Control of refractory pollutants as useful resources by hydrothermal reaction coupled with biological treatment methods

2006 ◽  
Vol 1 (3) ◽  
Author(s):  
K. Kim ◽  
M. Fujita ◽  
H. Daimon ◽  
K. Fujie

Relationship between structural conversion of refractory pollutants and their biodegradability improvement was clarified under various hydrothermal conditions to know the usability of treated refractory pollutants in biological treatment methods. Hydrothermal reaction was also verified by using real wastewater. High-molecular-weight structured poly vinyl alcohol and hydrocarbon structured chloroacetic acids were partially fractured by hydrolysis and dehydration at the beginning of hydrothermal reaction. Then partially fractured refractory pollutants were rapidly converted to easily degradable substances by thermal decomposition depending on hydrothermal conditions. This significant change occurred within 3 min from the moment reaching the desired conditions at 350 and 400oC. These results were very similar to the results of soybean milk, except dyeing wastewater involving aromatic compounds. Excess sludge treated by hydrothermal reaction was also converted to easily degradable substrate as carbon sources in a bioreactor. Hydrothermal reaction should be adjusted to increase the amount of biodegradable products in reactants, without much reduction of total organic carbon. The content change of refractory pollutants and excess sludge by hydrothermal reaction was the most important factor on the viewpoint of treated reactant reuse, for the following biological treatment methods.

2005 ◽  
Vol 52 (10-11) ◽  
pp. 533-541 ◽  
Author(s):  
K. Kim ◽  
M. Fujita ◽  
H. Daimon ◽  
K. Fujie

An application of hydrothermal reaction was investigated to reuse excess sludge as carbon sources for enhancement of biological phosphorus removal. Under the tested conditions, solubilization of treated excess sludge did not present much variation, sustaining around 65%, except the results obtained at 400°C. Biodegradability of excess sludge was improved through its content change by the reaction, without much reduction of carbon contents even in 7min. From the results of respirometric test, readily biodegradable substrate was found at 300°C. Then its portion of reaction products increased with increasing reaction temperature. In the readily biodegradable substrate, acetic and propionic acid, which are useful carbon sources for phosphorus accumulating microorganism under anaerobic condition, increased with increasing reaction temperature. Hydrothermal reaction might be accepted as suitable pretreatment method to treat excess sludge prior to biological treatment process. This technology also secures excess sludge reuse, enhancing biological phosphorus removal and improvement of biological treatment process.


2022 ◽  
Vol 157 ◽  
pp. 282-299
Author(s):  
Sertac Kirnaz ◽  
Sunidhi Singh ◽  
Charisse Capadona ◽  
Marianne Lintz ◽  
Jacob L. Goldberg ◽  
...  

1996 ◽  
Vol 457 ◽  
Author(s):  
Fatih Dogan ◽  
Shawn O'rourke ◽  
Mao-Xu Qian ◽  
Mehmet Sarikaya

ABSTRACTNanocrystalline powders with an average particle size of 50 nm has been synthesized in two materials systems under hydrothermal conditions below 100°C. Processing variables, such as temperature, concentration and molar ratio of reactants and reaction time were optimized to obtain particles of reduced size and stoichiometric compositions. Hydrothermal reaction takes place between Ba(OH)2 solution and titanium/iron precursors in sealed polyethylene bottles in the BaTiO3 and BaFe12O19 systems, respectively. While crystalline BaTiO3 forms relatively fast within a few hours, formation of fully crystalline and stoichiometric BaFei20i9 require considerably longer reaction times up to several weeks and strongly dependent on the Ba:Fe ratio of the precursors. The structural and compositional evaluation of the nanophase powders were studied by XRD and TEM techniques.


2011 ◽  
Vol 347-353 ◽  
pp. 3439-3442 ◽  
Author(s):  
Ying Qiu Xu ◽  
Guang Chuan Liang ◽  
Li Wang

The spinel nano-Li4Ti5O12 was prepared by hydrothermal reaction method. The crystal structure, morphology and charge/discharge capacities were characterized by powder X-ray diffraction and Scanning electron microscopy and program-controlled tester respectively. It showed that lithium titanate synthesized by the direct hydrothermal method has a uniform particle size distribution of about 100nm in cubic shape. Investigated the influence of different carbon sources on the structure and electrochemical properties. It was found that the discharge capacities could reach 172.2, 159.8, 156.2 and 148.3mAh/g at 0.2C, 1C, 2C and 5C rates, respectively.


2015 ◽  
Vol 43 (1) ◽  
pp. 39-44 ◽  
Author(s):  
Sándor Guba ◽  
Viola Somogyi ◽  
Erzsébet Szabóné Bárdos

Abstract The degradability of two commercially available pesticides was studied using heterogeneous photocatalytic and activated sludge treatment methods. The first pesticide contained 5% quizalofop-P-ethyl as an active ingredient and petroleum naphtha as a solvent, the latter causing difficulties both in photocatalytic and biological treatment methods. The active ingredient of the second compound was acetamiprid. The photocatalysis proved to be effective both under laboratory conditions (using UV light) and when exposed to sunlight, but the pesticides remained stable during the employed biological treatment. Preliminary information on its behaviour in soil was obtained from transport modelling.


2014 ◽  
Vol 962-965 ◽  
pp. 1490-1494
Author(s):  
Jian Zheng Li ◽  
Shuai Shi

Low nitrogen removal efficiency caused by the lack of carbon source in low C/N ratio wastewater restricts the wastewater biological treatment. Advances in wastewater biological treatment at low C/N ratio are reviewed in the paper from three aspects, including modifying traditional biological nitrogen removal process, developing novel biological nitrogen removal processes and optimizing traditional carbon source and developing new types of carbon sources. The mechanisms, advantages, and applications of these processes are also summarized and analyzed.


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