scholarly journals Key parameters controlling an adsorption process for the selective removal of arsenic from drinking water

2002 ◽  
Vol 2 (5-6) ◽  
pp. 111-117 ◽  
Author(s):  
S. Ouvrard ◽  
M.-O. Simonnot ◽  
M. Sardin
Keyword(s):  
Mass Transfer ◽  
Adsorption Process ◽  
Fine Particles ◽  
Mass Transfer Limitation ◽  
Water Ph ◽  
Regeneration Procedure ◽  
Removal Of Arsenic ◽  
The Impact ◽  
Elution Step ◽  
Flow Rate Influence

Arsenic can be selectively removed from water through adsorption on a natural manganese oxide. This paper presents some of the key parameters controlling such a process. Both production and regeneration steps were studied and the influence of three main controlling parameters was put to light. The water pH greatly influenced the adsorption capacity. Low water pH highly improved the treatment. The adsorption being under mass transfer limitation, flow rate influence was measured and optimization solutions were proposed. Finally, the impact of the regeneration procedure was evaluated on the adsorbent stability. It gave good arsenic elution results but the caustic elution step generated fine particles that could not be avoided. The following neutralization could however be adjusted in order to minimize further adsorbent dissolution.

scholarly journals The Impact of Iron Oxide Concentration on the Performance of Molten Oxide Electrolytes for the Production of Liquid Iron Metal

2019 ◽  
Vol 51 (1) ◽  
pp. 365-376
Author(s):  
Jan Wiencke ◽  
Hervé Lavelaine ◽  
Pierre-Jean Panteix ◽  
Carine Petitjean ◽  
Christophe Rapin
Keyword(s):  
Mass Transfer ◽  
Iron Oxide ◽  
Liquid Iron ◽  
Mass Transfer Limitation ◽  
Oxide Concentration ◽  
Ohmic Drop ◽  
Geometrical Form ◽  
Flow Through ◽  
Molten Oxide ◽  
The Impact

AbstractThe effect of iron oxide concentration on the conductive behavior of a molten oxide electrolyte has been investigated at 1823 K using stepped linear scan voltammetry. To maximize the current flow through the electrolyte the ohmic drop in the cell was minimized by shortening the electrode distance. The acquired current was then interpreted by means of an ohmic drop correction, taking into account the conductivity of the alumina-silicate electrolyte and the geometrical form factor of the cell. Via this methodology, a mass transfer limitation in dependence of the iron oxide concentration was identified. This mass transfer limitation vanishes above 7 wt pct of iron oxide where charge transfer starts to be limited solely by electrochemical reaction kinetics. In the analyzed range of concentration, an impact of iron oxide on electronic conduction was not measurable. In addition to these findings, the faradaic yield of the anode half-reaction was determined by the life-measure of O2-production. Hereby, a domain of an anodic yield close to 100 pct for various iron oxide concentrations was identified. Based on these findings, suitable conditions for the electrochemical production of liquid iron were determined.

scholarly journals Simulation aided analysis and experimental study of polyurethane polymerization reaction and foaming process

2017 ◽  
Author(s):  
◽  
Harith H. Al-Moameri
Keyword(s):  
Mass Transfer ◽  
Reaction Temperature ◽  
Research Process ◽  
Polymerization Reaction ◽  
Gel Point ◽  
Foam Formation ◽  
Simulation Code ◽  
Mass Transfer Limitation ◽  
Elementary Reactions ◽  
The Impact

A MatLab simulation model was developed to simulate polymerization reactions, gel point times and foam formation. The simulation is based on the simultaneous solution of typically 25-80 ordinary differential equations that describe elementary reactions, energy balances, and mass transfer. Laboratory polymerization experiments were performed to evaluate the accuracy of the simulations, including setting up experimental systems and measurement of temperature, height, and viscosity profiles of the urethane systems. The performance of physical and chemical blowing agents were simulated with mass transfer of the blowing agent estimated as a function of reaction temperature and resin viscosity. The simulation code of polyurethane reactions allows the studying of variables that are impossible to obtain in labs like the rate of foam's cell growth and pressure inside the cells. Also, simulation provides insight into mechanisms such as how attaining a reasonable maximum reaction temperature is important to properly cure foams and avoid foam shrinkage. The impact of mass transfer limitation of the reacting moieties was successfully simulated based on three fundamental approaches. Further modeling shows the ability to reduce the number of parameters used for simulating urethane reactions by considering the viscosity dependent term for the frequency factor of Arrhenius equation. Finally, the simulation studies of this research provide fundamental insights into the mechanism of homogeneous and catalytic reactions. This research process places high demands on identifying and testing highly-impactful fundamental mechanisms during polymerization that have not previously been identified.

scholarly journals Use of Multi-Anionic Sodium Tripolyphosphate to Enhance Dispersion of Concentrated Kaolin Slurries in Seawater

Metals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 1085
Author(s):  
Williams Leiva ◽  
Norman Toro ◽  
Pedro Robles ◽  
Edelmira Gálvez ◽  
Ricardo Ivan Jeldres
Keyword(s):  
Rheological Properties ◽  
Fine Particles ◽  
Sodium Tripolyphosphate ◽  
Mining Industry ◽  
Chord Length ◽  
Water Recovery ◽  
Reflectance Measurement ◽  
Anionic Charge ◽  
Free Environment ◽  
The Impact

This research aims to analyze the impact of sodium tripolyphosphate (STPP) as a rheological modifier of concentrated kaolin slurries in seawater at pH 8, which is characteristic of copper sulfide processing operations. The dispersion phenomenon was analyzed through chord length measurements using the focused beam reflectance measurement (FBRM) technique, complementing size distributions in unweighted and square-weighted modes. The reduction of the rheological properties was significant, decreasing from 231 Pa in a reagent-free environment to 80 Pa after the application of STPP. A frequency sweep in a linear viscoelastic regime indicated that by applying a characteristic dosage of 0.53 kg/t of STPP, the pulp before yielding increases its phase angle, which increases its liquid-like character. Measurements of the chord length verified the dispersion of particles, which showed an apparent increase in the proportion of fine particles and a reduction of the coarser aggregates when STPP was applied. Measurements of the zeta potential suggested that the high anionic charge of the reagent (pentavalent) increases the electrostatic repulsions between particles, overcoming the effect of cations in seawater. The results are relevant for the mining industry, especially when the deposits have high contents of complex gangues, such as clays, that increase the rheological properties. This increases the energy costs and water consumption needed for pumping the tailings from thickeners to the tailing storages facilities. The strategies that allow for the improvement of the fluidity and deformation of the tailings generate slack in order to maximize water recovery in the thickening stages.

scholarly journals Size-resolved characterization of organic aerosol in the North China Plain: new insights from high resolution spectral analysis

2021 ◽  
Author(s):  
Weiqi Xu ◽  
Chun Chen ◽  
Yanmei Qiu ◽  
Conghui Xie ◽  
Yunle Chen ◽  
...  
Keyword(s):  
Radiative Forcing ◽  
North China Plain ◽  
North China ◽  
Fine Particles ◽  
Large Fraction ◽  
Organic Aerosol ◽  
Size Distributions ◽  
The North ◽  
The Impact

Organic aerosol (OA), a large fraction of fine particles, has a large impact on climate radiative forcing and human health, and the impact depends strongly on size distributions. Here we...

scholarly journals The Impact of Changes in Cloud Water pH on Aerosol Radiative Forcing

2019 ◽  
Vol 46 (7) ◽  
pp. 4039-4048 ◽  
Author(s):  
S. T. Turnock ◽  
G. W. Mann ◽  
M. T. Woodhouse ◽  
M. Dalvi ◽  
F. M. O'Connor ◽  
...  
Keyword(s):  
Radiative Forcing ◽  
Cloud Water ◽  
Aerosol Radiative Forcing ◽  
Water Ph ◽  
The Impact ◽  
Aerosol Radiative

scholarly journals Impact of vehicular emissions on the formation of fine particles in the Sao Paulo Metropolitan Area: a numerical study with the WRF-Chem model

2016 ◽  
Vol 16 (2) ◽  
pp. 777-797 ◽  
Author(s):  
A Vara-Vela ◽  
M. F. Andrade ◽  
P. Kumar ◽  
R. Y. Ynoue ◽  
A. G. Muñoz
Keyword(s):  
Size Distribution ◽  
Metropolitan Area ◽  
Atmospheric Aerosols ◽  
Fine Particles ◽  
Sao Paulo ◽  
Vehicular Emissions ◽  
São Paulo ◽  
Mass Size Distribution ◽  
Mass Size ◽  
The Impact

Abstract. The objective of this work is to evaluate the impact of vehicular emissions on the formation of fine particles (PM2.5;  ≤  2.5 µm in diameter) in the Sao Paulo Metropolitan Area (SPMA) in Brazil, where ethanol is used intensively as a fuel in road vehicles. The Weather Research and Forecasting with Chemistry (WRF-Chem) model, which simulates feedbacks between meteorological variables and chemical species, is used as a photochemical modelling tool to describe the physico-chemical processes leading to the evolution of number and mass size distribution of particles through gas-to-particle conversion. A vehicular emission model based on statistical information of vehicular activity is applied to simulate vehicular emissions over the studied area. The simulation has been performed for a 1-month period (7 August–6 September 2012) to cover the availability of experimental data from the NUANCE-SPS (Narrowing the Uncertainties on Aerosol and Climate Changes in Sao Paulo State) project that aims to characterize emissions of atmospheric aerosols in the SPMA. The availability of experimental measurements of atmospheric aerosols and the application of the WRF-Chem model made it possible to represent some of the most important properties of fine particles in the SPMA such as the mass size distribution and chemical composition, besides allowing us to evaluate its formation potential through the gas-to-particle conversion processes. Results show that the emission of primary gases, mostly from vehicles, led to a production of secondary particles between 20 and 30 % in relation to the total mass concentration of PM2.5 in the downtown SPMA. Each of PM2.5 and primary natural aerosol (dust and sea salt) contributed with 40–50 % of the total PM10 (i.e. those  ≤  10 µm in diameter) concentration. Over 40 % of the formation of fine particles, by mass, was due to the emission of hydrocarbons, mainly aromatics. Furthermore, an increase in the number of small particles impaired the ultraviolet radiation and induced a decrease in ozone formation. The ground-level O3 concentration decreased by about 2 % when the aerosol-radiation feedback is taken into account.

scholarly journals Numerical Simulation of Heat Mass Transfer Effects on MHD Flow of Williamson Nanofluid by a Stretching Surface with Thermal Conductivity and Variable Thickness

Coatings ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 684
Author(s):  
Saeed Islam ◽  
Haroon Ur Rasheed ◽  
Kottakkaran Sooppy Nisar ◽  
Nawal A. Alshehri ◽  
Mohammed Zakarya
Keyword(s):  
Thermal Conductivity ◽  
Boundary Layer ◽  
Mass Transfer ◽  
Differential Equations ◽  
Variable Thickness ◽  
Heat Mass Transfer ◽  
Mathematical Formulation ◽  
Stretching Surface ◽  
Nanofluid Flow ◽  
The Impact

The current analysis deals with radiative aspects of magnetohydrodynamic boundary layer flow with heat mass transfer features on electrically conductive Williamson nanofluid by a stretching surface. The impact of variable thickness and thermal conductivity characteristics in view of melting heat flow are examined. The mathematical formulation of Williamson nanofluid flow is based on boundary layer theory pioneered by Prandtl. The boundary layer nanofluid flow idea yields a constitutive flow laws of partial differential equations (PDEs) are made dimensionless and then reduce to ordinary nonlinear differential equations (ODEs) versus transformation technique. A built-in numerical algorithm bvp4c in Mathematica software is employed for nonlinear systems computation. Considerable features of dimensionless parameters are reviewed via graphical description. A comparison with another homotopic approach (HAM) as a limiting case and an excellent agreement perceived.

To what extent does the environmental magnetism technique acts as a way of assessing the uptake of atmospheric particles by plants?

2021 ◽  
Author(s):  
Sarah Letaïef ◽  
Pierre Camps ◽  
Thierry Poidras ◽  
Patrick Nicol ◽  
Delphine Bosch ◽  
...  
Keyword(s):  
Air Quality ◽  
Endemic Species ◽  
Fine Particles ◽  
Magnetic Measurements ◽  
Deposition Velocity ◽  
Environmental Magnetism ◽  
Air Pollutant ◽  
Atmospheric Pollutants ◽  
Area Index ◽  
The Impact

<p>Numerous studies have already shown the possibility of tracing the sources, the<br>compositions, and the concentration of atmospheric pollutants deposited on plant<br>leaves. In environmental geochemistry, inter-element and isotope ratios from<br>chemical element assays have been used for these purposes. Alternatively,<br>environmental magnetism represents a quick and inexpensive asset that is<br>increasingly used as a relative indicator for concentrations of air pollutant on bio<br>accumulator surfaces such as plants. However, a fundamental issue is still pending:<br>Do plants in urban areas represent a sink for fine particles that is sufficiently effective<br>to improve air quality? This is a very topical issue because some studies have shown<br>that the foliage can trap fine particles by different dry deposition processes, while<br>other studies based on CFD models indicate that plant hedges in cities can hinder<br>the atmospheric dispersion of pollutants and therefore increase pollution at the level of<br>emission sources such as traffic. To date, no consensus was made because several<br>factors not necessary well known must be taken into account, such as, PM<br>concentration and size, prevailing wind, surface structures, epicuticular wax, to<br>mention just a few examples. A first step toward the understanding of the impact of<br>urban greens on air quality is the precise determination of the deposition velocity (Vd)<br>parameter. This latter is specific for each species and it is most of the time<br>underestimated in modeling-based studies by taking standard values.<br>In that perspective, we built a wind tunnel (6 m long, 86 cm wide and 86 cm high) to<br>perform analogical experiments on different endemic species. All parameters are<br>controlled, i.e, the wind speed, the nature and the injection time of pollutants (Gasoline<br>or Diesel exhausts, brakes or tires dust, etc…). We can provide the PM concentrations<br>upwind and downwind of natural reconstituted hedges by two dustmeters (LOACs -<br>MétéoModem). Beforehand, parameters such as the hedge resistance (%) or the leaf<br>area index (LAI) have been estimated for each studied specie to allow comparability<br>between plants removal potential. The interest would ultimately combine PM<br>concentration measured by size bins from the LOACs with magnetic measurements<br>(ARM, IRM100mT, IRM300mT and SIRM) of plant leaves. The idea is to check whether it<br>would be possible to precisely determine in situ the dust removal rate by urban greens<br>with environmental magnetism measurements. Up to now, we have carried out on<br>different endemic species such as Elaeagnus x ebbingei leaves and Mediterranean<br>pine needles, the results of which will be presented.</p>

scholarly journals Reuse of Newspaper As An Adsorbent For Cu (II) Removal By Citric Acid Modification

2018 ◽  
Vol 156 ◽  
pp. 02012 ◽  
Author(s):  
Mardiah ◽  
Rif’an Fathoni ◽  
Pratiwi Pudyaningtyas ◽  
Hamdania Gamu ◽  
Rinaldy
Keyword(s):  
Citric Acid ◽  
Adsorption Process ◽  
Kinetic Studies ◽  
Order Reaction ◽  
Acid Modification ◽  
Pseudo First Order Reaction ◽  
First Order ◽  
Pseudo Second Order ◽  
Heavy Metal Adsorbent ◽  
The Impact

High Consumption of paper, bring the impact of the waste paper itself. And the utilization of the paper is limited to recycled products and crafts, whereas paper such as newspaper still contains cellulose that can be potential to be used as a heavy metal adsorbent. In this study, newspaper was dissolved in sodium bicarbonate to reduce various impurities and then was reacted with citric acid (CA). The modified adsorbent was characterized by FTIR and was tested for adsorb Cu(II) in artificial solution. After adsorption process, the solution was filtered and analysed using Atomic Absorption Spectrophotometer (AAS). The adsorption experimental data was fitted to Langmuir, Freundlich, Tempkin, and Dubinin-Radushkevich for equilibrium model and was fitted to pseudo first order reaction and pseudo second order reaction for kinetic studies. The result showed that CA-modification newspaper able to remove heavy metals Cu(II) in solution.

scholarly journals Does afforestation deteriorate haze pollution in Beijing–Tianjin–Hebei (BTH), China?

2018 ◽  
Author(s):  
Xin Long ◽  
Naifang Bei ◽  
Jiarui Wu ◽  
Xia Li ◽  
Tian Feng ◽  
...  
Keyword(s):  
Forest Cover ◽  
Fine Particles ◽  
Control Strategies ◽  
Surface Wind ◽  
Forecast Model ◽  
Surface Wind Speed ◽  
Satellite Measurements ◽  
Haze Pollution ◽  
The Impact

Abstract. Although aggressive emission control strategies have been implemented recently in the Beijing–Tianjin–Hebei area (BTH), China, pervasive and persistent haze still frequently engulfs the region during wintertime. Afforestation in BTH, primarily concentrated in the Taihang and Yanshan Mountains, has constituted one of the controversial factors exacerbating the haze pollution due to its slowdown of the surface wind speed. We report here an increasing trend of forest cover in BTH during 2001–2013 based on long-term satellite measurements and the impact of the afforestation on the fine particles (PM2.5) level. Simulations using the Weather Research and Forecast model with chemistry reveal that the afforestation in BTH since 2001 generally deteriorates the haze pollution in BTH to some degree, enhancing PM2.5 concentrations by up to 6 % on average. Complete afforestation or deforestation in the Taihang and Yanshan Mountains would increase or decrease the PM2.5 level within 15 % in BTH. Our model results also suggest that implementing a large ventilation corridor system would not be effective or beneficial to mitigate the haze pollution in Beijing.

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