scholarly journals Synthesis and Enantiomeric Recognition Studies of Novel C2-Symmetrical Chiral Tetra-Amide Compounds

2021 ◽  
pp. 1293-1301
Author(s):  
Murat SÜNKÜR ◽  
Züleyha TİĞİZ ◽  
Deniz CEBE ◽  
Tarık ARAL
Keyword(s):  
Enantiomeric Recognition

Photophysical Characterisation, Metal Ion Binding and Enantiomeric Recognition of Chiral Ligands Containing Phenazine Fluorophore

2004 ◽  
Vol 69 (4) ◽  
pp. 885-896 ◽  
Author(s):  
Luisa Stella Dolci ◽  
Péter Huszthy ◽  
Erika Samu ◽  
Marco Montalti ◽  
Luca Prodi ◽  
...  
Keyword(s):  
Metal Ion ◽  
Photophysical Properties ◽  
Ion Binding ◽  
Metal Ion Binding ◽  
Ammonium Ions ◽  
Enantiomerically Pure ◽  
Binding Process ◽  
High Affinity ◽  
Enantiomeric Recognition ◽  
Chiral Species

Enantiomerically pure dimethyl- and diisobutyl-substituted phenazino-18-crown-6 ligands bind metal and ammonium ions and also primary aralkylammonium perchlorates in acetonitrile with high affinity, causing pronounced changes in their luminescence properties. In addition, they show enantioselectivity towards chiral primary aralkylammonium perchlorates. The possibility to monitor the binding process by photoluminescence spectroscopy can gain ground for the design of very efficient enantioselective chemosensors for chiral species. The observed changes in the photophysical properties are also an important tool for understanding the interactions present in the adduct.

ChemInform Abstract: Enantiomeric Recognition of Amine Compounds by Chiral Macrocyclic Receptors

ChemInform ◽  
2010 ◽  
Vol 29 (12) ◽  
pp. no-no
Author(s):  
X. X. ZHANG ◽  
J. S. BRADSHAW ◽  
R. M. IZATT
Keyword(s):  
Macrocyclic Receptors ◽  
Enantiomeric Recognition ◽  
Amine Compounds

scholarly journals Synthesis, Molecular Recognition Study and Liquid Membrane-Based Applications of Highly Lipophilic Enantiopure Acridino-Crown Ethers

Molecules ◽  
2020 ◽  
Vol 25 (11) ◽  
pp. 2571
Author(s):  
Ádám Golcs ◽  
Bálint Árpád Ádám ◽  
Viola Horváth ◽  
Tünde Tóth ◽  
Péter Huszthy
Keyword(s):  
Crown Ethers ◽  
Liquid Membrane ◽  
Structural Features ◽  
Amino Acid Derivatives ◽  
Electrochemical Studies ◽  
Model Compounds ◽  
Guest Molecules ◽  
Enantiomeric Recognition ◽  
Sensor Molecules ◽  
Phase Transport

New highly lipophilic enantiopure crown ethers containing a heterocyclic unit have been synthesized. Phase transport, UV-Vis- and fluorescence spectrophotometric investigations as well as electrochemical studies on the complexation of the new macrocycles with several amine and amino acid derivatives were also carried out. Achiral amines were used for studying the structural preference of the new macrocycles. Among the studied structural features of the guest molecules, the intermolecular π-π interaction showed the most significant effect on complexation, which made the aralkylamine-type compounds the most preferable guest molecules. The studied liquid membrane-based applications and photophysical investigations showed appreciable enantiomeric recognition toward some aralkylamine model compounds with homochiral preferences. New crown ether derivatives (R,R)-2 and (S,S)-2 were successfully applied as enantioselective carrier and sensor molecules.

ChemInform Abstract: ENANTIOMERIC RECOGNITION OF ORGANIC AMMONIUM SALTS BY CHIRAL CROWN ETHERS BASED ON THE PYRIDINO-18-CROWN-6 STRUCTURE

1984 ◽  
Vol 15 (25) ◽  
Author(s):  
R. B. DAVIDSON ◽  
J. S. BRADSHAW ◽  
B. A. JONES ◽  
N. K. DALLEY ◽  
J. J. CHRISTENSEN ◽  
...  
Keyword(s):  
Crown Ethers ◽  
Ammonium Salts ◽  
Chiral Crown Ethers ◽  
Enantiomeric Recognition

scholarly journals Synthesis and characterization of chiral ionic liquids based on quinine, l-proline and l-valine for enantiomeric recognition

2019 ◽  
Vol 283 ◽  
pp. 410-416 ◽  
Author(s):  
Tânia E. Sintra ◽  
Mikhail G. Gantman ◽  
Sónia P.M. Ventura ◽  
João A.P. Coutinho ◽  
Peter Wasserscheid ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Synthesis And Characterization ◽  
Chiral Ionic Liquids ◽  
Enantiomeric Recognition

Enantiomeric recognition of α-amino acid derivatives by chiral uranyl–salen receptors

2015 ◽  
Vol 56 (22) ◽  
pp. 2922-2926 ◽  
Author(s):  
Giuseppe Forte ◽  
Alessandro D’Urso ◽  
Francesco P. Ballistreri ◽  
Rosa M. Toscano ◽  
Gaetano A. Tomaselli ◽  
...  
Keyword(s):  
Amino Acid ◽  
Amino Acid Derivatives ◽  
Enantiomeric Recognition

scholarly journals Three-Dimensional Enantiomeric Recognition of Optically Trapped Single Chiral Nanoparticles

2018 ◽  
Vol 121 (2) ◽  
Author(s):  
Gabriel Schnoering ◽  
Lisa V. Poulikakos ◽  
Yoseline Rosales-Cabara ◽  
Antoine Canaguier-Durand ◽  
David J. Norris ◽  
...  
Keyword(s):  
Three Dimensional ◽  
Enantiomeric Recognition ◽  
Optically Trapped

scholarly journals Harnessing the enantiomeric recognition ability of hydrophobic polymers of intrinsic microporosity (PIM-1) toward amino acids by converting them into hydrophilic polymer dots

2020 ◽  
Vol 8 (39) ◽  
pp. 13827-13835
Author(s):  
Froozan Feizi ◽  
Mojtaba Shamsipur ◽  
Mohammad Bagher Gholivand ◽  
Avat (Arman) Taherpour ◽  
Ali Barati ◽  
...  
Keyword(s):  
Conjugated Polymer ◽  
Polymer Chains ◽  
Racemic Mixture ◽  
Hydrophobic Polymers ◽  
Polymer Dots ◽  
Recognition Ability ◽  
Enantiomeric Recognition ◽  
Conjugated Polymer Chains ◽  
Polymers Of Intrinsic Microporosity ◽  
Intrinsic Microporosity

In this work, we synthesized novel polymer dots (Pdots) from polymers of intrinsic microporosity (PIM-1) containing a racemic mixture of R- and S-chiral centers as the hydrophobic conjugated polymer chains.

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