheng ◽  
Tao Zhang ◽  
Lei Liu ◽  
Weixing Zhu ◽  
Wei Zhang ◽  
...  

Abstract. Nitrogen (N) deposition is generally considered to increase soil nitrous oxide (N2O) emission in N-rich forests. In many tropical forests, however, elevated N deposition has caused soil N enrichment and further phosphorus (P) deficiency, and the interaction of N and P to control soil N2O emission remains poorly understood, particularly in forests with different soil N status. In this study, we examined the effects of N and P additions on soil N2O emission in an N-rich old-growth forest and two N-limited younger forests (a mixed and a pine forest) in southern China to test the following hypotheses: (1) soil N2O emission is the highest in old-growth forest due to the N-rich soil; (2) N addition increases N2O emission more in the old-growth forest than in the two younger forests; (3) P addition decreases N2O emission more in the old-growth forest than in the two younger forests; and (4) P addition alleviates the stimulation of N2O emission by N addition. The following four treatments were established in each forest: Control, N addition (150 kg N ha−1 yr−1), P addition (150 kg P ha−1 yr−1), and NP addition (150 kg N ha−1 yr−1 plus 150 kg P ha−1 yr−1). From February 2007 to October 2009, monthly quantification of soil N2O emission was performed using static chamber and gas chromatography techniques. Mean N2O emission was shown to be significantly higher in the old-growth forest (13.9 ± 0.7 µg N2O-N m−2 h−1) than in the mixed (9.9 ± 0.4 µg N2O-N m−2 h−1) or pine (10.8 ± 0.5 µg N2O-N m−2 h−1) forests, with no significant difference between the latter two. N addition significantly increased N2O emission in the old-growth forest but not in the two younger forests. However, both P and NP addition had no significant effect on N2O emission in all three forests, suggesting that P addition alleviated the stimulation of N2O emission by N addition in the old-growth forest. Although P fertilization may alleviate the stimulated effects of atmospheric N deposition on N2O emission in N-rich forests, this effect may only occur under high N deposition and/or long-term P addition, and we suggest future investigations to definitively assess this management strategy and the importance of P in regulating N cycles from regional to global scales.


1997 ◽  
Vol 35 (5) ◽  
pp. 1-10 ◽  
Author(s):  
K. R. Reddy ◽  
E. M. D'Angelo

Wetlands support several aerobic and anaerobic biogeochemical processes that regulate removal/retention of pollutants, which has encouraged the intentional use of wetlands for pollutant abatement. The purpose of this paper is to present a brief review of key processes regulating pollutant removal and identify potential indicators that can be measured to evaluate treatment efficiency. Carbon and toxic organic compound removal efficiency can be determined by measuring soil or water oxygen demand, microbial biomass, soil Eh and pH. Similarly, nitrate removal can be predicted by dissolved organic C and microbial biomass. Phosphorus retention can be described by the availability of reactive Fe and Al in acid soils and Ca and Mg in alkaline soils. Relationships between soil processes and indicators are useful tools to transfer mechanistic information between diverse types of wetland treatment systems.


1996 ◽  
Vol 34 (9) ◽  
pp. 101-108 ◽  
Author(s):  
M. Kuroda ◽  
T. Watanabe ◽  
Y. Umedu

Application of a bio-electro reactor for treatment of various kinds of polluted water was investigated experimentally. Aqueous solution of nitrate, ammonium and/or organic matter were used as synthetic polluted water. Denitrification of the nitrate polluted water without organic matter proceeded effectively by utilizing hydrogen gas produced by electrolysis of water in the reactor. The bio-electro reactor was also available for the treatment of nitrate polluted water containing organic matter when the C/N concentration ratio was up to 1.0 under the condition of 100 mA of applied electric current. The nitrate removal efficiency from nitrate polluted water containing acetate at C/N=1.0 was more than 90% at 5 hours of HRT and 80% even at 2.8 h HRT. For the treatment of ammonium polluted water, nitrification and denitrification proceeded simultaneously in a bio-electro reactor where nitrifying and denitrifying microorganisms were immobilized on the electrodes. The results obtained in this study suggested that the bio-electro reactor system was capable to application for oxidation and reduction treatments of the nitrate and ammonium polluted water.


2015 ◽  
Vol 5 (1) ◽  
Author(s):  
Grendi Hendrastomo *

Shifting agricultural era to the era of industrialization left many problems, especially in the agricultural sector. Populist policies have on one hand brought the country many industrial investments that force economic growth, but on the other hand reduced the partisanship of country in agricultural sector. Agriculture as the basis for mass production of most Indonesian society has became casualties as part of the green revolution that is full of developing countries‘s propaganda which brings benefit and lead to dependency on developing countries. The downturn actors of agricultural field increased in line with growth of food-estate program to attract foreign investors to explore the agro sector. This article discusses on a critical review of agriculture in Indonesia’s slump that began with the green revolution with their panca usaha tani, starting from the decline of the agricultural sector, static industrial situation until the solutions that might be applied to enhance the economic growth and social dynamics of Indonesia.   Keywords: Industrialisation, Marginalization of Agriculture, Green Revolution


Author(s):  
Nardi ◽  
Syaiful Anwar ◽  
Mohamad Yani ◽  
Nurholis ◽  
Muhammad Hendrizal

Nitrous oxide (N2O) is a long-lived greenhouse gas with a warming potential of 300 times higher than CO2. Conserving of intact peat swamp forest can hold the natural physical and chemical properties of the soil, such that the N2O emission occurs naturally. To quantify N2O emission from peatland ecosystems, data availability is highly needed. The objectives of this study were to quantify the emission of N2O and determine the main factors controlling N2O emission from peatland conservation forests. This research was conducted from January to December 2020 in the Kampar Peninsula, Pelalawan Regency, Riau Province. This study found that N2O emission at peatland conservation forest was 0.23 ± 0.19 kg-N/ha/year. Substantial changes in soil and environmental factors such as water table, soil temperature, soil moisture, water-filled pore space, NH4-N, and NO3-N significantly affect the exchange of N2O between peatlands and the atmosphere.


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