Pretreatment processes for membrane filtration of raw water containing manganese

2001 ◽  
Vol 1 (5-6) ◽  
pp. 341-348 ◽  
Author(s):  
S. Takizawa ◽  
L. Fu ◽  
N. Pradhan ◽  
T. Ike ◽  
M. Ohtaki ◽  
...  
Keyword(s):  
Membrane Fouling ◽  
Membrane Filtration ◽  
Fixed Bed ◽  
Experimental Studies ◽  
Manganese Concentration ◽  
Fluidised Bed ◽  
Raw Water ◽  
Biological Pretreatment ◽  
Manganese Removal ◽  
Time Required

Experimental studies on chemical and biological pretreatments in membrane filtration processes were carried out to removal manganese contained in raw water and to prevent membrane fouling due to manganese. Two types of the pretreatment reactors, i.e. the fluidised-bed and fixed-bed configurations, were compared in the biological pretreatment experiments. New synthetic media (tubular polypropylene, I.D. 3 mm, O.D. 4 mm, length 5 mm) were used in all three experiments as a manganese-oxidising catalyst. The chemical pretreatment using sodium hypochlorite was effective in manganese removal and controlling membrane fouling; more than 0.8 mg-Cl2/L of chlorine dose was necessary to bring the manganese concentration from 0.4 mg/L in raw water to less than 0.05 mg/L. The biological pretreatment for manganese removal required a long start-up period of more than 40 days. The fixed-bed biological pretreatment was superior in manganese removal and in control of membrane fouling to the fluidised-bed biological pretreatment, which showed wash-out of the attached bacteria resulting in membrane fouling. The linear velocity and the empty-bed retention time required for the treatment of 0.14 mg-Mn/L in the fixed-bed biological pretreatment was 206 m/d and 8.0 minutes, respectively.

Treatment of highly-colored surface water by a hybrid microfiltration membrane system incorporating ion-exchange

2018 ◽  
Vol 19 (3) ◽  
pp. 855-863 ◽  
Author(s):  
T. Miyoshi ◽  
Y. Takahashi ◽  
T. Suzuki ◽  
R. Nitisoravut ◽  
C. Polprasert
Keyword(s):  
Surface Water ◽  
Hybrid System ◽  
Membrane Fouling ◽  
Membrane Filtration ◽  
Membrane System ◽  
Pilot Scale ◽  
Manganese Concentration ◽  
Moderate Increase ◽  
Coagulant Dosage ◽  
Filtration System

Abstract This study investigated the performance of a hybrid membrane filtration system to produce industrial water from highly-colored surface water. The system consists of a membrane filtration process with appropriate pretreatments, including coagulation, pre-chlorination, and anion exchange (IE) process. The results of the pilot-scale experiments revealed that the hybrid system can produce treated water with color of around 5 Pt-Co, dissolved manganese concentration of no more than 0.05 mg/L, and a silt density index (SDI) of no more than 5 when sufficient coagulant and sodium hypochlorite were dosed. Although the IE process effectively reduced the color of the water, a moderate increase in the color of the IE effluent was observed when there was a significant increase in the color of the raw water. This resulted in a severe membrane fouling, which was likely to be attributed to the excess production of inorganic sludge associated with the increased coagulant dosage required to achieve sufficient reduction of color. Such severe membrane fouling can be controlled by optimising the backwashing and relaxation frequencies during the membrane filtration. These results indicate that the hybrid system proposed is a suitable technology for treating highly-colored surface water.

Iron and manganese removal by a membrane filtration system

2001 ◽  
Vol 1 (5-6) ◽  
pp. 357-364 ◽  
Author(s):  
Y. Jimbo ◽  
K. Goto
Keyword(s):  
Membrane Filtration ◽  
Manganese Concentration ◽  
Sand Filtration ◽  
Design Standards ◽  
Manganese Removal ◽  
Filtration System ◽  
Small Capacity ◽  
Rapid Sand Filtration ◽  
Removal System ◽  
Iron And Manganese

The design standards of the iron and manganese removal system by membrane filtration were investigated. The membrane filtration after pre-chlorination could remove iron completely and could remove around 70% of manganese. In the case of manganese concentration being more than 0.05 mg/l, the membrane filtration could remove them completely after the deposition in the oxidation tank. The concentrations of iron and manganese were reduced more than 90% by the oxidation tank and were reduced until under the detection limit after the membrane filtration. The economic comparisons between the rapid sand filtration system and this membrane filtration system in a small capacity and a middle capacity were investigated. The 15 years total costs of the membrane filtration system were estimated to be smaller than or around equal to the rapid sand filtration system in both capacities.

Evaluating the membrane fouling formation and chemical cleaning strategy in forward osmosis membrane filtration treating domestic sewage

2018 ◽  
Vol 4 (12) ◽  
pp. 2092-2103 ◽  
Author(s):  
Nur Hafizah Ab Hamid ◽  
Liu Ye ◽  
David K. Wang ◽  
Simon Smart ◽  
Emmanuelle Filloux ◽  
...  
Keyword(s):  
Membrane Fouling ◽  
Nitrous Acid ◽  
Membrane Filtration ◽  
Forward Osmosis ◽  
Domestic Sewage ◽  
Chemical Cleaning ◽  
Free Nitrous Acid ◽  
Fouling Control ◽  
Filtration System ◽  
Time Required

Free nitrous acid (FNA) shows strong potential as an effective cleaning reagent in fouling control in a forward osmosis filtration system, with a relatively longer time required.

scholarly journals Raw Water Storage as a Simple Means for Controlling Membrane Fouling Caused by Inorganic Foulants in River Water in a Tropical Region

Water ◽  
2019 ◽  
Vol 11 (8) ◽  
pp. 1592
Author(s):  
Hashimoto ◽  
Gunawan ◽  
Wattanachira ◽  
Wongrueng ◽  
Takizawa
Keyword(s):  
Organic Carbon ◽  
River Water ◽  
Membrane Fouling ◽  
Membrane Filtration ◽  
Natural Waters ◽  
Water Storage ◽  
Storage Period ◽  
Tropical Region ◽  
Raw Water ◽  
Inorganic Substances

Natural waters in tropical countries are turbid and rich in inorganic substances such as iron and manganese. Hence, membrane fouling by these inorganic substances is the most serious problem in membrane filtration processes for potable water production. This study aimed to assess raw water storage as a simple but effective means for controlling membrane fouling in the filtration of river water in a tropical country. Raw water taken from the Ping River in Chiang Mai, Thailand, in different seasons, was either immediately filtered or stored in a tank for two days before filtration through a polyvinylidene difluoride (PVDF) membrane with a nominal pore size of 0.1 μm. The turbidity and particulate organic carbon (POC) in the raw water were reduced by storage, while dissolved manganese was oxidized during the storage period. Although the amounts of metallic substances retained on membranes were larger than those of silica and organic matter, their contribution to the fouling resistance was found to be less than silica and organic carbon. The fouling analysis using hydraulically irreversible fouling index (HIFI) was found to be not able to measure the effects of storage when the initial flux increased. Hence, the ratio of the hydraulically reversible fouling index (HRFI) to the total fouling index (TFI), i.e., HRFI/TFI, was proposed to elucidate the effects of raw water storage on membrane fouling, which was manifest during the early stage of membrane filtration operation.

Pilot-plant study of a high recovery membrane filtration process for drinking water treatment

2000 ◽  
Vol 41 (10-11) ◽  
pp. 77-84 ◽  
Author(s):  
J.Y. Huang ◽  
S. Takizawa ◽  
K. Fujita
Keyword(s):  
Membrane Fouling ◽  
Membrane Filtration ◽  
Cross Flow ◽  
Drinking Water Treatment ◽  
Pilot Scale ◽  
Raw Water ◽  
Circulation Flow ◽  
High Recovery ◽  
Chemical Cleaning ◽  
Cross Flow Filtration

Successful application of energy efficient dead-end micro-filtration (MF), which does not require recirculation like cross-flow filtration, depends on achieving high recovery rates. In this study, two different types of pilot scale membrane systems (horizontally and vertically stretched membrane filters) were evaluated based on the effects of pre-chlorination, intermittent chlorination and circulation flow by air-scrubbing. Additionally, the effects of operating factors including physical cleaning and chemical cleaning on membrane fouling were examined. The vertically stretched membranes showed better performance than horizontally stretched membranes at filtration fluxes of either 0.55 m/day or 0.78 m/day even under 2.6 to 27.5°C and raw water turbidity higher than 300 units, as long as intermittent chlorination (10 mg/l once a week) along with the circulation flow by air-scrubbing (once in 30 minutes) in the housing were employed. It was demonstrated that the vertically stretched membranes have been operated for one year without chemical cleaning of the membranes, wherein the recovery of raw water as a filtrate was 97.0% or 98.9%.

Membrane filtration of surface water in the presence of ozone

2001 ◽  
Vol 1 (5-6) ◽  
pp. 141-150 ◽  
Author(s):  
S. Sawada ◽  
I. Sumida ◽  
K. Matsumoto
Keyword(s):  
Organic Matter ◽  
Activated Carbon ◽  
Humic Acid ◽  
Membrane Fouling ◽  
Membrane Filtration ◽  
Membrane Surface ◽  
Dominant Factor ◽  
Stable Operation ◽  
Raw Water ◽  
Pre Treatment

The preliminary study investigated the effect of pre-ozonation of synthetic raw water (bentonite and humic acid) on membrane fouling. The results showed that humic acid, not bentonite, was the dominant factor in membrane fouling. When the synthetic raw water was pre-treated using ozone and activated carbon, stable operation was possible at twice the flux of membrane filtration without pre-treatment. Thus, ozone and activated carbon reduced the concentration of organic matter (humic acid), leading to an increase in flux. Secondly, an MF membrane filtration device with ozone tolerance was attached downstream of the ozone reactor so that residual ozone could reach the membrane surface. When water was treated with MF membrane filtration in the presence of ozone, the flux was stable at 4 m/d. The membrane filtration resistance increased when ozone was not injected, and decreased when it was injected. This phenomenon was repeatable. In the presence of ozone, organic matter that could accelerate fouling as decomposed and converted to less fouled materials, resulting in a suppression of fouling as well as facilitating removal of the fouling layer during back washing.

Removal of ammonia by natural clay minerals using fixed and fluidised bed column reactors

2001 ◽  
Vol 1 (1) ◽  
pp. 81-88 ◽  
Author(s):  
M.S. Çelik ◽  
B. Özdemir ◽  
M. Turan ◽  
I. Koyuncu ◽  
G. Atesok ◽  
...  
Keyword(s):  
Ion Exchange ◽  
Clay Minerals ◽  
Fixed Bed ◽  
Water Reservoir ◽  
Fluidised Bed ◽  
Raw Water ◽  
Natural Clay ◽  
Exchange Column ◽  
Ion Exchange Column ◽  
Synthetic Water

A series of fixed and fluidised bed ion exchange column runs were conducted to identify the ability of natural clay minerals, sepiolite and clinoptilolite, to remove ammonia from a contaminated drinking water reservoir. Ion exchange column tests using both fixed and fluidised bed were initially carried out with synthetic water composed of NH4Cl. Breakthrough curves as a function of flow rate, particle size, and initial ammonia concentration reveal that sepiolite does not have as high ion exchange capacity as clinoptilolite but maintains a steady adsorption up to higher bed volumes. The adsorption capacity was modified by using regeneration cycles at both acidic and alkaline pH. Furthermore, fluidised bed runs with clinoptilolite utilising water and air as fluidiser resulted in inferior results compared to those of fixed bed runs. This was respectively ascribed to the presence of ammonia in the circulating water and competition of exchangeable ions released in water and the ability of air to adsorb nitrogen. Tests conducted with natural raw water contaminated with sewage indicated that clinoptilolite adsorbs ammonia the same as the synthetic water. Regenerated clinoptilolite is capable of removing ammonia from both synthetic and actual raw water at a much higher rate than the untreated clinoptilolite.

Leading the City of Baltimore into the 21st Century: Flexible Treatment Solutions and Integrated Raw Water Management

2010 ◽  
Vol 5 (4) ◽  
Author(s):  
J. L. Manuszak ◽  
M. MacPhee ◽  
S. Liskovich ◽  
L. Feldsher
Keyword(s):  
Water Management ◽  
Water Quality ◽  
Water Supply ◽  
Conceptual Design ◽  
Membrane Filtration ◽  
Treatment Plant ◽  
Low Pressure ◽  
Management Tool ◽  
Raw Water ◽  
The City

The City of Baltimore, Maryland is one of many US cities faced with challenges related to increasing potable water demands, diminishing fresh water supplies, and aging infrastructure. To address these challenges, the City recently undertook a $7M study to evaluate water supply and treatment alternatives and develop the conceptual design for a new 120 million gallon per day (MGD) water treatment plant. As part of this study, an innovative raw water management tool was constructed to help model source water availability and predicted water quality based on integration of a new and more challenging surface water supply. A rigorous decision-making approach was then used to screen and select appropriate treatment processes. Short-listed treatment strategies were demonstrated through a year-long pilot study, and process design criteria were collected in order to assess capital and operational costs for the full-scale plant. Ultimately the City chose a treatment scheme that includes low-pressure membrane filtration and post-filter GAC adsorption, allowing for consistent finished water quality irrespective of which raw water supply is being used. The conceptual design includes several progressive concepts, which will: 1) alleviate treatment limitations at the City's existing plants by providing additional pre-clarification facilities at the new plant; and 2) take advantage of site conditions to design and operate the submerged membrane system by gravity-induced siphon, saving the City significant capital and operations and maintenance (O&M) costs. Once completed, the new Fullerton Water Filtration Plant (WFP) will be the largest low-pressure membrane plant in North America, and the largest gravity-siphon design in the world.

Coagulation/flocculation/ultrafiltration for natural organic matter removal in drinking water production

2004 ◽  
Vol 4 (5-6) ◽  
pp. 215-222 ◽  
Author(s):  
A.R. Costa ◽  
M.N. de Pinho
Keyword(s):  
Drinking Water ◽  
Organic Matter ◽  
Natural Organic Matter ◽  
Membrane Fouling ◽  
Membrane Filtration ◽  
Membrane Surface ◽  
Water Production ◽  
Cellulose Acetate Membranes ◽  
Wide Range ◽  
Drinking Water Production

Membrane fouling by natural organic matter (NOM), namely by humic substances (HS), is a major problem in water treatment for drinking water production using membrane processes. Membrane fouling is dependent on membrane morphology like pore size and on water characteristics namely NOM nature. This work addresses the evaluation of the efficiency of ultrafiltration (UF) and Coagulation/Flocculation/UF performance in terms of permeation fluxes and HS removal, of the water from Tagus River (Valada). The operation of coagulation with chitosan was evaluated as a pretreatment for minimization of membrane fouling. UF experiments were carried out in flat cells of 13.2×10−4 m2 of membrane surface area and at transmembrane pressures from 1 to 4 bar. Five cellulose acetate membranes were laboratory made to cover a wide range of molecular weight cut-off (MWCO): 2,300, 11,000, 28,000, 60,000 and 75,000 Da. Severe fouling is observed for the membranes with the highest cut-off. In the permeation experiments of raw water, coagulation prior to membrane filtration led to a significant improvement of the permeation performance of the membranes with the highest MWCO due to the particles and colloidal matter removal.

Predictability of fouling-potential of raw water for ultrafiltration membranes

2011 ◽  
Vol 11 (4) ◽  
pp. 481-489
Author(s):  
S. Krause ◽  
A. Obermayer
Keyword(s):  
Water Quality ◽  
Membrane Fouling ◽  
Large Scale ◽  
High Capacity ◽  
Raw Water ◽  
Ultrafiltration Membranes ◽  
Small Water ◽  
Lab Experiments ◽  
Flux Decline ◽  
Public Drinking Water

The public drinking water supply of southern Germany is characterized by a rather decentralized network. Due to the hydrogeological setting in these parts of Germany many of the small water works with an average capacity of 50 m3/h have to treat raw water extracted from karstic or cliffy aquifers. These raw waters tend to be contaminated with particles and pathogens acquired during snowmelt or after strong rainfalls. In the last decade ultrafiltration has become the technology of choice for the removal of the aforementioned contaminants. Flux decline caused by unanticipated membrane fouling is the main limitation for the application of ultrafiltration membranes. This paper describes how membrane fouling phenomena can be predicted by using a statistical approach based on data from large scale filtration systems in combination with field and lab experiments on raw water quality and membrane performance. The data defines water quality and respective fouling phenomena both in technical scale filtration plants and in lab experiments of eleven different raw waters. The method described here is more economically feasible for small water works when compared to typical pilot experiments that are used for high capacity water works.

Sign in / Sign up

Export Citation Format

Share Document