scholarly journals Electrochemical Impedance Spectroscopy and Gravimetric Study of the Corrosion Inhibition of API 5L X-52 steel in HCl Medium by Levofloxacin

2017 ◽  
Vol 6 (7) ◽  
pp. 623-628
Keyword(s):  
Electrochemical Impedance Spectroscopy ◽  
Impedance Spectroscopy ◽  
Corrosion Inhibition ◽  
Electrochemical Impedance ◽  
Hcl Medium

The effect of an N-heterocyclic compound on corrosion inhibition of J55 steel in sweet corrosive medium

2019 ◽  
Vol 43 (16) ◽  
pp. 6303-6313 ◽  
Author(s):  
Ambrish Singh ◽  
K. R. Ansari ◽  
M. A. Quraishi ◽  
Savas Kaya ◽  
Priyabrata Banerjee
Keyword(s):  
Carbon Dioxide ◽  
Weight Loss ◽  
Electrochemical Impedance Spectroscopy ◽  
Impedance Spectroscopy ◽  
Corrosion Inhibition ◽  
Heterocyclic Compound ◽  
Potentiodynamic Polarization ◽  
Corrosive Medium ◽  
Electrochemical Impedance ◽  
Nacl Solution

The corrosion inhibition behavior of a naphthoxazinone derivative 1-phenyl-1,2-dihydronaphtho[1,2-e][1,3]oxazin-3-one (PNO) on J55 steel in 3.5 wt% NaCl solution saturated with carbon dioxide was evaluated using weight loss, electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization.

scholarly journals Cation Effect in the Corrosion Inhibition Properties of Coumarate Ionic Liquids and Acrylic UV-Coatings

Polymers ◽  
2020 ◽  
Vol 12 (11) ◽  
pp. 2611
Author(s):  
Esther Udabe ◽  
Anthony Sommers ◽  
Maria Forsyth ◽  
David Mecerreyes
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Electrochemical Impedance Spectroscopy ◽  
Impedance Spectroscopy ◽  
Mild Steel ◽  
Corrosion Inhibition ◽  
Polymer Coating ◽  
Corrosion Inhibitors ◽  
Electrochemical Impedance ◽  
Polymer Coatings

Chromate free corrosion inhibitors are searched for to mitigate the economic loss caused by mid-steel corrosion. Here, we show metal-free organic inhibitors having free coumarate anions that can be used either as direct corrosion inhibitors or incorporated into a polymer coating obtained by UV-curing. Four different ionic liquid monomers and polymer coatings with hexoxycoumarate anion and different polymerizable counter cations were investigated. Potentiodynamic polarization, electrochemical impedance spectroscopy, and surface analyses have verified their corrosion inhibition performance on a mild steel AS1020 surface. In the case of the coumarate ionic liquid monomers, the most promising inhibitor is the one coupled with the ammonium cation, showing an inhibition efficiency of 99.1% in solution followed by the imidazolium, pyridinium, and anilinium. Next, the ionic liquid monomers were covalently integrated into an acrylic polymer coating by UV-photopolymerization. In this case, the barrier effect of the polymer coating is combined with the corrosion inhibitor effect of the pendant coumarate anion. Here, the best polymer coatings are those containing 20% imidazolium and pyridinium cations, presenting a greater impedance in the EIS (Electrochemical Impedance Spectroscopy) measurements and less evidence of corrosion in the scribe tests. This article shows that the cationic moiety of coumarate based ionic liquids and poly(ionic liquid)s has a significant effect on their excellent corrosion inhibition properties for a mild steel surface exposed to aqueous chloride solutions.

Corrosion Inhibition Study of Mild Steel in the Acidic Mediums Containing a Mineral Compound-Based Phosphate

2020 ◽  
pp. 187-206
Author(s):  
Moussa Ouakki ◽  
Mouhsine Galai ◽  
Mohammed Cherkaoui ◽  
Mohamed Ebn Touhami ◽  
E. H. Rifi ◽  
...  
Keyword(s):  
Electrochemical Impedance Spectroscopy ◽  
Impedance Spectroscopy ◽  
Mild Steel ◽  
Corrosion Inhibition ◽  
Electrochemical Impedance ◽  
Adsorbed Layer ◽  
Inhibition Mechanism ◽  
Double Layer Capacitance ◽  
Adsorption Model ◽  
Transfer Resistance

The corrosion inhibition of mild steel in hydrochloric, sulfuric, and phosphoric acids solutions containing a mineral compound-based phosphate (apatite) was evaluated by potentiodynamic polarization and electrochemical impedance spectroscopy. Potentio-dynamic polarization measurements reveal that the inhibition efficiency increased with the concentration of the apatite, which appears to be a cathodic type inhibitor in the three mediums. Electrochemical impedance spectroscopy confirms this result; indeed, the transfer resistance increases with apatite concentration. The authors note that the double layer capacitance decreases simultaneously suggesting the formation of an adsorbed layer on the mild steel surface. The inhibition mechanism has been elucidated by a thermodynamic study, which showed that the film was formed by physi-sorption. The adsorption model obeys to the Langmuir adsorption isotherm. The parameters of activation energy were evaluated and discussed.

Effect of Manganese Ions on Corrosion Inhibition of PANI for Mild Steel in 0.5 M H2SO4

2011 ◽  
Vol 415-417 ◽  
pp. 174-177
Author(s):  
Yu Qiu Huo ◽  
Ling Bai
Keyword(s):  
Cyclic Voltammetry ◽  
Electrochemical Impedance Spectroscopy ◽  
Impedance Spectroscopy ◽  
Mild Steel ◽  
Corrosion Inhibition ◽  
Corrosion Potential ◽  
Electrochemical Impedance ◽  
Steel Substrate ◽  
Manganese Ions ◽  
Mild Steel Substrate

Manganese ions doped Pani films were prepared by using a cyclic voltammetry technique on mild steel substrate. Corrosion resistances performances of them in 0.5 M H2SO4 solution were obtained by using electrochemical impedance spectroscopy (EIS), polarization curve, and SEM method. The results showed that manganese ions doped Pani particles became smaller and tighter, the resistance reduced, and the corrosion potential rose than Pani in H2SO4 solution.

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