Gas-Tight pH Measurements to Assess an Effect of CO2 on Groundwater

2018 ◽  
Author(s):  
Saeko Mito-Adachi ◽  
Ziqiu Xue ◽  
Bracken Wimmer ◽  
Abbas Iranmanesh ◽  
Hongbo Shao ◽  
...  
Keyword(s):  
2008 ◽  
Vol 59 (10) ◽  
Author(s):  
Paul Ionut Dron ◽  
Neculai Doru Miron ◽  
Gheorghe Surpateanu

The paper presents the synthesis of cyclo (bis-paraquat p-phenylene p-phenylene-carbonyl) tetrakis (hexafluorophosphate), named �CETOBOX�, and the closely related structural determinations. This compound exists in three tautomeric forms. These forms were evidentiated by NMR-data (1H-NMR, TOCSY, COSY, NOESY), UV-Vis spectra coupled with pH measurements and by synthesis. As the �CETOBOX� gives �in situ� only the corresponding monoylide, the synthesis of a new fluorescent indolizine cyclophane has been performed by a 3+2 cycloaddition. All structures of the new compounds presented herein have been established by NMR spectroscopy. Also, theoretical methods (MM3, AM1, AM1-COSMO and B88LYPDFT) have been used to determine the most stable conformer structures.


HortScience ◽  
1996 ◽  
Vol 31 (4) ◽  
pp. 643f-643
Author(s):  
Weimin Deng ◽  
Randolph M. Beaudry

Sampling factors that could affect gas chromatograph (GC) response for volatile analysis such as syringe pumping time, injection volume, needle length, temperature, and the type of volatile were investigated. Capillary GC column segments (steel and glass) were installed in gas-tight syringes and used as needles for volatile analysis. Standard stainless-steel needles were also used. Hexylacetate, ethyl-2-methylbutyrate, 6-methyl-5-hepten-2-one, and butanol standard were measured. The number of pumps required to maximize GC response for each needle–volatile combination was determined. Maximal GC response for hexylacetate using standard stainless steel, capillary glass, and capillary steel needles required 10, 20 and 30 pumps, respectively. However, for butanol measurement, the optimal syringe pump number was 5 to 10 for all needle types. The use of a capillary needle resulted in an increase in GC response in the range of 3- to 15-fold relative to a standard stainless steel needle. Injection volume affected GC response in a needle-and volatile-dependent manner. In no case did injection volume vs. GC response extrapolate through origin. The GC response for capillary column needles increased as temperature decreased. Capillary column needles may be useful tools for analysis of volatiles that readily partition into the column coating.


HortScience ◽  
1998 ◽  
Vol 33 (3) ◽  
pp. 498d-498
Author(s):  
Z.L. He ◽  
A.K. Alva ◽  
D.V. Calvert ◽  
D.J. Banks ◽  
Y.C. Li

A field experiment was conducted in a Riviera fine sand (Alfisol) with 25-year-old `White Marsh' grapefruit trees on Sour orange rootstock to monitor the downward transport of nutrients from fertilization practices. Fertilizer was applied as either dry granular broadcast (three applications/year) or fertigation (15 applications/year) at N rates of 56, 112, 168, and 336 kg/ha per year using a N:P:K blend (1.0:0.17:1.0). Soil solution was sampled bi-weekly from suction lysimeters, installed under the tree canopy, about 120 cm from the tree trunk, at two depths representing above (120 cm) and below (180 cm) the hard pan. The concentrations of K, Ca, and Mg were greater at the 180- than at 120-cm depth, whereas, the converse was true with respect to the concentration of P in soil solution. Over a 2-year period, the mean concentrations of P and K varied from 0.031-0.976 and 150-250 mg·L–1, respectively. Increased rate of fertilization also appeared to increase the concentrations of Ca and Mg in the soil solution. This could be due to effects of slight acidification of the soil with increased rates of ammonium form of N. A parallel study on pH measurements has shown evidence of soil acidification, under the tree canopy, with increased rates of ammonium fertilization. In a bedded grove, the soil solution above the hard pan is likely to seep into the water furrow, which is discharged into the drainage water.


2020 ◽  
Vol 1 (4) ◽  
Author(s):  
Peizeng Yang ◽  
Yaye Wang ◽  
Junhe Lu ◽  
Viktor Tishchenko ◽  
Qingguo Huang ◽  
...  

This study examined the degradation of perfluorooctanesulfonate (PFOS) in electrochemical oxidation (EO) processes in the presence of trichloroethylene (TCE). The EO experiment was performed in a gas-tight reactor using Magnéli phase titanium suboxide (Ti4O7) as the anode. The experimental data demonstrated that 75% of PFOS (2 μM) was degraded at 10 mA/cm2 current density in 30 min without TCE present in the solution, while the presence of 76 μM TCE apparently inhibited the degradation of PFOS, reducing its removal down to 53%. Defluorination ratio suggested that PFOS was significantly mineralized upon EO treatment, and it appeared to be not influenced by the presence of TCE. The respective pseudo-first order rate constants (kobs) of PFOS removal were 0.0471 and 0.0254 min-1 in the absence and presence of TCE. The degradation rates of both PFOS and TCE increased with current density rising from 2.5 to 20 mA/cm2. In the presence of TCE, chloride, chlorate, and perchlorate were formed that accounted for 79.7 %, 5.53%, and 1.51% of the total chlorine at 60 min. This work illustrates the promise of the Magnéli phase Ti4O7 electrode based electrochemical oxidation technology for degrading per- and polyfluoroalkyl substances (PFASs) and co-contaminants in groundwaters.


Sensors ◽  
2021 ◽  
Vol 21 (10) ◽  
pp. 3426
Author(s):  
Magdalena Paulina Buras ◽  
Fernando Solano Donado

Harsh pollutants that are illegally disposed in the sewer network may spread beyond the sewer network—e.g., through leakages leading to groundwater reservoirs—and may also impair the correct operation of wastewater treatment plants. Consequently, such pollutants pose serious threats to water bodies, to the natural environment and, therefore, to all life. In this article, we focus on the problem of identifying a wastewater pollutant and localizing its source point in the wastewater network, given a time-series of wastewater measurements collected by sensors positioned across the sewer network. We provide a solution to the problem by solving two linked sub-problems. The first sub-problem concerns the detection and identification of the flowing pollutants in wastewater, i.e., assessing whether a given time-series corresponds to a contamination event and determining what the polluting substance caused it. This problem is solved using random forest classifiers. The second sub-problem relates to the estimation of the distance between the point of measurement and the pollutant source, when considering the outcome of substance identification sub-problem. The XGBoost algorithm is used to predict the distance from the source to the sensor. Both of the models are trained using simulated electrical conductivity and pH measurements of wastewater in sewers of a european city sub-catchment area. Our experiments show that: (a) resulting precision and recall values of the solution to the identification sub-problem can be both as high as 96%, and that (b) the median of the error that is obtained for the estimation of the source location sub-problem can be as low as 6.30 m.


1962 ◽  
Vol 237 (3) ◽  
pp. 963-967
Author(s):  
S.J.G. Semple ◽  
G. Mattock ◽  
R. Uncles
Keyword(s):  

1991 ◽  
Vol 74 (2) ◽  
pp. 400-403
Author(s):  
Walter Fiddler ◽  
Robert C Doerr ◽  
Robert A Gates

Abstract A method Is described for analysis of minced fish-meat and surlmi-meat frankfurters for dimethylamine (DMA), trimethyiamine (TMA), and trimethyiamine oxide (TMAO) using a headspace-gas chromatographic technique. After simple acid extraction and addition of NaOH, the headspace was directly Injected Into a gas chromatograph by a gas-tight syringe. DMA and TMA were separated on a Chromosorb 103 column and detected by a flame Ionization detector. TMAO was measured as TMA after Zn reduction. Repeatability of the method for DMA, TMA, and TMAO was 6.6,1.0, and 18.8 ppm, respectively. The method was applicable to Alaska pollock-meat and Atlantic menhaden-meat frankfurters, unwashed, and washed mince and surlml.


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