Measurement of Gas Diffusivity In Heavy Oils

10.2118/98-63 ◽  
1998 ◽  
Author(s):  
Y. Zhang ◽  
C.L. Hyndman ◽  
B. Maini
Keyword(s):  
2000 ◽  
Vol 25 (1-2) ◽  
pp. 37-47 ◽  
Author(s):  
Y.P. Zhang ◽  
C.L. Hyndman ◽  
B.B. Maini
Keyword(s):  

Author(s):  
V.A. Munoz ◽  
R.J. Mikula ◽  
C. Payette ◽  
W.W. Lam

The transformation of high molecular weight components present in heavy oils into useable liquid fuels requires their decomposition by means of a variety of processes. The low molecular weight species produced recombine under controlled conditions to generate synthetic fuels. However, an important fraction undergo further recombination into higher molecular weight components, leading to the formation of coke. The optical texture of the coke can be related to its originating components. Those with high sulfur and oxygen content tend to produce cokes with small optical texture or fine mosaic, whereas compounds with relatively high hydrogen content are likely to produce large optical texture or domains. In addition, the structure of the parent chemical components, planar or nonplanar, determines the isotropic or anisotropic character of the coke. Planar molecules have a tendency to align in an approximately parallel arrangement to initiate the formation of the nematic mesophase leading to the formation of anisotropic coke. Nonplanar highly alkylated compounds and/or those rich in polar groups form isotropic coke. The aliphatic branches produce steric hindrance to alignment, whereas the polar groups participate in cross-linking reactions.


2008 ◽  
Author(s):  
Birol Demiral ◽  
Serhat Akin ◽  
Cagdas Acar ◽  
Berna Hascakir

Author(s):  
Pedro Romero Rojas ◽  
◽  
Alexandrina Cristea ◽  
Paul Pavlakos ◽  
Okan Ergündüz ◽  
...  

Agriculture ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 443
Author(s):  
Camille Rousset ◽  
Timothy J. Clough ◽  
Peter R. Grace ◽  
David W. Rowlings ◽  
Clemens Scheer

Pastures require year-round access to water and in some locations rely on irrigation during dry periods. Currently, there is a dearth of knowledge about the potential for using irrigation to mitigate N2O emissions. This study aimed to mitigate N2O losses from intensely managed pastures by adjusting irrigation frequency using soil gas diffusivity (Dp/Do) thresholds. Two irrigation regimes were compared; a standard irrigation treatment based on farmer practice (15 mm applied every 3 days) versus an optimised irrigation treatment where irrigation was applied when soil Dp/Do was ≈0.033 (equivalent to 50% of plant available water). Cow urine was applied at a rate of 700 kg N ha−1 to simulate a ruminant urine deposition event. In addition to N2O fluxes, soil moisture content was monitored hourly, Dp/Do was modelled, and pasture dry matter production was measured. Standard irrigation practices resulted in higher (p = 0.09) cumulative N2O emissions than the optimised irrigation treatment. Pasture growth rates under treatments did not differ. Denitrification during re-wetting events (irrigation and rain) contributed to soil N2O emissions. These results warrant further modelling of irrigation management as a mitigation option for N2O emissions from pasture soils, based on Dp/Do thresholds, rainfall, plant water demands and evapotranspiration.


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