Single-disc investigations on nitrogen removal of higher loads in sequencing batch and continuously operated RDR systems

2000 ◽  
Vol 41 (4-5) ◽  
pp. 77-84 ◽  
Author(s):  
J. Lindemann ◽  
U. Wiesmann

Nitrification of ammonium-rich synthetic wastewater was studied in a continuously operated rotating disc reactor (RDR) with additional aeration. For a wastewater with 500 mg L−1 NH4−N a nearly complete oxidation to nitrate could be demonstrated for a hydraulic residence time of 27 h (HRT). The reactor was nearly completely mixed. Nevertheless, the biofilm covering the first discs was remarkably thicker than that of the last discs. In order to study the bioactivity of selected discs, single-disc reactors were used. The determined ammonium oxidation rate was nearly independent of the thickness and location of the disc. In contrast, the nitrite oxidation rate increased from the first to the last discs. Some results from experiments on nitrogen removal in sequencing batch single-disc reactors (SBSDR) are discussed. The SBSDR was operated with 2 phases, a partially submerged phase for nitrification and a completely submerged anoxic phase in which acetate was added for denitrification. It was advantageous to operate without additional aeration and thus produce more nitrite and saving carbon and energy. First results of the treatment of a synthetic wastewater with a C:N ratio of 1 in a 5-phase SBBR process providing 2 nitrification, 2 anoxic and a final aerobic post-treatment phase showed average specific rates.

2004 ◽  
Vol 50 (6) ◽  
pp. 207-215 ◽  
Author(s):  
Y.-H. Ahn ◽  
H.-C. Kim

The sustainable anaerobic nitrogen removal and microbial granulation were investigated by using a laboratory anaerobic granular sludge bed reactor, treating synthetic (inorganic and organic) wastewater and piggery waste. From inorganic synthetic wastewater, lithoautotrophic ammonium oxidation to nitrite/nitrate was observed by an addition of hydroxylamine. Also, the results revealed that the Anammox intermediates (particularly, hydrazine) contents in the substrate would be one of the important parameters for success of the anaerobic nitrogen removal process. The results from organic synthetic wastewater show that if the Anammox organism were not great enough in the startup of the process, denitritation and anaerobic ammonification would be a process prior to the Anammox reaction. The anaerobic ammonium removal from the piggery waste was performed successfully, probably due to the Anammox intermediates contained in the substrate. This reactor shows a complex performance including the Anammox reaction and HAP crystallization, as well as having partial denitritation occurring simultaneously. From the activity test, the maximum specific N conversion rate was 0.1 g NH4-N/g VSS/day (0.77 g T-N/g VSS/day), indicating that potential denitritation is quite high. The NO2-N/NH4-N ratio to Anammox is 1.17. The colour of the biomass treating the piggery waste changed from black to dark red. It was also observed that the red-colored granular sludge had a diameter of 1-2 mm. The settleability assessment of the granular sludge revealed that the granular sludge had a good settleability even though it was worse than that of seed granular sludge.


2020 ◽  
Vol 81 (1) ◽  
pp. 62-70
Author(s):  
Roumi Bhattacharya ◽  
Debabrata Mazumder

Abstract Nitrification of ammonium nitrogen (NH4+-N)-bearing synthetic wastewater was performed in a batch-activated sludge reactor by varying the initial ammonium nitrogen concentration up to 400 mg/L at a pH of 8.1 ± 0.2 and temperature of 36 ± 2 °C for developing the process kinetics using acclimatised biomass. Maximum ammonium nitrogen removal efficiency of 98.3% was achieved with initial ammonium nitrogen and mixed liquor suspended solids concentration of 235 mg/L and 2,180 mg/L, respectively, at 48 h batch period. Based on the experimental results, kinetic constants for ammonia nitrogen removal following Monod's approach were obtained as maximum substrate removal rate coefficient = 0.057 per day, yield coefficient = 0.336 mg volatile suspended solids/mg ammonium nitrogen, half velocity constant = 12.95 mg NH4+-N/L and endogenous decay constant = 0.02 per day. Nitrification is a consecutive reaction with ammonium oxidation as the first step followed by nitrite oxidation. The overall rate of nitrite and nitrate formation was observed to be 1.44 per day and 0.34 per day, respectively.


2017 ◽  
Vol 76 (11) ◽  
pp. 3101-3113
Author(s):  
Quynh Nga Le ◽  
Chihiro Yoshimura ◽  
Manabu Fujii

Abstract The effect of inorganic suspended solids (ISS) on nitrification in freshwater samples has been described inconsistently and remains unclear. This study therefore investigated the effects of the chemical characteristics and concentration of ISS on the nitrification rate by focusing on Nitrosomonas europaea and Nitrobacter winogradskyi as the two most dominant nitrification species in freshwater. Batch-wise experiments were conducted using three chemically well-characterized ISS (i.e. the clay minerals montmorillonite, sericite, and kaolinite in the concentration range 0–1,000 mg L−1). The results show that the ammonium oxidation rate constant (kNH4) was significantly affected by the ISS type, whereas changes in the ISS concentration had an insignificant effect on kNH4, except for kaolinite. The highest kNH4 was observed in samples containing sericite (kNH4, 0.067 L mg−1 day−1), followed by samples containing montmorillonite (kNH4, 0.044 L mg−1 day−1). The ammonium oxidation rate was low in the control and kaolinite samples. Nitrite oxidation was enhanced in the presence of all types of ISS. The rate constants of ISS-mediated nitrite oxidation (kNO2, 0.13–0.21 L mg−1 day−1) were not significantly different among the three types of ISS, but kNO2 was significantly affected by ISS concentration. Overall, our study indicated various effects of the ISS type and concentration on nitrification and, in particular, a notable positive effect of sericite.


2010 ◽  
Vol 62 (5) ◽  
pp. 1037-1044 ◽  
Author(s):  
Daijun Zhang ◽  
Qing Cai ◽  
Bo Zu ◽  
Cui Bai ◽  
Ping Zhang

Ammonia oxidizing bacteria-enriched sludge was obtained in a sequencing batch reactor with synthetic wastewater. Batch tests of ammonia oxidation were carried out with the sludge, in the presence of only trace NO2 and in the presence of O2 and trace NO2, respectively. The Andrews model is used to describe NO2-dependent ammonia oxidation. The maximum ammonia oxidation rate of 139.11 mg N·(g sludge COD h)−1, occurred in the presence of 21% O2 and 100 ppm NO2, which was 3 times higher than the aerobic ammonia oxidation rate without NO2. The kinetic model of ammonia oxidation in the presence of O2 and trace NO2 is developed, and the function of NO2 apparently enhancing ammonia oxidation is suggested. The maximal nitrogen removel of 34.19% occurred at the 21% O2 and 100 ppm NO2 in the mixed gases. Nitrogen removal principally depended on the denitrification activity and NO2-dependent ammonia oxidation activity of ammonia-oxidizing bacteria (AOB).


2013 ◽  
Vol 67 (3) ◽  
pp. 549-556
Author(s):  
Shun Shi ◽  
Wendong Tao

This study developed a simple numerical model for nitrogen removal in biofilters, which was designed to enhance simultaneous nitritation and anaerobic ammonium oxidation (anammox). It is the first attempt to simulate anammox together with two-step nitrification in natural treatment systems, which may have different kinetic parameters and temperature effects from conventional bioreactors. Prediction accuracy was improved by adjusting kinetic coefficients over the startup period of the biofilters. The maximum rates of nitritation and nitrite oxidation increased linearly over time during the startup period. Simulations confirmed successful enhancement of simultaneous nitritation and anammox (SNA) in the biofilters, with anammox contributing 35% of ammonium removal. Effluent ammonium concentration was affected by influent ammonium concentration and the maximum nitritation rate, and was insensitive to the maximum nitrite oxidation rate and anammox substrate factor. Ammonium removal via SNA was likely limited by biomass of aerobic ammonia oxidizing bacteria in the biofilters. The developed model is a promising tool for studying the dynamics of nitrogen removal processes including SNA in natural treatment systems.


2013 ◽  
Vol 67 (6) ◽  
pp. 1280-1287 ◽  
Author(s):  
Chuang Yao ◽  
Heng-Yi Lei ◽  
Qiang Yu ◽  
Shu-Ping Li ◽  
Hua-Liang Li ◽  
...  

A novel magnetic carrier with surface magnetic field of 4 mT was developed for studying the magnetic enhanced bio-effect on nitrification. The bio-effect on nitrificaton induced by the magnetic carrier was studied by comparing the performance of sequencing batch biofilm reactors filled with magnetic (MC) and non-magnetic (NMC) carriers. The result showed that the bioreactor with MC had better performance for nitrification than bioreactor with NMC. During the biofilm culturing period, the time required for nitrification formation in biofilm of the MC reactor was 25% less than that for the NMC reactor. The results also showed that the ammonium oxidation rate of the MC reactor was 1.6-fold faster than that in the NMC reactor at high influent NH4-N concentration, while nitrite oxidation rate was always accelerated regardless of influent NH4-N concentration. The specific oxygen uptake rate analysis revealed that ammonia and nitrite oxidation activities in biofilm of the MC reactor were 1.65 and 1.98 times greater than those of the NMC reactor, respectively.


2011 ◽  
Vol 183-185 ◽  
pp. 522-526 ◽  
Author(s):  
Ling Ling Li ◽  
Bo Yang ◽  
Peng Zhou

During the process of cultivation of salt-tolerant nitrifying bacteria, the increase in NaCl concentrations was carried out in two different manners. The NaCl concentration in reactor A was increased by increment of 5 g/L, while the NaCl concentration in reactor B was increased by increment of 2.5 g/L. The impacts of NaCl content on the fresh culture and two acclimated cultures were investigated, which focused upon the changes of the specific ammonium oxidation rate (SAOR) and specific nitrite oxidation rate (SNOR). The results indicated that fresh nitrifiers were severely inhibited by high salinity. At NaCl concentration of 25 g/L, ammonia-oxidizing bacteria (AOB) and nitrite-oxidizing bacteria (NOB) completely lost the nitrification capability. After 46 days of acclimation, the nitrifying bacteria could be adapted to the saline wastewater. The average SAOR and SNOR in reactor B were slightly higher than those in reactor A, which meant that low increment in salt concentration may be in favor of the development of salt-tolerant nitrifiers. But the two NaCl increasing approaches did not affect the SAOR and SNOR too much. Salt-tolerant nitrifiers could be well developed with the two acclimation manners.


2010 ◽  
Vol 5 (3) ◽  
Author(s):  
Cheng-Nan Chang ◽  
Li-Ling Lee ◽  
Han-Hsien Huang ◽  
Ying-Chih Chiu

The performance of a real-time controlled Sequencing Batch Membrane Bioreactor (SBMBR) for removing organic matter and nitrogen from synthetic wastewater has been investigated in this study under two specific ammonia loadings of 0.0086 and 0.0045g NH4+-N gVSS−1 day−1. Laboratory results indicate that both COD and DOC removal are greater than 97.5% (w/w) but the major benefit of using membrane for solid-liquid separation is that the effluent can be decanted through the membrane while aeration is continued during the draw stage. With a continued aeration, the sludge cake layer is prevented from forming thus alleviating the membrane clogging problem in addition to significant nitrification activities observed in the draw stage. With adequate aeration in the oxic stage, the nitrogen removal efficiency exceeding 99% can be achieved with the SBMBR system. Furthermore, the SBMBR system has also been used to study the occurrence of ammonia valley and nitrate knee that can be used for real-time control of the biological process. Under appropriate ammonia loading rates, applicable ammonia valley and nitrate knee are detected. The real-time control of the SBMBR can be performed based on on-line ORP and pH measurements.


2021 ◽  
Vol 9 (3) ◽  
pp. 105252
Author(s):  
Amin Mojiri ◽  
John L. Zhou ◽  
Harsha Ratnaweera ◽  
Akiyoshi Ohashi ◽  
Noriatsu Ozaki ◽  
...  

2009 ◽  
Vol 59 (3) ◽  
pp. 573-582 ◽  
Author(s):  
Xiao-ming Li ◽  
Dong-bo Wang ◽  
Qi Yang ◽  
Wei Zheng ◽  
Jian-bin Cao ◽  
...  

It was occasionally found that a significant nitrogen loss in solution under neutral pH value in a sequencing batch reactor with a single-stage oxic process using synthetic wastewater, and then further studies were to verify the phenomenon of nitrogen loss and to investigate the pathway of nitrogen removal. The result showed that good performance of nitrogen removal was obtained in system. 0–7.28 mg L−1 ammonia, 0.08–0.38 mg L−1 nitrite and 0.94–2.12 mg L−1 nitrate were determined in effluent, respectively, when 29.85–35.65 mg L−1 ammonia was feeding as the sole nitrogen source in influent. Furthermore, a substantial nitrogen loss in solution (95% of nitrogen influent) coupled with a little gaseous nitrogen increase in off-gas (7% of nitrogen influent) was determined during a typical aerobic phase. In addition, about 322 mg nitrogen accumulation (84% of nitrogen influent) was detected in activated sludge. Based on nitrogen mass balance calculation, the unaccounted nitrogen fraction and the ratio of nitrogen accumulation in sludge/nitrogen loss in solution were 14.6 mg (3.7% of nitrogen influent) and 0.89, respectively. The facts indicated that the essential pathway of nitrogen loss in solution in this study was excess nitrogen accumulation in activated sludge.


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