Butyl Rubber: Compound Development and Characterization.

2000 ◽  
Author(s):  
James M. Sloan
Keyword(s):  
Butyl Rubber ◽  
Rubber Compound

Effects of Aging on the Morphology of Rubber-Brass Interfacial Layer

2011 ◽  
Vol 39 (1) ◽  
pp. 20-43 ◽  
Author(s):  
A. Ashirgade ◽  
P. B. Harakuni ◽  
W. J. Vanooij
Keyword(s):  
Chemical Composition ◽  
Interfacial Layer ◽  
Secondary Ion Mass Spectrometry ◽  
Morphological Changes ◽  
Grazing Incidence ◽  
Complex Nature ◽  
Rubber Compound ◽  
Tire Cord ◽  
Morphological Transformation ◽  
Adhesion Promoter

Abstract Adhesion between rubber compound and brass-plated steel tire cord is crucial in governing the overall performance of tires. The rubber-brass interfacial adhesion is influenced by the chemical composition and thickness of the interfacial layer. It has been shown that the interfacial layer consists mainly of sulfides and oxides of copper and zinc. This paper discusses the effect of changes in the chemical composition and the structure of the interfacial layers due to addition of adhesion promoter resins. Grazing incidence x-ray diffraction (GIXRD) experiments were run on sulfidized polished brass coupons previously bonded to five experimental rubber compounds. It was confirmed that heat and humidity conditions lead to physical and chemical changes of the rubber-steel tire cord interfacial layer, closely related to the degree of rubber-brass adhesion. Morphological transformation of the interfacial layer led to loss of adhesion after aging. The adhesion promoter resins inhibit unfavorable morphological changes in the interfacial layer, thus stabilizing it during aging and prolonging failure. Tire cord adhesion tests illustrated that the one-component resins improved adhesion after aging using a rubber compound with lower cobalt loading. Based on the acquired diffraction profiles, these resins were also found to impede crystallization of the sulfide layer after aging, leading to improved adhesion. Secondary ion mass spectrometry depth profiles and scanning electron microscopy micrographs strongly corroborated the findings from GIXRD. This interfacial analysis adds valuable information to our understanding of the complex nature of the rubber-brass bonding mechanism.

Thermoelastoplasts based on the mixture of thermoplastic polyolefins and butyl rubber

2018 ◽  
pp. 33-42
Author(s):  
Z. N. Guseynova ◽  
◽  
N. T. Kakhramanov ◽  
B. A. Mamedov ◽  
V. S. Osipchik ◽  
...  
Keyword(s):  
Butyl Rubber

Technological characteristics of injection molding of dynamic elastoplasts based on thermoplastic polyolefins and butyl rubber

2019 ◽  
pp. 58-67
Author(s):  
N. T. Kakhramanov ◽  
◽  
Z. N. Huseynova ◽  
V. S. Osipchik ◽  
R. V. Kurbanova ◽  
...  
Keyword(s):  
Injection Molding ◽  
Butyl Rubber ◽  
Technological Characteristics

Partial replacement of carbon black by nanoclay in butyl rubber compounds for tubeless tires

2017 ◽  
Vol 59 (11-12) ◽  
pp. 1054-1060 ◽  
Author(s):  
Mohan Kumar Harikrishna Kumar ◽  
Subramaniam Shankar ◽  
Rathanasamy Rajasekar ◽  
Pal Samir Kumar ◽  
Palaniappan Sathish Kumar
Keyword(s):  
Carbon Black ◽  
Butyl Rubber ◽  
Partial Replacement ◽  
Rubber Compounds

The influence of oxidized technical carbon N121 on the properties of butyl-based rubbers

2019 ◽  
pp. 123-128
Author(s):  
M. N. Nagornaya ◽  
A. V. Myshliavtsev ◽  
S. Ya. Khodakova
Keyword(s):  
Hydrogen Peroxide ◽  
Carbon Black ◽  
Gas Permeability ◽  
Mechanical Tests ◽  
Butyl Rubber ◽  
Rubber Mixture ◽  
Active Forms Of Oxygen ◽  
Technical Carbon ◽  
Furnace Black ◽  
The Subject

The subject of the study were samples of channel technical carbon K354, furnace technical carbon N121 and experimental – based on TUN121, oxidized with active forms of oxygen. Samples of carbon black were studied in the composition of a rubber mixture based on BK 1675N butyl rubber. The purpose of this study was to determine the possibility of using oxidized technical carbon N121 in fillers of rubber based on butyl rubber, instead of carbon black K354. The physicochemical properties of the samples of technical carbon under study, the results of physical and mechanical tests, and the gas permeability tests of rubber mixtures filled with the samples under study are presented. A conclusion is made about the possibility of replacing channel technical carbon K354 with furnace black carbon N121 oxidized with 30% hydrogen peroxide.

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