scholarly journals Isothermal, kinetics and thermodynamics studies of the biosorption of Pb(II) ion from aqueous solution using the scale of croaker fish (Genyonemus lineatus)

2013 ◽  
Vol 3 (3) ◽  
pp. 239-248
Author(s):  
Mojisola O. Nkiko ◽  
Abideen I. Adeogun ◽  
N. A. Adesola Babarinde ◽  
Oluwabunmi J. Sharaibi
Keyword(s):  
Aqueous Solution ◽  
Metal Ion ◽  
Sorption Process ◽  
Ion Concentration ◽  
Isothermal Kinetics ◽  
Fish Scale ◽  
Biosorption Process ◽  
Equilibrium Data ◽  
Pseudo Second Order ◽  
Biomass Dosage

Biosorbent prepared from the scale of croaker fish (Genyonemus lineatus) has been used for the removal of Pb(II) ion from aqueous solution in a batch system. The effects of some important parameters such as pH, initial metal concentration, temperature and biosorbent dosage on biosorption capacity were investigated. Equilibrium time for the biosorption process is 20 and 30 min at lower and higher concentrations, respectively. The process at 28 °C is in agreement with a pseudo-second-order kinetics model. The equilibrium data obeyed the Langmuir adsorption isotherm with a maximum monolayer adsorption capacity of 14.58 mg g−1. The study showed that the sorption process depends on biomass dosage, temperature, pH and initial metal ion concentration. The calculated thermodynamics parameters (ΔGo, ΔHo and ΔSo) indicated that the biosorption of the metal ion onto fish scale is feasible, spontaneous and exothermic in nature.

scholarly journals Development of Wood Apple Shell (Feronia acidissima) Powder Biosorbent and Its Application for the Removal of Cd(II) from Aqueous Solution

2014 ◽  
Vol 2014 ◽  
pp. 1-8 ◽  
Author(s):  
Ch. Suresh ◽  
D. Harikisore Kumar Reddy ◽  
Yapati Harinath ◽  
B. Ramesh Naik ◽  
K. Seshaiah ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Metal Ion ◽  
Ion Concentration ◽  
Isotherm Models ◽  
X Ray Diffraction ◽  
Biosorption Process ◽  
Initial Ph ◽  
Carboxylic Groups ◽  
Pseudo Second Order ◽  
Complexation Reactions

A biosorbent was prepared by using wood apple shell (WAS) powder and studied its application for the removal of Cd(II) from aqueous solution by a batch method. The biosorbent was characterized by infrared spectroscopy, X-ray diffraction, scanning electron microscopy, and elemental analysis. WAS is principally made up of lignin and cellulose, containing functional groups such as alcoholic, ketonic, and carboxylic groups which can be involved in complexation reactions with Cd(II). The effect of experimental parameters like initial pH, contact time, metal ion concentration, and sorbent dose on adsorption was investigated. The optimum pH for biosorption of Cd(II) onto WAS was found to be pH 5.0 and the quantitative removal of Cd(II) ions was achieved in 30 min. The kinetic study showed that the biosorption process followed the pseudo-second-order rate. Experimental data were analyzed by Langmuir, Freundlich, and Dubinin-Radushkevich isotherm models. Desorption studies were carried out using HCl solution.

Characteristics of sorption of uncomplexed and complexed Pb(II) from aqueous solutions onto peat

2012 ◽  
Vol 66 (4) ◽  
Author(s):  
Laura Bulgariu ◽  
Dumitru Bulgariu ◽  
Matei Macoveanu
Keyword(s):  
Aqueous Solution ◽  
Metal Ion ◽  
Sorption Process ◽  
Ion Concentration ◽  
Complexing Agents ◽  
Hydroxyl Groups ◽  
Mechanism Analysis ◽  
Maximum Sorption ◽  
Initial Ph ◽  
Equilibrium Data

AbstractBatch experiments aimed at the sorption of Pb(II) onto peat were performed from an aqueous solution in both the absence and presence of common complexing agents (acetate or citrate). The influence of the initial pH of the solution, metal ion concentration and contact time on the sorption efficiency of Pb(II) was examined at ambient temperature (18 ± 0.5) °C for each experiment. The results showed that the presence of acetate improved the efficiency of the sorption process, while the presence of citrate in the aqueous solution decreased the efficiency of the Pb(II) sorption onto peat. The equilibrium data fitted well with the Langmuir isotherm model and confirmed the monolayer sorption of uncomplexed and complexed Pb(II) species onto peat. The values of maximum sorption capacities (q max) were 135.13 mg g−1 for Pb(II) complexed with acetate, q > 79.36 mg g−1 for uncomplexed Pb, q > 38.46 mg g−1 for Pb(II) complexed with citrate. The kinetics of Pb(II) sorption onto peat, in both the absence and presence of complexing agents, indicated a pseudosecond order mechanism. Analysis of IR spectra showed that carboxylic and hydroxyl groups had an important role in the binding process of Pb(II) species onto peat.

Chemically Modified Lagenaria vulgaris as a Biosorbent for the Removal of CuII from Water

2013 ◽  
Vol 66 (2) ◽  
pp. 227 ◽  
Author(s):  
Maja N. Stanković ◽  
Nenad S. Krstić ◽  
Ian J. Slipper ◽  
Jelena Z. Mitrović ◽  
Miljana D. Radović ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Metal Ion ◽  
Sorption Process ◽  
Ion Concentration ◽  
Linear Regression Method ◽  
Order Kinetic ◽  
Maximum Sorption Capacity ◽  
Chemically Modified ◽  
Biomass Dosage ◽  
Lagenaria Vulgaris

The ability of a biosorbent based on a chemically modified Lagenaria vulgaris shell for CuII ion removal from aqueous solution was studied in batch conditions. The biosorbent was characterized by Fourier-transform infrared spectroscopy and the effect of relevant parameters such as contact time, pH, biomass dosage, and initial metal ion concentration was evaluated. The sorption process was found to be fast, attaining equilibrium within 40 min, and results were found to be best fitted by a pseudo-second order kinetic model. Experimental data showed that the biosorption is highly pH dependent, and the optimal pH was 5.0. Results were analyzed in terms of the following adsorption isotherms: Langmuir, Freundlich, Temkin, and Flory–Huggins, by a linear regression method. The CuII biosorption followed the Langmuir isotherm model (r2 = 0.998) with the maximum sorption capacity of 14.95 mg g–1. The methyl-sulfonated Lagenaria vulgaris biomass investigated in this study exhibited a high potential for the removal of CuII from aqueous solution.

scholarly journals Eco-Efficient Biosorbent Based on Leucaena leucocephala Residues for the Simultaneous Removal of Pb(II) and Cd(II) Ions from Water System: Sorption and Mechanism

2019 ◽  
Vol 2019 ◽  
pp. 1-13 ◽  
Author(s):  
C. A. Cimá-Mukul ◽  
Youness Abdellaoui ◽  
Mohamed Abatal ◽  
Joel Vargas ◽  
Arlette A. Santiago ◽  
...  
Keyword(s):  
Leucaena Leucocephala ◽  
Metal Ion ◽  
Water System ◽  
Ion Concentration ◽  
Point Of Zero Charge ◽  
Southern Mexico ◽  
Lead And Cadmium ◽  
Biosorption Process ◽  
Monolayer Adsorption ◽  
Pseudo Second Order

Leucaena leucocephala is a potential source of polyphenols widely available in southern Mexico. This work highlights the extraction of polyphenols from Leucaena leucocephala leaves waste (LLEPs) and the evaluation of their efficiency to remove the single and multicomponent Pb(II) and Cd(II) metal ions from aqueous solutions. Batch test conditions were carried out to examine the effects of contact time, initial metal ion concentration, and adsorbent dosage on the biosorption process. The surface textures and the composition of the LLEP biosorbent was characterized using pH of point of zero charge (pHPZC), attenuated total reflectance Fourier transform infrared (ATR-FTIR), and matrix-assisted laser desorption/ionization time of flight (MALDI-TOF) mass spectrometry, respectively. Further analysis using ATR-FTIR after adsorption contact of biosorbent was also investigated. The highest Langmuir saturation monolayer adsorption capacity, qm, for the removal of Pb(II) by LLEPs was obtained as 25.51 and 21.55 mg/g in mono- and bimetal solutions, respectively. The pseudo-second-order model provided the best fit for the kinetic data obtained for the removal of Pb(II), Cd(II), and their mixture, and the k2 values depend on the adsorbent mass. This implied that the chemisorption process might be the mechanism of the solute ions-LLEPs interaction in this study. Furthermore, nearly 100% removal of lead and cadmium individually and 95% of their mixture was found using 0.9 g of LLEPs.

scholarly journals Removal of Fe2+, Zn2+ and Mn2+ ions from the mining wastewater by lemon peel waste

2020 ◽  
Vol 85 (10) ◽  
pp. 1371-1382
Author(s):  
Sladjana Meseldzija ◽  
Jelena Petrovic ◽  
Antonije Onjia ◽  
Tatjana Volkov-Husovic ◽  
Aleksandra Nesic ◽  
...  
Keyword(s):  
Aqueous Solutions ◽  
Metal Ion ◽  
Sorption Process ◽  
Ion Concentration ◽  
Hno3 Solution ◽  
Lemon Peel ◽  
Maximum Sorption ◽  
Equilibrium Data ◽  
Desorption Study ◽  
Mining Wastewater

This study is aimed to evaluate the possibility of lemon peel, as an agro-industrial waste, to remove Fe2+, Zn2+ and Mn2+ from single aqueous solutions and mining wastewater. For this purpose, the influence of various parameters: sorption time, initial pH solution, initial metal ion concentration and a dose of sorbent on the sorption process were studied in batch experiments. The experimental equilibrium data have been analysed utilizing linearized forms of Langmuir, Freundlich, Temkin and Dubinin?Radushkevich isotherms. The Langmuir isotherm provided the best theoretical correlation of the experimental equilibrium data for Fe2+, Zn2+ and Mn2+, with the maximum sorption capacities of 4.40, 5.03 and 4.52 mg g-1, respectively. The percentage of targeted ions removal from single aqueous solutions was 92.9 % (Zn2+), 84.5 % (Fe2+) and 78.2 % (Mn2+). Regarding the sorption capability of lemon peel in mining wastewater, the maximum removal of Fe2+, Zn2+ and Mn2+ from mining wastewater was 49.62, 33.97 and 9.11 %, respectively. In addition, the potential reusability of the lemon peel as sorbent was investigated through desorption study in 0.1M of CH3COO4, HCl and HNO3 solution. The highest rate of desorption was achieved in 0.1 M HCl solution, reached a value of 55.19 % for Mn2+ and 37.24 % for Zn2+, while for Fe2+ the highest value of 25.82 % was achieved in 0.1M HNO3 solution.

scholarly journals (3-Aminopropyl) Triethoxysilane (APTES) Functionalized Magnetic Nanosilica Graphene Oxide (MGO) Nanocomposite for the Comparative Adsorption of the Heavy Metal (Pb(II), Cd(II) and Ni(II)) ions from Aqueous Solution

2021 ◽  
Author(s):  
C Donga ◽  
S Mishra ◽  
A Aziz ◽  
L Ndlovu ◽  
A Kuvarega ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Graphene Oxide ◽  
Metal Ion ◽  
Ion Concentration ◽  
Batch Adsorption ◽  
Solution Ph ◽  
Magnetic Graphene Oxide ◽  
Equilibrium Data ◽  
Langmuir Isotherm Model ◽  
Adsorption Equilibrium Data

Abstract (3-aminopropyl) triethoxysilane (APTES) modified magnetic graphene oxide was synthesized and applied in the adsorption of three heavy metals, Pb(II), Cd(II) and Ni(II) from aqueous solution. An approach to prepare magnetic GO was adopted by using (3-aminopropyl) triethoxysilane (APTES) as a functionalizing agent on magnetic nanosilica coupled with GO to form the Fe3O4@SiO2-NH2/GO nanocomposite. FT-IR, XRD, BET, UV, VSM, SAXS, SEM and TEM were used to characterize the synthesized nanoadsorbents. Batch adsorption studies were conducted to investigate the effect of solution pH, initial metal ion concentration, adsorbent dosage and contact time. The maximum equilibrium time was found to be 30 min for Pb(II), Cd(II) and 60 min for Ni(II). The kinetics studies showed that the adsorption of Pb(II), Cd(II) and Ni(II) onto Fe3O4@SiO2-NH2/GO followed the pseudo-second-order kinetics. All the adsorption equilibrium data were well fitted to Langmuir isotherm model and maximum monolayer adsorption capacity for Pb(II), Cd(II) and Ni(II) were 13.46, 18.58 and 13.52 mgg-1, respectively. The Fe3O4@SiO2-NH2/GO adsorbents were reused for at least 7 cycles without the leaching of mineral core, showing the enhanced stability and potential application of Fe3O4@SiO2-NH2/GO adsorbents in water/wastewater treatment.

scholarly journals Thermodynamic Study on the Adsorption of Pb2+and Zn2+From Aqueous Solution by Human Hair

2010 ◽  
Vol 7 (4) ◽  
pp. 1296-1303 ◽  
Author(s):  
A. S. Ekop ◽  
N. O. Eddy
Keyword(s):  
Aqueous Solution ◽  
Human Hair ◽  
Contact Time ◽  
Metal Ion ◽  
Ion Concentration ◽  
Optimum Conditions ◽  
Batch System ◽  
Freundlich Adsorption Isotherm ◽  
Equilibrium Data ◽  
Adsorption Equilibrium Data

Adsorption of Pb(II) and Zn(II) ions from aqueous solutions was studied in a batch system using modified human hair. The optimum conditions for the adsorption of Pb(II) and Zn(II) ions from aqueous solution by human hair were investigated by considering the extent of adsorption with respect to contact time, initial metal ion concentration and temperature. The results obtained indicates that the extent of metal ions removed decreases with increasing contact time but increased with increase in the initial metal ion concentration. The adsorption equilibrium data best fitted Freundlich adsorption isotherm. The adsorption of Pb(II) and Zn(II) ions onto human hair is endothermic, spontaneous and is characterised by increasing degree of orderliness.

scholarly journals Preparation and characterization of chitosan/Fe2O3 nano composite for the adsorption of thorium (IV) ion from aqueous solution

2018 ◽  
Vol 78 (3) ◽  
pp. 708-720 ◽  
Author(s):  
B. Rouhi Broujeni ◽  
A. Nilchi ◽  
A. H. Hassani ◽  
R. Saberi
Keyword(s):  
Aqueous Solution ◽  
Adsorption Capacity ◽  
Metal Ion ◽  
Ion Concentration ◽  
P Value ◽  
X Ray Diffraction ◽  
Nano Composite ◽  
Statistical Measures ◽  
Pseudo Second Order

Abstract In this study, novel chitosan/Fe2O3nano composite Ch/Fe-Onc was synthesized and evaluated as an adsorbent for removing thorium (IV) (Th4+) ion from aqueous solution. The Ch/Fe-Onc was characterized by X-ray diffraction (XRD), Brunauer–Emmett–Teller (BET), Fourier transform infrared (FTIR) and scanning electron microscopy (SEM). Response surface methodology (RSM) was used in the optimization of Th4+ adsorption for parameters such as pH, the initial metal ion concentration (Th4+ concentration) and contact time. The statistical measures (i.e. analysis of variance, R2, the lack of fit test and the P value) specify that the developed model is proper. Furthermore, the adsorption kinetics was well defined by the pseudo-second-order equation, while the adsorption isotherms were better fitted by the Langmuir model. The adsorption capacity of Ch/Fe-Onc was 430 mg Th4+g−1 composite which leads to 99% removal at 25 °C. Moreover, thermodynamic parameters which state the natural and endothermic nature of the reactions were determined. The loaded Th4+ can be easily regenerated with HNO3 and the Ch/Fe-Onc can be used repeatedly without any significant reduction in its adsorption capacity. The desorption level of Th4+ from the Ch/Fe-Onc by using 0.1 M HNO3, was more than 95%.

scholarly journals Phragmites karkaas a Biosorbent for the Removal of Mercury Metal Ions from Aqueous Solution: Effect of Modification

2015 ◽  
Vol 2015 ◽  
pp. 1-12 ◽  
Author(s):  
Muhammad Hamid Raza ◽  
Aqsa Sadiq ◽  
Umar Farooq ◽  
Makshoof Athar ◽  
Tajamal Hussain ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Metal Ion ◽  
Freundlich Isotherm ◽  
Agitation Speed ◽  
Second Order ◽  
Ion Concentration ◽  
Order Kinetic ◽  
Order Kinetic Model ◽  
Pseudo Second Order ◽  
Phragmites Karka

Batch scale studies for the adsorption potential of novel biosorbentPhragmites karka(Trin), in its natural and treated forms, were performed for removal of mercury ions from aqueous solution. The study was carried out at different parameters to obtain optimum conditions of pH, biosorbent dose, agitation speed, time of contact, temperature, and initial metal ion concentration. To analyze the suitability of the process and maximum amount of metal uptake, Dubinin-Radushkevich (D-R) model, Freundlich isotherm, and Langmuir isotherm were applied. The values ofqmaxfor natural and treated biosorbents were found at 1.79 and 2.27 mg/g, respectively. The optimum values of contact time and agitation speed were found at 50 min and 150 rpm for natural biosorbent whereas 40 min and 100 rpm for treated biosorbent, respectively. The optimum biosorption capacities were observed at pH 4 and temperature 313 K for both naturalP. karkaand treatedP. karka.RLvalues indicate that comparatively treatedP. karkawas more feasible for mercury adsorption compared to naturalP. karka. Both pseudo-first-order and pseudo-second-order kinetic models were applied and it was found that data fit best to the pseudo-second-order kinetic model. Thermodynamic studies indicate that adsorption process was spontaneous, feasible, and endothermic.

scholarly journals Biosorption of nickel (II) and zinc (II) from aqueous solutions by the biomass of yeast Yarrowia lipolytica

2017 ◽  
Vol 19 (1) ◽  
pp. 1-10 ◽  
Author(s):  
Sławomir Wierzba
Keyword(s):  
Metal Ions ◽  
Yarrowia Lipolytica ◽  
Freundlich Isotherm ◽  
Isotherm Models ◽  
Biosorption Process ◽  
Equilibrium Data ◽  
Pseudo Second Order ◽  
Amine Groups ◽  
Biomass Dosage ◽  
Yeast Yarrowia Lipolytica

Abstract This study examined the biosorption process of Ni(II) and Zn(II) from an aqueous solution by dead biomass of Yarrowia lipolytica. Optimum biosorption conditions were determined as a function of pH, biomass dosage, contact time, and temperature. The biosorbent was characterized by FTIR, which indicated the participation of hydroxyl, carboxyl, amide and amine groups in the process of binding the metal ions. The results showed that the biosorption processes of both metal ions closely followed pseudo-second order kinetics. The equilibrium data of Ni(II) and Zn(II) ions at 20, 30 and 40°C fitted the Langmuir and Freundlich isotherm models. Langmuir isotherm provided a better fit to the equilibrium data, with a maximum biosorption capacity of the Y. lipolytica biomass for Ni(II) and Zn(II) of 30.12 and 44.44 mg/g respectively. The calculated thermodynamic parameters demonstrated that the biosorption of Ni(II) and Zn(II) ions onto the Y. lipolytica was feasible, spontaneous and endothermic.

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