Development of an integrated iron oxide adsorption/membrane separation system for water treatment

2002 ◽  
Vol 2 (5-6) ◽  
pp. 293-300 ◽  
Author(s):  
K.-W. Lee ◽  
K.-H. Choo ◽  
S.-J. Choi ◽  
K. Yamamoto

The performance of an integrated iron oxide particle (IOPs) adsorption and ultrafiltration (UF) process was investigated in terms of natural organic matter removal and membrane permeability during treatment of a drinking water source. Throughout the fractionation of raw water and subsequent UF of fractioned portions, the significance of each component in raw water affecting flux decline during IOP-UF was evaluated. Natural organic matter (NOM) removal efficiencies for the IOP-UF system increased markedly as a substantial amount of IOPs was added into suspension, without any negative effect on permeate flux. During IOP-UF testings, there was no difference in NOM removal regardless of the locations of IOPs whether they were either in suspension or deposited on the UF membrane, but significant initial flux reduction occurred with the formation of a precoat (attached) layer. However, all IOPs in suspension and in the cake were effective in both removing NOM and preventing irreversible fouling as long as they were removed by backwashing. Dissolved matter obtained from filtration through a 0.45 μm filter was more responsible for flux decline in UF than larger colloids. Particularly, IOP-adsorbable dissolved matter accounted for 60% of total flux decline, confirming the attractiveness of IOP addition to UF.

2004 ◽  
Vol 4 (5-6) ◽  
pp. 207-213 ◽  
Author(s):  
K.-H. Choo ◽  
I.-H. Park ◽  
S.-J. Choi

Natural organic matter (NOM) removal and membrane fouling were investigated using iron oxide-coated microfiltration (MF) systems for drinking water treatment. Addition of iron oxide particle (IOP) adsorbents into MF always improved NOM removal and reduced fouling, but IOP dosing methods did affect the membrane performance. The IOP coating layer formed on the membrane surface played a major role in preventing membrane fouling by residual NOM in water. Pre-mixing of IOP with raw water followed by continuous injection into the MF system controlled membrane fouling better than pre- and intermittent loadings of IOP. This could be in close association with the distribution of IOPs across the hollow fiber MF surfaces and the effectiveness of contact of IOP with feedwater. The turbidity of water influenced the MF system with intermittent IOP loads more greatly than that with IOP in suspension. There existed an optimal IOP dose where membrane fouling can be minimized achieving maximal NOM removal.


2017 ◽  
Vol 17 (4) ◽  
pp. 1080-1087
Author(s):  
Jieun Lee ◽  
Saravanamuth Vigneswaran ◽  
Yongshun Zhang ◽  
Ramireddy S. P. Raj Reddy ◽  
Zongwen Liu

A carbon nanotube (CNT) ultrafiltration (UF) membrane was applied to natural organic matter (NOM) removal in pond water treatment. The source water was pretreated by flocculation and/or adsorption prior to the UF process to alleviate permeate flux decline and improve NOM removal efficiency. The performance of a commercial polyethersulfone (PES) UF membrane was compared to evaluate that of the CNT membrane. The CNT membrane outperformed the PES-UF membrane. The permeate flux, total organic carbon and humic acid (HA) removal rate of the CNT membrane was observed to be 230 LMH/bar, 60%, and 80% when 30 mg/L poly aluminium chloride (PACI) flocculation was applied. This highlights that the permeate flux was three times higher with slightly higher rejection efficiency than the PES-UF membrane. In particular, severe permeate flux decline was completely overcome by the CNT membrane with 30 mg/L PACI coagulation. For powder activated carbon (PAC) adsorption, even though there was a severe permeate flux decline in the CNT membrane, almost complete HA removal (98%) was achieved when 0.5 g/L PAC adsorption was coupled. Based on the superior performance of the CNT membrane with pretreatment, the CNT membrane is suggested to be a robust system for a high concentration of organic matter pond water treatment without membrane flux decline.


2016 ◽  
Vol 283 ◽  
pp. 330-337 ◽  
Author(s):  
Abdullah Ogutverici ◽  
Levent Yilmaz ◽  
Ulku Yetis ◽  
Filiz B. Dilek

2001 ◽  
Vol 1 (4) ◽  
pp. 237-245 ◽  
Author(s):  
V. Gauthier ◽  
B. Barbeau ◽  
R. Millette ◽  
J.-C. Block ◽  
M. Prévost

The concentrations of suspended particles were measured in the drinking water of two distribution systems, and the nature of these particles documented. The concentrations of particulate matter were invariably found to be small (maximum 350 μg/L). They are globally in the very low range in comparison with dissolved matter concentrations, which are measured in several hundreds of mg/L. Except during special water quality events, such as turnover of the raw water resource, results show that organic matter represents the most important fraction of suspended solids (from 40 to 76%) in treated and distributed water. Examination of the nature of the particles made it possible to develop several hypotheses about the type of particles penetrating Montreal's distribution system during the turnover period (algae skeleton, clays). These particles were found to have been transported throughout the distribution systems quite easily, and this could result in the accumulation of deposits if their surface charge were ever even slightly destabilised, or if the particles were to penetrate the laminar flow areas that are fairly typical of remote locations in distribution systems.


2008 ◽  
Vol 27 (9) ◽  
pp. 1875 ◽  
Author(s):  
Mohammed Baalousha ◽  
Adriana Manciulea ◽  
Susan Cumberland ◽  
Kevin Kendall ◽  
Jamie R. Lead

2008 ◽  
Vol 8 (6) ◽  
pp. 681-690 ◽  
Author(s):  
H. M. Szabo ◽  
I. Lindfors ◽  
T. Tuhkanen

In this study Natural organic matter (NOM) characteristics and variations of catchment samples (brooks and collector lakes) from Western Finland, and drinking water produced from the same catchment were examined. Seasonal and spatial NOM variations were followed by means of DOC and HPLC-SEC with UV and fluorescence detection. NOM decreased from drains to lakes by 35 to 75% and from drains to drinking water by 73 to 94%. Drains had a higher NOM content in summer and a lower NOM content in winter and spring. Lakes showed inverse patterns and had a higher NOM content in winter and spring and a lower NOM content in summer. HPLC-SEC separated 8 molecular weight fractions. In drains the HMW fractions represented up to 80% of the NOM, in lake waters HMW fractions accounted for 50 to 70% of the NOM. In drinking water IMW fractions dominated. Increased NOM in raw water during winter was associated with increased IMW fractions and the appearance of HMW fractions in drinking water, DOC increasing from 1.4 mg C/L in summer to 5.8 mg C/L in winter. SPH-Tryptophan correlated with the dissolved organic nitrogen and DOC of the samples. The drain affected by agriculture generally presented higher SPH-Tryptophan values than the unaffected drain.


2007 ◽  
Vol 7 (18) ◽  
pp. 2651-2655 ◽  
Author(s):  
M.A. Zazouli ◽  
S. Nasseri . ◽  
A.H. Mahvi . ◽  
A.R. Mesdaghinia . ◽  
M. Younecian . ◽  
...  

2004 ◽  
Vol 50 (12) ◽  
pp. 279-285 ◽  
Author(s):  
J.H. Kweon ◽  
D.F. Lawler

The biggest impediment for applying membrane processes is fouling that comes from mass flux (such as particle and organic matter) to the membrane surface and its pores. Numerous research articles have indicated that either particles or natural organic matter (NOM) has been the most detrimental foulant. Therefore, the role of particles in membrane fouling was investigated with two synthetic waters (having either particles alone or particles with simple organic matter) and a natural water. Membrane fouling was evaluated with flux decline behavior and direct images from scanning electron microscopy. The results showed that the combined fouling by kaolin and dextran (a simple organic compound selected as a surrogate for NOM) showed no difference from the fouling with only the organic matter. The similarity might stem from the fact that dextran (i.e., polysaccharide) has no ability to be adsorbed on the clay material, so that the polysaccharide behaves the same with respect to the membrane with or without clay material being present. In contrast to kaolin, the natural particles showed a dramatic effect on membrane fouling.


Stroke ◽  
2007 ◽  
Vol 38 (10) ◽  
pp. 2733-2737 ◽  
Author(s):  
Andreas Saleh ◽  
Michael Schroeter ◽  
Adrian Ringelstein ◽  
Hans-Peter Hartung ◽  
Mario Siebler ◽  
...  

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