Laboratory Tests on Heavy Oil Recovery by Steam Injection

1983 ◽  
Vol 23 (03) ◽  
pp. 417-426 ◽  
Author(s):  
Philip J. Closmann ◽  
Richard D. Seba

Abstract This paper presents results of laboratory experiments conducted to determine the effect of various parameters on residual oil saturation from steamdrives of heavy-oil reservoirs. These experiments indicated that remaining oil saturation, both at steam breakthrough and after passage of several PV of steam, is a function of oil/water viscosity ratio at saturated steam conditions. Introduction Considerable attention has been given to thermal techniques for stimulating production of underground hydrocarbons, particularly the more viscous oils production of underground hydrocarbons, particularly the more viscous oils and tars. Steam injection has been studied as one means of heating oil in place, reducing its viscosity, and thus making its displacement easier. place, reducing its viscosity, and thus making its displacement easier. A number of investigators have measured residual oil saturations remaining in the steam zone. Willman et al. also analyzed the steam displacement process to account for the oil recoveries observed. A number of methods have been developed to calculate the size of the steam zone and to predict oil recoveries by application of Buckley-Leverett theory, including the use of numerical simulation. The work described here was devoted to an experimental determination of oil recovery by steam injection in linear systems. The experiments were unscaled as far as fluid flow rates, gravity forces, and heat losses were concerned. Part of the study was to determine recoveries of naturally occurring very viscous tars in a suite of cores containing their original oil saturation. The cores numbered 95, 140, and 143 are a part of this group. Heterogeneities in these cores, however, led to the extension of the work to more uniform systems, such as sandpacks and Dalton sandstone cores. Our interest was in obtaining an overall view of important variables that affected recovery. In particular, because of the significant effect of steam distillation, most of the oils used in this study were chosen to avoid this factor. We also studied the effect of pore size on the residual oil saturation. As part of this work, we investigated the effect of the amount of water flushed through the system ahead of the steam front in several ways:the production rate was varied by a factor of four,the initial oil saturation was varied by a factor of two, andthe rate of heat loss was varied by removing the heat insulation from the flow system. Description of Apparatus and Experimental Technique Two types of systems were studied: unconsolidated sand and consolidated sandstone. The former type was provided by packing a section of pipe with 50–70 mesh Ottawa sand. Most runs on this type of system were in an 18-in. (45.72-cm) section of 1 1/2 -in. (3.8 1 -cm) diameter pipe, although runs on 6-in. (15.24-cm) and 5-ft (152.4-cm) lengths were also included. Consolidated cores 9 to 13 in. (22.86 to 33.02 cm) long and approximately 2 1/4 in. (5.72 cm) in diameter were sealed in a piece of metal pipe by means of an Epon/sand mixture. A photograph of two 9-in. (22.86-cm) consolidated natural cores (marked 95 and 143) from southwest Missouri, containing original oil, is shown as Fig. 1. In all steamdrive runs, the core was thermally insulated to reduce heat loss, unless the effect of heat loss was specifically being studied. Flow was usually horizontal except for the runs in which the effects of flushing water volume and of unconsolidated-sand pore size were examined. Micalex end pieces were used on the inlet end in initial experiments with consolidated cores to reduce heat leakage from the steam line to the metal jacket on the outside of the core. During most runs, however, the entire input assembly eventually became hot. SPEJ p. 417

1983 ◽  
Vol 23 (02) ◽  
pp. 349-357 ◽  
Author(s):  
C. Travis Presley

Abstract This paper describes an empirical relationship between sulfonate retention and final residual oil saturation achieved by a micellar/polymer oil-recovery process. Using this relationship and certain assumptions, one can derive expressions for predicting oil recovery performance in coreflood experiments. The equations contain two experimental constants:sulfonate retention anda factor related to the oil-recovery efficiency of the sulfonate slug in cores, specific to both the slug and core material. This same relationship applies to both linear and radial cores. The equations derived predict nonlinear scaling effects. These effects have been demonstrated in laboratory corefloods. Introduction Sulfonate retention, as defined in the literature, represents the loss of a critical component and consequently affects the efficiency of micellar/polymer oil-recovery processes. In this case, sulfonate retention is discussed in connection with laboratory corefloods. An operational definition of the retained sulfonate is that quantity of sulfonate remaining in the core, by whatever mechanism, after a core has been flushed with drive fluid to final oil saturation. The remainder of the originally injected sulfonate has presumably been propagated through the core. For the systems studied. a relationship has been found between residual oil saturation after a micellar/polymer flood and the net amount of sulfonate propagated through a given element of core. This relationship was established by determining residual oil saturation and sulfonate retention in successive sections of flooded cores taken along the direction of increasing travel of micellar slug. The measurements were obtained by a postflood extraction of these core sections and subsequent analysis of the extract. These data were analyzed by viewing a coreflood as a series of smaller sequential floods of the core elements where each successive element was treated with less sulfonate. Effect of Sulfonate Retention on Residual Oil Saturation Linear Cores Coreflood data were collected using Slug A and Henry crude oil in fired Berea sandstone cores that previously had been waterflooded to residual oil saturation. Slug composition is given in Appendix A. Each coreflood experiment was performed using four cylindrical cores connected in series to form one composite core. The individual core segments were each 2 in. × 1 ft long (5.2 cm × 30.5 cm), so that the composite core was 4 ft (1.2 m) long. Experimental details of the flooding method are discussed in Appendix B. After a micellar/polymer flood was completed, the composite core was separated and the individual core elements were analyzed for oil saturation and sulfonate retention. The analytical procedure is described in Appendix B and is patterned after the method described by Smith et al. By performing the experiments in this way, we obtain the average residual oil saturation over the individual segments of a flooded core. We have called these values "point oil saturation," (Sor)m, to distinguish them from the average oil saturation over the composite core, which we have called average oil saturation," S orj. Fig. 1 shows two interpretations of these tandem corefloods. Fig. 1a shows the quantities that are measured experimentally. The amount of sulfonate initially injected (m 1) is known, as is the weight of each core segment (mCi). SPEJ P. 349^


2021 ◽  
Author(s):  
Randy Agra Pratama ◽  
Tayfun Babadagli

Abstract Our previous research, honoring interfacial properties, revealed that the wettability state is predominantly caused by phase change—transforming liquid phase to steam phase—with the potential to affect the recovery performance of heavy-oil. Mainly, the system was able to maintain its water-wetness in the liquid (hot-water) phase but attained a completely and irrevocably oil-wet state after the steam injection process. Although a more favorable water-wetness was presented at the hot-water condition, the heavy-oil recovery process was challenging due to the mobility contrast between heavy-oil and water. Correspondingly, we substantiated that the use of thermally stable chemicals, including alkalis, ionic liquids, solvents, and nanofluids, could propitiously restore the irreversible wettability. Phase distribution/residual oil behavior in porous media through micromodel study is essential to validate the effect of wettability on heavy-oil recovery. Two types of heavy-oils (450 cP and 111,600 cP at 25oC) were used in glass bead micromodels at steam temperatures up to 200oC. Initially, the glass bead micromodels were saturated with synthesized formation water and then displaced by heavy-oils. This process was done to exemplify the original fluid saturation in the reservoirs. In investigating the phase change effect on residual oil saturation in porous media, hot-water was injected continuously into the micromodel (3 pore volumes injected or PVI). The process was then followed by steam injection generated by escalating the temperature to steam temperature and maintaining a pressure lower than saturation pressure. Subsequently, the previously selected chemical additives were injected into the micromodel as a tertiary recovery application to further evaluate their performance in improving the wettability, residual oil, and heavy-oil recovery at both hot-water and steam conditions. We observed that phase change—in addition to the capillary forces—was substantial in affecting both the phase distribution/residual oil in the porous media and wettability state. A more oil-wet state was evidenced in the steam case rather than in the liquid (hot-water) case. Despite the conditions, auspicious wettability alteration was achievable with thermally stable surfactants, nanofluids, water-soluble solvent (DME), and switchable-hydrophilicity tertiary amines (SHTA)—improving the capillary number. The residual oil in the porous media yielded after injections could be favorably improved post-chemicals injection; for example, in the case of DME. This favorable improvement was also confirmed by the contact angle and surface tension measurements in the heavy-oil/quartz/steam system. Additionally, more than 80% of the remaining oil was recovered after adding this chemical to steam. Analyses of wettability alteration and phase distribution/residual oil in the porous media through micromodel visualization on thermal applications present valuable perspectives in the phase entrapment mechanism and the performance of heavy-oil recovery. This research also provides evidence and validations for tertiary recovery beneficial to mature fields under steam applications.


2021 ◽  
Author(s):  
Prakash Purswani ◽  
Russell T. Johns ◽  
Zuleima T. Karpyn

Abstract The relationship between residual saturation and wettability is critical for modeling enhanced oil recovery (EOR) processes. The wetting state of a core is often quantified through Amott indices, which are estimated from the ratio of the saturation fraction that flows spontaneously to the total saturation change that occurs due to spontaneous flow and forced injection. Coreflooding experiments have shown that residual oil saturation trends against wettability indices typically show a minimum around mixed-wet conditions. Amott indices, however, provides an average measure of wettability (contact angle), which are intrinsically dependent on a variety of factors such as the initial oil saturation, aging conditions, etc. Thus, the use of Amott indices could potentially cloud the observed trends of residual saturation with wettability. Using pore network modeling (PNM), we show that residual oil saturation varies monotonically with the contact angle, which is a direct measure of wettability. That is, for fixed initial oil saturation, the residual oil saturation decreases monotonically as the reservoir becomes more water-wet (decreasing contact angle). Further, calculation of Amott indices for the PNM data sets show that a plot of the residual oil saturation versus Amott indices also shows this monotonic trend, but only if the initial oil saturation is kept fixed. Thus, for the cases presented here, we show that there is no minimum residual saturation at mixed-wet conditions as wettability changes. This can have important implications for low salinity waterflooding or other EOR processes where wettability is altered.


2011 ◽  
Vol 12 (1) ◽  
pp. 31-38 ◽  
Author(s):  
Muhammad Taufiq Fathaddin ◽  
Asri Nugrahanti ◽  
Putri Nurizatulshira Buang ◽  
Khaled Abdalla Elraies

In this paper, simulation study was conducted to investigate the effect of spatial heterogeneity of multiple porosity fields on oil recovery, residual oil and microemulsion saturation. The generated porosity fields were applied into UTCHEM for simulating surfactant-polymer flooding in heterogeneous two-layered porous media. From the analysis, surfactant-polymer flooding was more sensitive than water flooding to the spatial distribution of multiple porosity fields. Residual oil saturation in upper and lower layers after water and polymer flooding was about the same with the reservoir heterogeneity. On the other hand, residual oil saturation in the two layers after surfactant-polymer flooding became more unequal as surfactant concentration increased. Surfactant-polymer flooding had higher oil recovery than water and polymer flooding within the range studied. The variation of oil recovery due to the reservoir heterogeneity was under 9.2%.


SPE Journal ◽  
2010 ◽  
Vol 15 (04) ◽  
pp. 943-951 ◽  
Author(s):  
A.. Saraf ◽  
A.H. de Zwart ◽  
Peter K. Currie ◽  
Mohammad A.J. Ali

Summary Recently, it has been shown that the presence of residual oil in a formation can have a considerable influence on the trapping mechanisms for particles present in reinjected produced water (Ali 2007; Ali et al. 2005, 2007, 2009). This article reports on a further set of extensive coreflow experiments that confirm and extend these results. The tests were conducted in a computerized-tomography (CT) scanner, allowing direct observation of the buildup of particle deposition along the core. These experiments are relevant to operational issues associated with produced-water reinjection (PWRI). In many cases, produced water is injected into formations containing oil, so reduced oil saturation is achieved rapidly in the area around the well. Even if the well is outside the oil zone, trapped oil droplets are always present in produced water, and a residual-oil zone will gradually build up around the well. Major differences are found between the deposition profiles for fully water-saturated cores and the cores having residual-oil saturation. In particular, particles penetrate deeper into the core with residual-oil saturation, and considerably more particles pass completely through the core without being trapped. The X-ray technique allows direct observation during the experiment of the deposition process inside the core, eliminating the complicating effect of any external filter cake. As a result, an analysis can be performed of the deposition parameters relevant inside the core using deep-bed-filtration theory, and the results of this analysis are presented. In particular, it is shown that the values of the filtration function determined from the CT-scan (X-ray) data are consistent with those obtained from analysis of the effluent concentration. Moreover, both methods of analysis find quite clearly that the filtration coefficient increases with decreasing flow rate. The results indicate that formation damage near a wellbore during water injection will be reduced by the presence of residual oil, and that particles will penetrate deeper into the formation. The result is also relevant to injection under fracturing conditions because particle deposition in the wall of the fracture (where residual oil may be present) is one of the mechanisms governing fracture growth.


2020 ◽  
Vol 9 (2) ◽  
pp. 80-87
Author(s):  
Ahmad Muraji Suranto ◽  
Boni Swadesi ◽  
Indah Widyaningsih ◽  
Ratna Widyaningsih ◽  
Sri Wahyu Murni ◽  
...  

Steam injection can be success in increasing oil recovery by determining the steam chamber growth. It will impact on the steam distribution and steam performance in covering hot areas in the reservoir.  An injection plan and a proper cyclic steam stimulation (CSS) schedule are critical in predicting how steam chamber can grow and cover the heat area. A reservoir simulation model will be used to understand how CSS really impact in steam chamber generation and affect the oil recovery. This paper generates numerous scenarios to see how steam working in heavy oil system particularly in unconsolidated sand reservoir. Combine the CSS method and steam injection continue investigate in this research. We will validate the scenarios based on the how fast steam chest can grow and get maximum oil recovery. Reservoir simulation resulted how steam chest behavior in unconsolidated sand to improve oil recovery; It concluded that by combining CSS and Steam Injection, we may get a faster steam chest growth and higher oil recovery by 61.5% of heavy oil system.


2015 ◽  
Vol 2015 ◽  
pp. 1-11 ◽  
Author(s):  
Renyi Cao ◽  
Changwei Sun ◽  
Y. Zee Ma

Surface property of rock affects oil recovery during water flooding. Oil-wet polar substances adsorbed on the surface of the rock will gradually be desorbed during water flooding, and original reservoir wettability will change towards water-wet, and the change will reduce the residual oil saturation and improve the oil displacement efficiency. However there is a lack of an accurate description of wettability alternation model during long-term water flooding and it will lead to difficulties in history match and unreliable forecasts using reservoir simulators. This paper summarizes the mechanism of wettability variation and characterizes the adsorption of polar substance during long-term water flooding from injecting water or aquifer and relates the residual oil saturation and relative permeability to the polar substance adsorbed on clay and pore volumes of flooding water. A mathematical model is presented to simulate the long-term water flooding and the model is validated with experimental results. The simulation results of long-term water flooding are also discussed.


1982 ◽  
Vol 22 (05) ◽  
pp. 722-730 ◽  
Author(s):  
L.L. Handy ◽  
J.O. Amaefule ◽  
V.M. Ziegler ◽  
I. Ershaghi

Abstract The thermal stabilities of several sulfonate surfactantsand one nonionic surfactant have been evaluated. Thedecomposition reactions have been observed to followfirst-order kinetics. Consequently, a quantitativemeasure of a surfactant's stability at a given temperatureis its half-life. Furthermore, the activation energy can beestimated from rate data obtained at two or moretemperatures. This permits limited extrapolation of theobserved decomposition rates to lower temperatures forwhich the rates are too low for convenient measurement.The surfactants we investigated are being considered forsteamflood additives and need to be relatively stable atsteam temperatures.None of the surfactants evaluated to date has therequisite stability for use in steamfloods. The most stablepetroleum sulfonate we have investigated has a half-lifeof 11 days at 180 degrees C (356 degrees F). With this half-life, substantial overdosing would be required tomaintain the minimum effective surfactant concentration forthe life of the flood. On the other hand, the estimatedhalflife for this surfactant at 93 degrees C (200 degrees F), calculated by extrapolation, would be 33 years.Tests with the nonionic surfactant, nonylphenoxy-polyethanol, have shown this material to have a very short half-life at steam temperatures, but it doesappear to be more stable at concentrations greater than thecritical micelle concentration(CMC). In limited tests, the sulfonates showed increased stability in the presenceof a 2-M salt solution. Introduction Several chemical additives are being considered for usewith steamfloods to reduce the producing steam/oilratios and to increase oil recovery from steam projects.The emphasis to date has been on inorganic chemicaladditives. Sodium hydroxide has been used in the fieldwithout success. We have been investigating thepotential benefits of using organic surfactants. This hasbeen discusssed recently by Brown et al. and byGopalakrishnan et al. The surfactant would be introducedinto the reservoir along, with the steam at the beginning ofthe steamflood and, possibly, intermittently during the floodprocess. The surfactant would be injected in diluteconcentrations and would be expected to travel in thatportion of the reservoir being flooded by hot water.Although the residual oil saturation in the steam zone has been observed to be very low, residual saturation in thehot water portion of the steamflood is expected to be thenormal waterflood residual. A surfactant in the hot watermay reduce this residual oil saturation. A synergistic effect could be observed between the surfactant and thetemperature to give better performance than would beobserved for a surfactant flood at normal reservoirtemperatures.For the process to work as anticipated, the surfactantmust move in the heated portion of the reservoir, and it must be sufficiently stable at elevated temperatures tofunction as an effective recovery agent for the life of theflood. Therefore, two aspects of the process are beingstudied simultaneously. One of these is the effect oftemperature on adsorption of the surfactants, and theother is the effect of heat on the stability of thesurfactants. The effect of temperature on adsorption will bediscussed in a later paper. The objective of this paper isto discuss the experimental evaluation of the thermalstability of some surfactant types that could haveapplication in reservoir floods. The effect of temperatureon adsorption and stability of these surfactants also willbe important in micellar floods at higher reservoirtemperatures. Experimental Procedures Several anionic and noninoic surfactants were selectedfor evaluation. SPEJ P. 722^


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