scholarly journals Application of response surface methodology to optimize the COD removal efficiency of an EGSB reactor treating poultry slaughterhouse wastewater

2019 ◽  
Vol 14 (3) ◽  
pp. 507-514 ◽  
Author(s):  
Y. Williams ◽  
M. Basitere ◽  
S. K. O. Ntwampe ◽  
M. Ngongang ◽  
M. Njoya ◽  
...  
Keyword(s):  
Response Surface Methodology ◽  
Response Surface ◽  
Removal Efficiency ◽  
Treatment Process ◽  
High Strength ◽  
Cod Removal ◽  
Organic Loading Rate ◽  
Wastewater Treatment Process ◽  
Slaughterhouse Wastewater ◽  
Cod Removal Efficiency

Abstract The poultry slaughterhouse industry consumes a large volume of potable water for bird processing and equipment cleaning, which culminates in the generation of high strength poultry slaughterhouse wastewater (PSW). The wastewater contains high concentrations of organic matter, suspended solids, nitrogen and nutrients. Most poultry slaughterhouses in South Africa (SA) discharge their wastewater into the municipal sewer system after primary treatment. Due to its high strength, PSW does not meet SA's industrial discharge standards. Discharge of untreated PSW to the environment raises environmental health concerns due to pollution of local rivers and fresh water sources, leading to odour generation and the spread of diseases. Thus, the development of a suitable wastewater treatment process for safe PSW discharge to the environment is a necessity. In this study, a biological PSW treatment process using an Expanded Granular Sludge Bed (EGSB) was evaluated. Response surface methodology coupled with central composite design was used to optimize the performance of the EGSB reactor. The dependant variable used for optimization was chemical oxygen demand (COD) removal as a function of two independent variables, hydraulic retention time (HRT) and organic loading rate (OLR). The interactions between HRT, OLR and COD removal were analysed, and a two factorial (2FI) regression was determined as suitable for COD removal modelling. The optimum COD removal of 93% was achieved at an OLR of 2 g-COD/L/d and HRT of 4.8 days. The model correlation coefficient (R2) of 0.980 indicates that it is a good fit and is suitable for predicting the EGSB's COD removal efficiency.

Electrocoagulation and nanofiltration integrated process application in purification of bilge water using response surface methodology

2016 ◽  
Vol 74 (3) ◽  
pp. 564-579 ◽  
Author(s):  
Ceyhun Akarsu ◽  
Yasin Ozay ◽  
Nadir Dizge ◽  
H. Elif Gulsen ◽  
Hasan Ates ◽  
...  
Keyword(s):  
Response Surface Methodology ◽  
Response Surface ◽  
Removal Efficiency ◽  
Cod Removal ◽  
Positive Sign ◽  
Aluminum Electrode ◽  
Integrated Process ◽  
Bilge Water ◽  
Cod Removal Efficiency ◽  
Initial Ph

Marine pollution has been considered an increasing problem because of the increase in sea transportation day by day. Therefore, a large volume of bilge water which contains petroleum, oil and hydrocarbons in high concentrations is generated from all types of ships. In this study, treatment of bilge water by electrocoagulation/electroflotation and nanofiltration integrated process is investigated as a function of voltage, time, and initial pH with aluminum electrode as both anode and cathode. Moreover, a commercial NF270 flat-sheet membrane was also used for further purification. Box–Behnken design combined with response surface methodology was used to study the response pattern and determine the optimum conditions for maximum chemical oxygen demand (COD) removal and minimum metal ion contents of bilge water. Three independent variables, namely voltage (5–15 V), initial pH (4.5–8.0) and time (30–90 min) were transformed to coded values. The COD removal percent, UV absorbance at 254 nm, pH value (after treatment), and concentration of metal ions (Ti, As, Cu, Cr, Zn, Sr, Mo) were obtained as responses. Analysis of variance results showed that all the models were significant except for Zn (P > 0.05), because the calculated F values for these models were less than the critical F value for the considered probability (P = 0.05). The obtained R2 and Radj2 values signified the correlation between the experimental data and predicted responses: except for the model of Zn concentration after treatment, the high R2 values showed the goodness of fit of the model. While the increase in the applied voltage showed negative effects, the increases in time and pH showed a positive effect on COD removal efficiency; also the most effective linear term was found as time. A positive sign of the interactive coefficients of the voltage–time and pH–time systems indicated synergistic effect on COD removal efficiency, whereas interaction between voltage and pH showed an antagonistic effect.

scholarly journals Investigating the Result of Current Density, Temperature, and Electrolyte Concentration on COD: Subtraction of Petroleum Refinery Wastewater Using Response Surface Methodology

Water ◽  
2021 ◽  
Vol 13 (6) ◽  
pp. 835
Author(s):  
Sharon Chakawa ◽  
Mujahid Aziz
Keyword(s):  
Response Surface Methodology ◽  
Response Surface ◽  
Removal Efficiency ◽  
Current Density ◽  
Petroleum Refinery ◽  
Cod Removal ◽  
Refinery Wastewater ◽  
Cod Removal Efficiency ◽  
Petroleum Refinery Wastewater ◽  
Nacl Concentration

Electrochemical oxidation (EO) investigated chemical oxygen demand (COD) subtraction from petroleum refinery wastewater (PRW) as a capable remediation process. Titanium substrates coated with iridium–tantalum oxide mixtures (Ti/IrO2–Ta2O5) were used as the dimensional stable anode (DSA). The Box-Behnken Design (BBD), a statistical experimental design and response surface methodology (RSM), was used to matrix the current density, temperature, and electrolyte (NaCl) concentration variables, with COD removal efficiency as the response factor. A second-order verifiable relationship between the response and independent variables was derived where the analysis of variance displayed a high coefficient of determination value (R2 = 0.9799). The predicted values calculated with the model equations were very close to the experimental values where the model was highly significant. Based on the BBD for current density, the optimum process conditions, temperature and electrolyte (NaCl) concentration were 7.5 mA/cm2, 42 °C and 4.5 g/L, respectively. They were resulting in a COD removal efficiency of 99.83% after a 12-hour EO period.

scholarly journals Treatment of oilfield wastewater by combined process of micro-electrolysis, Fenton oxidation and coagulation

2017 ◽  
Vol 76 (12) ◽  
pp. 3278-3288 ◽  
Author(s):  
Zhenchao Zhang
Keyword(s):  
Reaction Time ◽  
Removal Efficiency ◽  
Treatment Process ◽  
Cod Removal ◽  
Fenton Oxidation ◽  
Oily Wastewater ◽  
Optimum Conditions ◽  
Combined Process ◽  
Cod Removal Efficiency ◽  
Optimized Conditions

Abstract In this study, a combined process was developed that included micro-electrolysis, Fenton oxidation and coagulation to treat oilfield fracturing wastewater. Micro-electrolysis and Fenton oxidation were applied to reduce chemical oxygen demand (COD) organic load and to enhance organic components gradability, respectively. Orthogonal experiment were employed to investigate the influence factors of micro-electrolysis and Fenton oxidation on COD removal efficiency. For micro-electrolysis, the optimum conditions were: pH, 3; iron-carbon dosage, 50 mg/L; mass ratio of iron-carbon, 2:3; reaction time, 60 min. For Fenton oxidation, a total reaction time of 90 min, a H2O2 dosage of 12 mg/L, with a H2O2/Fe2+ mole ratio of 30, pH of 3 were selected to achieve optimum oxidation. The optimum conditions in coagulation process: pH, cationic polyacrylamide dosage, mixing speed and time is 4.3, 2 mg/L, 150 rpm and 30 s, respectively. In the continuous treatment process under optimized conditions, the COD of oily wastewater fell 56.95%, 46.23%, 30.67%, respectively, from last stage and the total COD removal efficiency reached 83.94% (from 4,314 to 693 mg/L). In the overall treatment process under optimized conditions, the COD of oily wastewater was reduced from 4,314 to 637 mg/L, and the COD removal efficiency reached 85.23%. The contribution of each stage is 68.45% (micro-electrolysis), 24.07% (Fenton oxidation), 7.48% (coagulation), respectively. Micro-electrolysis is the uppermost influencing process on COD removal. Compared with the COD removal efficiency of three processes on raw wastewater under optimized conditions: the COD removal efficiency of single micro-electrolysis, single Fenton oxidation, single coagulation is 58.34%, 44.88% and 39.72%, respectively. Experiments proved the effect of combined process is marvelous and the overall water quality of the final effluent could meet the class III national wastewater discharge standard of petrochemical industry of China (GB8978-1996).

scholarly journals Optimization of electrocoagulation of instant coffee production wastewater using the response surface methodology

2017 ◽  
Vol 19 (2) ◽  
pp. 67-71 ◽  
Author(s):  
Ha Manh Bui
Keyword(s):  
Response Surface Methodology ◽  
Response Surface ◽  
Removal Efficiency ◽  
Current Density ◽  
Cod Removal ◽  
Coefficient Of Determination ◽  
Electrolysis Time ◽  
Instant Coffee ◽  
Operating Variables ◽  
Initial Ph

Abstract The COD removal efficiency from an instant coffee processing wastewater using electrocoagulation was investigated. For this purpose, the response surface methodology was employed, using central composing design to optimize three of the most important operating variables, i.e., electrolysis time, current density and initial pH. The results based upon statistical analysis showed that the quadratic models for COD removal were significant at very low probability value (<0.0001) and high coefficient of determination (R2 = 0.9621) value. The statistical results also indicated that all the three variables and the interaction between initial pH and electrolysis time were significant on COD abatement. The maximum predicted COD removal using the response function reached 93.3% with electrolysis time of 10 min, current density of 108.3 A/m2 and initial pH of 7.0, respectively. The removal efficiency value was agreed well with the experimental value of COD removal (90.4%) under the optimum conditions.

Characteristic of Granular Sludge Bed and Granular Sludge in Interior Diversion Expanded Granular Sludge Bed

2013 ◽  
Vol 726-731 ◽  
pp. 2813-2817
Author(s):  
Guang Li ◽  
Jing Li ◽  
Ke Sun
Keyword(s):  
Removal Efficiency ◽  
Granular Sludge ◽  
Gas Production ◽  
Cod Removal ◽  
Organic Loading Rate ◽  
Anaerobic Sludge ◽  
Cod Removal Efficiency ◽  
Seed Sludge ◽  
Bed Expansion

The interior diversion expanded granular sludge bed was concurrently operated for 140d to study the characteristic of the granular sludge bed. The influent COD concentration varied from 2000mg/L to 22300 mg/L, hydraulic retention time was maintained constant at 24 h and the organic loading rate was changed through a change in substrate concentration. The results showed that the reactor had great COD removal efficiency. When the MLSS was 23.1g/L, the influent COD was 18890mg/L, the COD removal efficiency was 80.4%; The interior diversion EGSB could greatly improve the role of gas-dynamic, when the liquid upflow velocity was 3.55m/h, the gas production was 5.96 L/d shows higher sludge bed expansion rate than 2.77 L/d about 9.5%. During the experimental, the anaerobic sludge has the following properties: the average sludge diameter was increased from 0.41mm to 1.66mm. Observed under the scanning electronic microscopy, we found that the sludge appeared obviously granulation, the bacteria amount and species are more than seed sludge after operation of 50d. It was found that rough surface of anaerobic sludge has clear figure with being covered by mucous lamina, with visible hole or cavity on surface.

Pilot-Scale Experiences on Anaerobic Fluidized-Bed Treatment of Brewery Wastes

1990 ◽  
Vol 22 (9) ◽  
pp. 157-166 ◽  
Author(s):  
G. K. Anderson ◽  
I. Ozturk ◽  
C. B. Saw
Keyword(s):  
Fluidized Bed ◽  
Removal Efficiency ◽  
Pilot Scale ◽  
Methanogenic Bacteria ◽  
Cod Removal ◽  
Organic Loading Rate ◽  
Cod Removal Efficiency ◽  
Wide Range ◽  
Monod Kinetic ◽  
Brewery Wastes

This paper covers the results of a pilot-plant study on the Anaerobic Fluidized-Bed Reactor (AFBR) treatment of brewery wastes. The AFBR was operated over a wide range of organic and hydraulic loading rates for a study period of more than eight months. The reactor consisted of a clear PVC column with a diameter of 165 mm and 3 m in height. Sand having a median diameter of 0.5 mm was used as the medium. The AFBR was fed with wastewaters collected from a local brewery. A COD removal efficiency of greater than 75% was observed at an organic loading rate (OLR) of 8.9 kg COD/m3 of expended bed/day for 82 days from start-up. The OLR was increased to greater than 14 kg COD/m3.d and a COD to methane conversion of 87% was achieved. Effects of OLR and COD removal efficiency on gas flowrate and on gas composition as well as concentrations of suspended solids (SS) and volatile acids (VA) were investigated. It was observed that biomass distribution along the height of the AFBR was not uniform and a strong stratification of biomass exists between the upper and lower parts of the system. The ecological structure of biomass was examined by SEM and clumps of methanogenic bacteria were identified. The Monod kinetic parameters were determined using steady-state operating data and compared to similar results given in the literature for the same waste.

Anaerobic Fluidized-Bed Treatment of Brewery Wastes and Bioenergy Recovery

1989 ◽  
Vol 21 (12) ◽  
pp. 1681-1684 ◽  
Author(s):  
I. Ozturk ◽  
G. K. Anderson ◽  
C. B. Saw
Keyword(s):  
Fluidized Bed ◽  
Removal Efficiency ◽  
Cod Removal ◽  
Organic Loading Rate ◽  
Utilization Rate ◽  
Specific Substrate ◽  
Cod Removal Efficiency ◽  
Start Up ◽  
Specific Substrate Utilization Rate ◽  
Brewery Wastes

This paper presents the results of a pilot plant study using an Anaerobic Fluidized Bed Reactor (AFBR) for treatment of brewery wastes. A COD removal efficiency of greater than 75% was observed at an organic loading rate (OLR) of 9.5 kg COD/m3-day for a Deriod of 82 days from start-up. COD removal efficiency was greater than 74% at an OLR of 14.6 kg COD/m3 expanded bed (e.b)-day. A COD to methane conversion of 87% was achieved. Experimental results have suggested that the COD removal efficiency of an AFBR is only a function of COD loading, and neither the feed COD nor HRT alone significantly affect the performance of the reactor. A linear relationship was found between the specific substrate utilization rate and the specific methane production rate. It was observed that the distribution of the biomass along the height of the reactor is not uniform, and the biomass hold-up near the top of the reactor may reach concentrations of greater than 20,000 mg/l.

A submerged tubular ceramic membrane bioreactor for high strength wastewater treatment

2003 ◽  
Vol 47 (1) ◽  
pp. 105-111 ◽  
Author(s):  
D.D. Sun ◽  
J.L. Zeng ◽  
J.H. Tay
Keyword(s):  
Wastewater Treatment ◽  
Removal Efficiency ◽  
Retention Time ◽  
Membrane Bioreactor ◽  
Ceramic Membrane ◽  
Treatment Plant ◽  
High Strength ◽  
Cod Removal ◽  
Utilization Rate ◽  
Cod Removal Efficiency

A 4 L submerged tubular ceramic membrane bioreactor (MBR) was applied in laboratory scale to treat 2,400 mg-COD/L high strength wastewater. A prolonged sludge retention time (SRT) of 200 day, in contrast to the conventional SRT of 5 to 15 days, was explored in this study, aiming to reduce substantially the amount of disposed sludge. The MBR system was operated for a period of 142 days in four runs, differentiated by specific oxygen utilization rate (SOUR) and hydraulic retention time (HRT). It was found that the MBR system produced more than 99% of suspended solid reduction. Mixed liquor suspended solids (MLSS) was found to be adversely proportional to HRT, and in general higher than the value from a conventional wastewater treatment plant. A chemical oxygen demand (COD) removal efficiency was achieved as high as 98% in Run 1, when SOUR was in the range of 100-200 mg-O/g-MLVSS/hr. Unexpectedly, the COD removal efficiency in Run 2 to 4 was higher than 92%, on average, where higher HRT and abnormally low SOUR of 20-30 mg-O/g-MLVSS/hr prevailed. It was noted that the ceramic membrane presented a significant soluble nutrient rejection when the microbial metabolism of biological treatment broke down.

scholarly journals Upflow Anaerobic Filter for the Treatment of Wastewater from a Natural Rubber Latex Concentration Unit

2021 ◽  
Vol 20 (4) ◽  
Author(s):  
Nithya Gopinath ◽  
Madhu G. ◽  
Joseph Francis
Keyword(s):  
Production Rate ◽  
Removal Efficiency ◽  
Cod Removal ◽  
Organic Loading Rate ◽  
Organic Loading ◽  
Rubber Latex ◽  
Loading Rates ◽  
Anaerobic Filter ◽  
Cod Removal Efficiency ◽  
Concentration Unit

In this study, wastewater from a centrifuge rubber latex concentration unit was experimentally treated by an up-flow anaerobic filter (UAF) at variable hydraulic detention time to investigate the COD removal efficiency and the gas production rate. The UAF reactors were made of PVC pipe with an inside diameter of 9.5 cm, 180 cm in height, with a bed volume of 12.8 L, and filled with polyethylene media. The initial COD concentration of wastewater was in the range 4620 - 10400 mg.L-1. HRTs were controlled at 20 days, with the organic loading rate varying from 2.9 to 10.5 kg.day.m-3. The findings show that the COD removal efficiency of the system was in the range of 85% to 92% for the varying organic loading rates. In addition, the specific methane production rate varied from 8.2 to 14 L of CH4 produced/g of COD destroyed/day for the different organic loading rates.

Buoyant Filter Bio-Reactor (BFBR)–a novel anaerobic wastewater treatment unit

2008 ◽  
Vol 58 (2) ◽  
pp. 373-377
Author(s):  
Soosan J. Panicker ◽  
M. C. Philipose ◽  
Ajit Haridas
Keyword(s):  
Removal Efficiency ◽  
Treatment Plant ◽  
Cod Removal ◽  
Upflow Anaerobic Sludge Blanket ◽  
Organic Loading Rate ◽  
Anaerobic Sludge ◽  
Treatment Unit ◽  
Biogas Yield ◽  
Cod Removal Efficiency ◽  
Anaerobic Sludge Blanket

The Buoyant Filter Bio-Reactor (BFBR) is a novel and very efficient method for the treatment of complex wastewater. Sewage is a complex wastewater containing insoluble COD contributed by fat and proteins. The fat and proteins present in the domestic sewage cause operational problems and underperformance in the Upflow Anaerobic Sludge Blanket Reactor, used now for treating sewage anaerobically. The biogas yield from the BFBR is 0.36 m3/kg COD reduced and the methane content was about 70–80%. Production of methane by anaerobic digestion of organic waste had the benefit of lower energy costs for treatment and is thus environmentally beneficial to the society by providing a clean fuel from renewable feed stocks. The BFBR achieved a COD removal efficiency of 80–90% for an organic loading rate of 4.5 kg/m3/d at a hydraulic retention time of 3.25 hours. The effluent COD was less than 100 mg/l, thus saving on secondary treatment cost. No pretreatment like sedimentation was required for the influent to the BFBR. The BFBR can produce low turbidity effluent as in the activated sludge process (ASP). The land area required for the BFBR treatment plant is less when compared to ASP plant. Hence the problem of scarcity of land for the treatment plant is reduced. The total expenditure for erecting the unit was less than 50% as that of conventional ASP for the same COD removal efficiency including land cost.

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