Characterization of Surfactants Using a Scaling Law Interpretation of Coreflood Residual Oil Saturation Profiles

1983 ◽  
Vol 23 (03) ◽  
pp. 511-518
Author(s):  
L.A. Davis ◽  
T.N. Tyler ◽  
D.F. Brost ◽  
H.K. Haskin
Keyword(s):  
Microwave Absorption ◽  
Oil Recovery ◽  
Scaling Law ◽  
Linear Scaling ◽  
Chemical Flooding ◽  
Residual Oil ◽  
Oil Saturation ◽  
Residual Oil Saturation ◽  
Saturation Profiles

Abstract The characterization of surfactant candidates for a given reservoir can be improved by the use of linear coreflood residual-oil-saturation profiles measured along the core after chemical flooding. A surfactant formulation's functional relation of oil recovery to slug size can be calculated from a single coreflood with the assumption of a relaxed scaling law. A volumetric linear scaling approach is developed from laboratory coreflood data. Residual-oil-saturation profiles measured in reservoir material with a microwave absorption instrument support this approximate scaling relation. Analysis of 32 linear surfactant-slug corefloods is presented as additional verification. The limits of this scaling law are defined, with emphasis on the role of mixing and dispersion. The procedure for using saturation profiles to calculate oil recovery as a function of slug size is developed and a test case is presented. A recovery relation derived from a single coreflood saturation profile is compared with that determined by multiple conventional corefloods. Introduction Many techniques and instruments are now available for noninvasive measurement of oil/brine saturations along linear cores during secondary and tertiary displacement experiments, these are reviewed briefly in Ref. 1. The most popular recent method is based on the microwave absorption properties of water. Such saturation- profile measurements provide much more information on a given chemical-flood experiment than can be collected merely from effluent material balance. This abundance of data can be used in two ways: to determine relations that would otherwise have to be developed laboriously from many separate conventional corefloods and to develop predictive capability for estimating surfactant- flood performance in new situations. Both applications are possible as an outgrowth of the concept of volumetric linear scaling for chemical flooding proposed by Parsons and Jones. This relaxed scaling technique is supported by the data of Ref. 6 and a wide variety of conventional and scanned corefloods presented in this work. A process can be defined as volumetrically linearly scalable if the fluid compositions and saturations at any point in the matrix at any time are functions only of the PV of fluids injected relative to that point with respect to the injection point. This can be stated simply for a single slug of surfactant: a given-PV slug of surfactant will produce the same compositions and saturation distributions in a core of any physical shape and size. Moreover, a 0. 10-PV slug injected into a 2-m core will produce the same composition and saturation distribution in the first meter of that core as would be produced over the entire length of a 1-m core that had seen a 0.20-PV slug. This is a trivial-but not an obvious-view of the recovery process. Limitations to this relative-sizing concept are discussed in the following paragraph. SPEJ P. 511^

Relationship between Residual Saturations and Wettability using Pore-Network Modeling

2021 ◽  
Author(s):  
Prakash Purswani ◽  
Russell T. Johns ◽  
Zuleima T. Karpyn
Keyword(s):  
Contact Angle ◽  
Oil Recovery ◽  
Network Modeling ◽  
Pore Network ◽  
Residual Oil ◽  
Residual Saturation ◽  
Oil Saturation ◽  
Pore Network Modeling ◽  
Residual Oil Saturation ◽  
Eor Processes

Abstract The relationship between residual saturation and wettability is critical for modeling enhanced oil recovery (EOR) processes. The wetting state of a core is often quantified through Amott indices, which are estimated from the ratio of the saturation fraction that flows spontaneously to the total saturation change that occurs due to spontaneous flow and forced injection. Coreflooding experiments have shown that residual oil saturation trends against wettability indices typically show a minimum around mixed-wet conditions. Amott indices, however, provides an average measure of wettability (contact angle), which are intrinsically dependent on a variety of factors such as the initial oil saturation, aging conditions, etc. Thus, the use of Amott indices could potentially cloud the observed trends of residual saturation with wettability. Using pore network modeling (PNM), we show that residual oil saturation varies monotonically with the contact angle, which is a direct measure of wettability. That is, for fixed initial oil saturation, the residual oil saturation decreases monotonically as the reservoir becomes more water-wet (decreasing contact angle). Further, calculation of Amott indices for the PNM data sets show that a plot of the residual oil saturation versus Amott indices also shows this monotonic trend, but only if the initial oil saturation is kept fixed. Thus, for the cases presented here, we show that there is no minimum residual saturation at mixed-wet conditions as wettability changes. This can have important implications for low salinity waterflooding or other EOR processes where wettability is altered.

scholarly journals SURFACTANT-POLYMER FLOODING PERFORMANCE IN HETEROGENEOUS TWO-LAYERED POROUS MEDIA

2011 ◽  
Vol 12 (1) ◽  
pp. 31-38 ◽  
Author(s):  
Muhammad Taufiq Fathaddin ◽  
Asri Nugrahanti ◽  
Putri Nurizatulshira Buang ◽  
Khaled Abdalla Elraies
Keyword(s):  
Porous Media ◽  
Oil Recovery ◽  
Polymer Flooding ◽  
Water Flooding ◽  
Residual Oil ◽  
Oil Saturation ◽  
Reservoir Heterogeneity ◽  
Residual Oil Saturation ◽  
Layered Porous Media ◽  
Multiple Porosity

In this paper, simulation study was conducted to investigate the effect of spatial heterogeneity of multiple porosity fields on oil recovery, residual oil and microemulsion saturation. The generated porosity fields were applied into UTCHEM for simulating surfactant-polymer flooding in heterogeneous two-layered porous media. From the analysis, surfactant-polymer flooding was more sensitive than water flooding to the spatial distribution of multiple porosity fields. Residual oil saturation in upper and lower layers after water and polymer flooding was about the same with the reservoir heterogeneity. On the other hand, residual oil saturation in the two layers after surfactant-polymer flooding became more unequal as surfactant concentration increased. Surfactant-polymer flooding had higher oil recovery than water and polymer flooding within the range studied. The variation of oil recovery due to the reservoir heterogeneity was under 9.2%.

Laboratory Tests on Heavy Oil Recovery by Steam Injection

1983 ◽  
Vol 23 (03) ◽  
pp. 417-426 ◽  
Author(s):  
Philip J. Closmann ◽  
Richard D. Seba
Keyword(s):  
Pore Size ◽  
Heat Loss ◽  
Oil Recovery ◽  
Heavy Oil ◽  
Steam Injection ◽  
Residual Oil ◽  
Oil Saturation ◽  
Residual Oil Saturation ◽  
The Core ◽  
Unconsolidated Sand

Abstract This paper presents results of laboratory experiments conducted to determine the effect of various parameters on residual oil saturation from steamdrives of heavy-oil reservoirs. These experiments indicated that remaining oil saturation, both at steam breakthrough and after passage of several PV of steam, is a function of oil/water viscosity ratio at saturated steam conditions. Introduction Considerable attention has been given to thermal techniques for stimulating production of underground hydrocarbons, particularly the more viscous oils production of underground hydrocarbons, particularly the more viscous oils and tars. Steam injection has been studied as one means of heating oil in place, reducing its viscosity, and thus making its displacement easier. place, reducing its viscosity, and thus making its displacement easier. A number of investigators have measured residual oil saturations remaining in the steam zone. Willman et al. also analyzed the steam displacement process to account for the oil recoveries observed. A number of methods have been developed to calculate the size of the steam zone and to predict oil recoveries by application of Buckley-Leverett theory, including the use of numerical simulation. The work described here was devoted to an experimental determination of oil recovery by steam injection in linear systems. The experiments were unscaled as far as fluid flow rates, gravity forces, and heat losses were concerned. Part of the study was to determine recoveries of naturally occurring very viscous tars in a suite of cores containing their original oil saturation. The cores numbered 95, 140, and 143 are a part of this group. Heterogeneities in these cores, however, led to the extension of the work to more uniform systems, such as sandpacks and Dalton sandstone cores. Our interest was in obtaining an overall view of important variables that affected recovery. In particular, because of the significant effect of steam distillation, most of the oils used in this study were chosen to avoid this factor. We also studied the effect of pore size on the residual oil saturation. As part of this work, we investigated the effect of the amount of water flushed through the system ahead of the steam front in several ways:the production rate was varied by a factor of four,the initial oil saturation was varied by a factor of two, andthe rate of heat loss was varied by removing the heat insulation from the flow system. Description of Apparatus and Experimental Technique Two types of systems were studied: unconsolidated sand and consolidated sandstone. The former type was provided by packing a section of pipe with 50–70 mesh Ottawa sand. Most runs on this type of system were in an 18-in. (45.72-cm) section of 1 1/2 -in. (3.8 1 -cm) diameter pipe, although runs on 6-in. (15.24-cm) and 5-ft (152.4-cm) lengths were also included. Consolidated cores 9 to 13 in. (22.86 to 33.02 cm) long and approximately 2 1/4 in. (5.72 cm) in diameter were sealed in a piece of metal pipe by means of an Epon/sand mixture. A photograph of two 9-in. (22.86-cm) consolidated natural cores (marked 95 and 143) from southwest Missouri, containing original oil, is shown as Fig. 1. In all steamdrive runs, the core was thermally insulated to reduce heat loss, unless the effect of heat loss was specifically being studied. Flow was usually horizontal except for the runs in which the effects of flushing water volume and of unconsolidated-sand pore size were examined. Micalex end pieces were used on the inlet end in initial experiments with consolidated cores to reduce heat leakage from the steam line to the metal jacket on the outside of the core. During most runs, however, the entire input assembly eventually became hot. SPEJ p. 417

scholarly journals MICROEMULSION FLOODING MECHANISM FOR OPTIMUM OIL RECOVERY ON CHEMICAL INJECTION

2018 ◽  
Vol 40 (2) ◽  
pp. 85-90
Author(s):  
Yani Faozani Alli ◽  
Edward ML Tobing ◽  
Usman Usman
Keyword(s):  
Oil Recovery ◽  
Mobility Control ◽  
Chemical Flooding ◽  
Residual Oil ◽  
Core Flooding ◽  
Oil Viscosity ◽  
Oil Saturation ◽  
Remaining Oil ◽  
Tertiary Oil Recovery

The formation of microemulsion in the injection of surfactant at chemical flooding is crucial for the effectiveness of injection. Microemulsion can be obtained either by mixing the surfactant and oil at the surface or injecting surfactant into the reservoir to form in situ microemulsion. Its translucent homogeneous mixtures of oil and water in the presence of surfactant is believed to displace the remaining oil in the reservoir. Previously, we showed the effect of microemulsion-based surfactant formulation to reduce the interfacial tension (IFT) of oil and water to the ultralow level that suffi cient enough to overcome the capillary pressure in the pore throat and mobilize the residual oil. However, the effectiveness of microemulsion flooding to enhance the oil recovery in the targeted representative core has not been investigated.In this article, the performance of microemulsion-based surfactant formulation to improve the oil recovery in the reservoir condition was investigated in the laboratory scale through the core flooding experiment. Microemulsion-based formulation consist of 2% surfactant A and 0.85% of alkaline sodium carbonate (Na2CO3) were prepared by mixing with synthetic soften brine (SSB) in the presence of various concentration of polymer for improving the mobility control. The viscosity of surfactant-polymer in the presence of alkaline (ASP) and polymer drive that used for chemical injection slug were measured. The tertiary oil recovery experiment was carried out using core flooding apparatus to study the ability of microemulsion-based formulation to recover the oil production. The results showed that polymer at 2200 ppm in the ASP mixtures can generate 12.16 cP solution which is twice higher than the oil viscosity to prevent the fi ngering occurrence. Whereas single polymer drive at 1300 ppm was able to produce 15.15 cP polymer solution due to the absence of alkaline. Core flooding experiment result with design injection of 0.15 PV ASP followed by 1.5 PV polymer showed that the additional oil recovery after waterflood can be obtained as high as 93.41% of remaining oil saturation after waterflood (Sor), or 57.71% of initial oil saturation (Soi). Those results conclude that the microemulsion-based surfactant flooding is the most effective mechanism to achieve the optimum oil recovery in the targeted reservoir.

scholarly journals Modeling Wettability Variation during Long-Term Water Flooding

2015 ◽  
Vol 2015 ◽  
pp. 1-11 ◽  
Author(s):  
Renyi Cao ◽  
Changwei Sun ◽  
Y. Zee Ma
Keyword(s):  
Oil Recovery ◽  
Water Flooding ◽  
Residual Oil ◽  
Displacement Efficiency ◽  
Oil Saturation ◽  
Residual Oil Saturation ◽  
Polar Substance ◽  
Oil Displacement Efficiency ◽  
Reservoir Wettability

Surface property of rock affects oil recovery during water flooding. Oil-wet polar substances adsorbed on the surface of the rock will gradually be desorbed during water flooding, and original reservoir wettability will change towards water-wet, and the change will reduce the residual oil saturation and improve the oil displacement efficiency. However there is a lack of an accurate description of wettability alternation model during long-term water flooding and it will lead to difficulties in history match and unreliable forecasts using reservoir simulators. This paper summarizes the mechanism of wettability variation and characterizes the adsorption of polar substance during long-term water flooding from injecting water or aquifer and relates the residual oil saturation and relative permeability to the polar substance adsorbed on clay and pore volumes of flooding water. A mathematical model is presented to simulate the long-term water flooding and the model is validated with experimental results. The simulation results of long-term water flooding are also discussed.

Thermal Stability of Surfactants for Reservoir Application (includes associated papers 11323 and 11597 )

1982 ◽  
Vol 22 (05) ◽  
pp. 722-730 ◽  
Author(s):  
L.L. Handy ◽  
J.O. Amaefule ◽  
V.M. Ziegler ◽  
I. Ershaghi
Keyword(s):  
Nonionic Surfactant ◽  
Oil Recovery ◽  
Half Life ◽  
Elevated Temperatures ◽  
Effect Of Temperature ◽  
Residual Oil ◽  
Chemical Additives ◽  
Thermal Stabilities ◽  
Oil Saturation ◽  
Residual Oil Saturation

Abstract The thermal stabilities of several sulfonate surfactantsand one nonionic surfactant have been evaluated. Thedecomposition reactions have been observed to followfirst-order kinetics. Consequently, a quantitativemeasure of a surfactant's stability at a given temperatureis its half-life. Furthermore, the activation energy can beestimated from rate data obtained at two or moretemperatures. This permits limited extrapolation of theobserved decomposition rates to lower temperatures forwhich the rates are too low for convenient measurement.The surfactants we investigated are being considered forsteamflood additives and need to be relatively stable atsteam temperatures.None of the surfactants evaluated to date has therequisite stability for use in steamfloods. The most stablepetroleum sulfonate we have investigated has a half-lifeof 11 days at 180 degrees C (356 degrees F). With this half-life, substantial overdosing would be required tomaintain the minimum effective surfactant concentration forthe life of the flood. On the other hand, the estimatedhalflife for this surfactant at 93 degrees C (200 degrees F), calculated by extrapolation, would be 33 years.Tests with the nonionic surfactant, nonylphenoxy-polyethanol, have shown this material to have a very short half-life at steam temperatures, but it doesappear to be more stable at concentrations greater than thecritical micelle concentration(CMC). In limited tests, the sulfonates showed increased stability in the presenceof a 2-M salt solution. Introduction Several chemical additives are being considered for usewith steamfloods to reduce the producing steam/oilratios and to increase oil recovery from steam projects.The emphasis to date has been on inorganic chemicaladditives. Sodium hydroxide has been used in the fieldwithout success. We have been investigating thepotential benefits of using organic surfactants. This hasbeen discusssed recently by Brown et al. and byGopalakrishnan et al. The surfactant would be introducedinto the reservoir along, with the steam at the beginning ofthe steamflood and, possibly, intermittently during the floodprocess. The surfactant would be injected in diluteconcentrations and would be expected to travel in thatportion of the reservoir being flooded by hot water.Although the residual oil saturation in the steam zone has been observed to be very low, residual saturation in thehot water portion of the steamflood is expected to be thenormal waterflood residual. A surfactant in the hot watermay reduce this residual oil saturation. A synergistic effect could be observed between the surfactant and thetemperature to give better performance than would beobserved for a surfactant flood at normal reservoirtemperatures.For the process to work as anticipated, the surfactantmust move in the heated portion of the reservoir, and it must be sufficiently stable at elevated temperatures tofunction as an effective recovery agent for the life of theflood. Therefore, two aspects of the process are beingstudied simultaneously. One of these is the effect oftemperature on adsorption of the surfactants, and theother is the effect of heat on the stability of thesurfactants. The effect of temperature on adsorption will bediscussed in a later paper. The objective of this paper isto discuss the experimental evaluation of the thermalstability of some surfactant types that could haveapplication in reservoir floods. The effect of temperatureon adsorption and stability of these surfactants also willbe important in micellar floods at higher reservoirtemperatures. Experimental Procedures Several anionic and noninoic surfactants were selectedfor evaluation. SPEJ P. 722^

Peripheral Low Salinity Water Injection Handil Case Study

2021 ◽  
Author(s):  
Julfree Sianturi ◽  
Bayu Setyo Handoko ◽  
Aditya Suardiputra ◽  
Radya Senoputra
Keyword(s):  
Oil Recovery ◽  
Water Injection ◽  
Water Flooding ◽  
Residual Oil ◽  
Oil Saturation ◽  
Residual Oil Saturation ◽  
Low Salinity ◽  
Low Salinity Water ◽  
Salinity Water ◽  
Low Salinity Water Injection

Abstract Handil Field is a giant mature oil and gas field situated in Mahakam Delta, East Kalimantan Indonesia. Peripheral Low Salinity Water injection was performed since 1978 with an extraordinary result. The paper is intending to describe the success story of this secondary recovery by low salinity water injection application in the peripheral of Handil field main zone, which successfully increased the oil recovery and brought down the remaining oil saturation beyond the theoretical value of residual oil saturation number. Water producer wells were drilled to produce low salinity water from shallow reservoirs 400 - 1000 m depth then it was injected to main zone reservoirs where the main accumulation of oil situated. This low salinity water reacted positively with the rock properties and in-situ fluids which was described as wettability alteration in the reservoir. It is related to initial reservoir condition, connate water saturation, rock physics and connate water salinity. This peripheral scheme then observed having the sweeping effect on top of pressure maintenance due to long period of injection. The field production performance was indicating the important reduction of residual oil saturation in some reservoirs with continuous low salinity water injection. From static Oil in Place calculation, some reservoirs have high current oil recovery up to 80%. This was proved by in situ residual oil saturation measurement which was performed in 2007 and 2011. It was indicating the low residual saturation as low as 8% - 15%. This excellent result was embraced by a progressive development plan, where water flooding with pattern and chemical injection will be performed later on. The continuation of this peripheral injection is in an on-going development with patterns injection which is called water flooding development. An important oil recovery can be achieved with a simple scheme of low salinity injection, performed in a close network injection, where the water treatment is simple yet significant oil gain was recovered. This innovation technique brings more revenue with less investment compared to chemical EOR injection.

Heavy Oil Recovery by Alkaline-Cosolvent-Polymer Flood: A Multi-Scale Research Using CT Imaging

2021 ◽  
Author(s):  
Hang Su ◽  
Fujian Zhou ◽  
Lida Wang ◽  
Chuan Wang ◽  
Lixia Kang ◽  
...  
Keyword(s):  
Computed Tomography ◽  
Ct Scan ◽  
Enhanced Oil Recovery ◽  
Oil Recovery ◽  
Micro Ct ◽  
Residual Oil ◽  
Micro Computed Tomography ◽  
Total Acid ◽  
Oil Saturation ◽  
Residual Oil Saturation

Abstract For reservoirs containing oil with a high total acid number, alkali-cosolvent-polymer (ACP) flood can potentially increase the oil recovery by its saponification effects. The enhanced oil recovery performance of ACP flood has been studied at core and reservoir scale in detail, however, the effect of ACP flood on residual oil saturation in the swept area still lacks enough research. Medical computed tomography (Medical-CT) scan and micro computed tomography (Micro-CT) scan are used in combination to visualize micro-scale flow and reveal the mechanisms of residual oil reduction during ACP flood. The heterogeneous cores containing two layers of different permeability are used for coreflood experiment to clarify the enhanced oil recovery (EOR) performance of ACP food in heterogeneous reservoirs. The oil saturation is monitored by Medical-CT. Then, two core samples are drilled in each core after flooding and the decrease of residual oil saturation caused by ACP flood is further quantified by Micro-CT imageing. Results show that ACP flood is 14.5% oil recovery higher than alkaline-cosolvent (AC) flood (68.9%) in high permeability layers, 17.9% higher than AC flood (26.3%) in low permeability layers. Compared with AC flood, ACP flood shows a more uniform displacement front, which implies that the injected polymer effectively weakened the viscosity fingering. Moreover, a method that can calculate the ratio of oil-water distribution in each pore is developed to establish the relationship between the residual oil saturation of each pore and its pore size, and reached the conclusion that they follow the power law correlation.

Sulfonate Retention and Residual Oil Saturation

1983 ◽  
Vol 23 (02) ◽  
pp. 349-357 ◽  
Author(s):  
C. Travis Presley
Keyword(s):  
Oil Recovery ◽  
Core Material ◽  
Residual Oil ◽  
Oil Saturation ◽  
Residual Oil Saturation ◽  
The Core ◽  
Polymer Flood ◽  
Core Elements ◽  
The Individual ◽  
Individual Core

Abstract This paper describes an empirical relationship between sulfonate retention and final residual oil saturation achieved by a micellar/polymer oil-recovery process. Using this relationship and certain assumptions, one can derive expressions for predicting oil recovery performance in coreflood experiments. The equations contain two experimental constants:sulfonate retention anda factor related to the oil-recovery efficiency of the sulfonate slug in cores, specific to both the slug and core material. This same relationship applies to both linear and radial cores. The equations derived predict nonlinear scaling effects. These effects have been demonstrated in laboratory corefloods. Introduction Sulfonate retention, as defined in the literature, represents the loss of a critical component and consequently affects the efficiency of micellar/polymer oil-recovery processes. In this case, sulfonate retention is discussed in connection with laboratory corefloods. An operational definition of the retained sulfonate is that quantity of sulfonate remaining in the core, by whatever mechanism, after a core has been flushed with drive fluid to final oil saturation. The remainder of the originally injected sulfonate has presumably been propagated through the core. For the systems studied. a relationship has been found between residual oil saturation after a micellar/polymer flood and the net amount of sulfonate propagated through a given element of core. This relationship was established by determining residual oil saturation and sulfonate retention in successive sections of flooded cores taken along the direction of increasing travel of micellar slug. The measurements were obtained by a postflood extraction of these core sections and subsequent analysis of the extract. These data were analyzed by viewing a coreflood as a series of smaller sequential floods of the core elements where each successive element was treated with less sulfonate. Effect of Sulfonate Retention on Residual Oil Saturation Linear Cores Coreflood data were collected using Slug A and Henry crude oil in fired Berea sandstone cores that previously had been waterflooded to residual oil saturation. Slug composition is given in Appendix A. Each coreflood experiment was performed using four cylindrical cores connected in series to form one composite core. The individual core segments were each 2 in. × 1 ft long (5.2 cm × 30.5 cm), so that the composite core was 4 ft (1.2 m) long. Experimental details of the flooding method are discussed in Appendix B. After a micellar/polymer flood was completed, the composite core was separated and the individual core elements were analyzed for oil saturation and sulfonate retention. The analytical procedure is described in Appendix B and is patterned after the method described by Smith et al. By performing the experiments in this way, we obtain the average residual oil saturation over the individual segments of a flooded core. We have called these values "point oil saturation," (Sor)m, to distinguish them from the average oil saturation over the composite core, which we have called average oil saturation," S orj. Fig. 1 shows two interpretations of these tandem corefloods. Fig. 1a shows the quantities that are measured experimentally. The amount of sulfonate initially injected (m 1) is known, as is the weight of each core segment (mCi). SPEJ P. 349^

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