A Technique For Measuring Steam And Water Relative Permeabilities At Residual Oil In Natural Cores: CT Scan Saturations

1993 ◽  
Vol 32 (09) ◽  
Author(s):  
Philip J. Closmann ◽  
Harold J. Vinegar
1975 ◽  
Vol 15 (05) ◽  
pp. 376-384 ◽  
Author(s):  
R.M. Weinbrandt ◽  
H.J. Ramey ◽  
F.J. Casse

MEMBERS SPE-AIME Abstract Equipment was constructed to perform dynamic displacement experiments on small core samples under conditions of elevated temperature. Oil-water flowing fraction and pressure drop were recorded continuously for calculation of both the relative permeability ratio and the individual relative permeability ratio and the individual relative permeabilities. Imbibition relative permeabilities permeabilities. Imbibition relative permeabilities were measured for five samples of Boise sandstone at room temperature and at 175deg.F. The fluids used were distilled water and a white mineral oil. The effect of temperature on absolute permeability was investigated for six Boise sandstone samples and two Berea sandstone samples. Results for all samples were similar. The irreducible water saturation increased significantly, while the residual oil saturation decreased significantly with temperature increase. The individual relative permeability to oil increased for all water saturations below the room-temperature residual oil saturation, but the relative permeability to water at flood-out increased with permeability to water at flood-out increased with temperature increase. Absolute permeability decreased with temperature increase. Introduction Test environment is generally acknowledged to have a significant effect on measurement of relative permeability. The environment consists not only permeability. The environment consists not only of the temperature and pressure, but also of the fluids used and the core condition. Several workers have used the approach of completely simulating the reservoir conditions in the laboratory experiment. Such methods are termed "restored state." Restored state data are generally different from "room condition" data; since several variables are involved, it is difficult to determine the importance of each variable. Another approach used attributes the changes in relative permeability to changes in the rock-fluid interaction or wettability. Wettability, however, depends on many variables. Specifically, wettability depends on the composition of the rock surface, the composition of the fluids, the saturation history of the rock surface, and the temperature and pressure of the system. The purpose of this study is to isolate temperature as a variable in the relative permeability of a given rock-fluid system. Work on isolation of temperature as a variable in relative permeability has been conducted since the early 1960s. Edmondsons established results in 1965 for a Berea sandstone core using both water/refined oil and water/crude oil as fluid pairs. He showed a change in the relative permeability ratio accompanied by a decrease in the residual oil saturation with temperature increase. Edmondson showed no data for water saturations below 40 percent, and his curves show considerable scatter in the middle saturation ranges. Edmondson's work was the only study to use consolidated cores to investigate the effect of temperature on relative permeability measurements. Poston et al. presented waterflood data for sand packs containing 80-, 99-, a nd 600-cp oil, and packs containing 80-, 99-, a nd 600-cp oil, and observed an increase in the individual relative permeabilities with temperature increase. The permeabilities with temperature increase. The increase in the oil and the water permeability was accompanied by an increase in irreducible water saturation and a decrease in the residual oil saturation with temperature increase. Poston et al. was the only work to present individual oil and water permeability. Davidsons presented results for displacement of No. 15 white oil from a sand pack by distilled water, steam, or nitrogen. However, he found little permeability-ratio dependence in the middle permeability-ratio dependence in the middle saturation ranges. Davidson, too, found a decrease in the residual oil saturation with temperature increase, but he did not include data on irreducible water saturation. SPEJ P. 376


2021 ◽  
Author(s):  
Subodh Gupta

Abstract The objective of this paper is to present a fundamentals-based, consistent with observation, three-phase flow model that avoids the pitfalls of conventional models such as Stone-II or Baker's three-phase permeability models. While investigating the myth of residual oil saturation in SAGD with comparing model generated results against field data, Gupta et al. (2020) highlighted the difficulty in matching observed residual oil saturation in steamed reservoir with Stone-II and Baker's linear models. Though the use of Stone-II model is very popular for three-phase flow across the industry, one issue in the context of gravity drainage is how it appears to counter-intuitively limit the flow of oil when water is present near its irreducible saturation. The current work begins with describing the problem with existing combinatorial methods such as Stone-II, which in turn combine the water-oil, and gas-oil relative permeability curves to yield the oil relative permeability curve in presence of water and gas. Then starting with the fundamentals of laminar flow in capillaries and with successive analogical formulations, it develops expressions that directly yield the relative permeabilities for all three phases. In this it assumes a pore size distribution approximated by functions used earlier in the literature for deriving two-phase relative permeability curves. The outlined approach by-passes the need for having combinatorial functions such as prescribed by Stone or Baker. The model so developed is simple to use, and it avoids the unnatural phenomenon or discrepancy due to a mathematical artefact described in the context of Stone-II above. The model also explains why in the past some researchers have found relative permeability to be a function of temperature. The new model is also amenable to be determined experimentally, instead of being based on an assumed pore-size distribution. In that context it serves as a set of skeletal functions of known dependencies on various saturations, leaving constants to be determined experimentally. The novelty of the work is in development of a three-phase relative permeability model that is based on fundamentals of flow in fine channels and which explains the observed results in the context of flow in porous media better. The significance of the work includes, aside from predicting results more in line with expectations and an explanation of temperature dependent relative permeabilities of oil, a more reliable time dependent residual oleic-phase saturation in the context of gravity-based oil recovery methods.


2021 ◽  
Author(s):  
Hang Su ◽  
Fujian Zhou ◽  
Lida Wang ◽  
Chuan Wang ◽  
Lixia Kang ◽  
...  

Abstract For reservoirs containing oil with a high total acid number, alkali-cosolvent-polymer (ACP) flood can potentially increase the oil recovery by its saponification effects. The enhanced oil recovery performance of ACP flood has been studied at core and reservoir scale in detail, however, the effect of ACP flood on residual oil saturation in the swept area still lacks enough research. Medical computed tomography (Medical-CT) scan and micro computed tomography (Micro-CT) scan are used in combination to visualize micro-scale flow and reveal the mechanisms of residual oil reduction during ACP flood. The heterogeneous cores containing two layers of different permeability are used for coreflood experiment to clarify the enhanced oil recovery (EOR) performance of ACP food in heterogeneous reservoirs. The oil saturation is monitored by Medical-CT. Then, two core samples are drilled in each core after flooding and the decrease of residual oil saturation caused by ACP flood is further quantified by Micro-CT imageing. Results show that ACP flood is 14.5% oil recovery higher than alkaline-cosolvent (AC) flood (68.9%) in high permeability layers, 17.9% higher than AC flood (26.3%) in low permeability layers. Compared with AC flood, ACP flood shows a more uniform displacement front, which implies that the injected polymer effectively weakened the viscosity fingering. Moreover, a method that can calculate the ratio of oil-water distribution in each pore is developed to establish the relationship between the residual oil saturation of each pore and its pore size, and reached the conclusion that they follow the power law correlation.


1982 ◽  
Vol 22 (03) ◽  
pp. 371-381 ◽  
Author(s):  
Jude O. Amaefule ◽  
Lyman L. Handy

Abstract Relative permeabilities of systems containing low- tension additives are needed to develop mechanistic insights as to how injected aqueous chemicals affect fluid distribution and flow behavior. This paper presents results of an experimental investigation of the effect of low interfacial tensions (IFT's) on relative oil/water permeabilities of consolidated porous media. The steady- and unsteady-state displacement methods were used to generate relative permeability curves. Aqueous low-concentration surfactant systems were used to vary IFT levels. Empirical correlations were developed that relate the imbibition relative permeabilities, apparent viscosity, residual oil, and water saturations to the interfacial tension through the capillary number (Nc=v mu / sigma). They require two empirical, experimentally generated coefficients. The experimental results show that the relative oil/water permeabilities at any given saturation are affected substantially by IFT values lower than 10-1 mN/m. Relative oil/water permeabilities increased with decreasing IFT (increasing N ). The residual oil and residual water saturations (S, and S) decreased, while the total relative mobilities increased with decreasing IFT. The correlations predict values of relative oil/water permeability ratios, fractional flow, and residual saturations that agree with our experimental data. Apparent mobility design viscosities decreased exponentially with the capillary number. The results of this study can be used with simulators to predict process performance and efficiency for enhanced oil-recovery projects in which chemicals are considered for use either as waterflood or steamflood additives. However, the combined effect of decreased interfacial tension and increased temperature on relative permeabilities has not yet been studied. Introduction Oil displacement with an aqueous low-concentration surfactant solution is primarily dependent on the effectiveness of the solutions in reducing the IFT between the aqueous phase and the reservoir oil. With the attainment of ultralow IFT's (10 mN/m) and with adequate mobility controls, all the oil contacted can conceivably be displaced. When the interfacial tension is reduced to near zero values, the process tends to approach miscible displacement. However, most high-concentration soluble oil systems revert to immiscible displacement processes as the injected chemical traverses the reservoir. This is a result of the continual depletion of the surfactant by adsorption on the rock and by precipitation with divalent cations in the reservoir brine. The mechanism by which residual oil is mobilized by low-tension displacing fluids cannot be explained solely by the application of Darcy's law to both the aqueous and the oleic phases. On the other hand, in those reservoir regions in which water and oil are flowing concurrently as continuous phases, Darcy's law would be expected to apply and the relative permeability concept would be valid. If a low-tension aqueous phase were to invade a region in which the oil had not as yet been reduced to a discontinuous irreducible saturation, one would expect, also, that the relative permeability concept would be applicable. Under circumstances for which these conditions apply, relative permeabilities at low interfacial tensions would be required, The effect of IFT's on relative permeability curves has received limited treatment in the petroleum literature. Leverett reported a small but definite tendency for a water/oil system in unconsolidated rocks to exhibit 20 to 30% higher relative permeabilities if the IFT was decreased from 24 to 5 mN/m. Mungan studied interfacial effects on oil displacement in Teflons cores. The interfacial tension values varied from 5 to 40 mN/m. SPEJ P. 371^


1984 ◽  
Vol 24 (02) ◽  
pp. 224-232 ◽  
Author(s):  
F.J. Fayers ◽  
J.D. Matthews

Abstract This paper examines normalized forms of Stone's two methods for predicting three-phase relative permeabilities. Recommendations are made on selection of the residual oil parameter, S om, in Method I. The methods are tested against selected published three-phase experimental data, using the plotting program called CPS-1 to infer improved data fitting. It is concluded that the normalized Method I with the recommended form for S om, is superior to Method II. Introduction Stone has produced two methods for estimating three-phase relative permeability from two-phase data. Both models assume a dominant wetting phase (usually water), a dominant nonwetting phase (gas), and an intermediate wetting phase (usually oil). The relative permeabilities for the water and gas are assumed to permeabilities for the water and gas are assumed to depend entirely on their individual saturations because they occupy the smallest and largest pores, respectively. The oil occupies the intermediate-size pores so that the oil relative permeability is an unknown function of water and gas saturation. For his first method, Stone proposed a formula for oil relative, permeability that was a product of oil relative permeability in the absence of gas, oil relative permeability in the absence of gas, oil relative permeability in the absence of mobile water, and some permeability in the absence of mobile water, and some variable scaling factors. He compared this formula with the experimental results of Corey et al., Dalton et al., and Saraf and Fatt. The formula is likely to be most in error at low oil relative permeability where more data are needed that show the behavior of residual oil saturation as a function of mixed gas and water saturations. In particular, the best value for the parameter S om that occurs in the model is not well resolved. In his second method, Stone developed a new formula and compared it against the data of Corey et al., Dalton et al., Saraf And Fatt, and some residual oil data from Holmgren and Morse. Stone suggested that his second method gave reasonable agreement with experiments without the need to include the parameter S om. If in the absence of residual oil data, S om = 0 is used in the first method, the second method is then better than the first method, although it tends to under predict relative permeability. Dietrich and Bondor later showed that Stone's second method did not adequately approximate the two-phase data unless the oil relative permeability at connate water saturation, k rocw, was close to unity. Dietrich and Bondor suggested a normalization that achieved consistency with the two-phase data when k rocw, was not unity. This normalization can be unsatisfactory because k roc an exceed unity in some saturation ranges if k rocw is small. More recently this objection has been overcome by the normalization of Method II introduced by Aziz and Settari. Aziz and Settari also pointed out a similar normalization problem with Stone's first method and suggested an alternative to overcome the deficiency. However, no attempt was made to investigate the accuracy of these normalized formulas with respect to experimental data. In the next section of the paper we review the principal forms of Stone's formulas, and introduce some new ideas on the use and choice of the parameter S om. Later we examine the first of Stone's assumptions that water and gas relative permeabilities are functions only of their respective saturations for a water-wet system. This involves a critical review of all the published experimental measurements. Earlier reviews did not take into account some of the available data. Last, we examine the predictions of normalized Stone's methods for oil relative permeability against the more reliable experimental results. It is concluded that the normalized Stone's Method I with the improved definition of S om is more accurate than the normalized Method II. Mathematical Definition of Three-Phase Relative Permeabilities We briefly review the principal forms of the Stone's formulas that use the two-phase relative permeabilities defined by water/oil displacement in the absence of gas, k rw = k rw (S w) and k row = k row (S w) and gas/oil displacement in the presence of connate water, k rg = k rg (S g) and k rog = k rog (S g). SPEJ p. 224


1980 ◽  
Vol 20 (05) ◽  
pp. 391-401 ◽  
Author(s):  
D.G. Longeron

Abstract Laboratory studies have been conducted to determine the influence of the composition of gas and oil phases on the parameters involved in the description of two-phase flow in porous media when the compositions of the phases vary over a wide range. Relative permeabilities to gas and oil were determined under high pressure and temperature for binary systems (methane/n-heptane, methane/n-decane, etc.), leading to very wide variations of the interfacial tensions values. Investigations were focused specifically on mixtures involving low interfacial tensions, down to 0.001 mN/m. This study has shown that residual oil saturations and relative permeabilities determined from the displacement tests with a filtration velocity of about 20 cm/hr are affected strongly by interfacial tension, especially when it is lower than 10-2 mN/m. Introduction This study deals with the influence of the compositions of the liquid and vapor phases in equilibrium on displacements of oil by gas in porous media. One of the goals of high-pressure or enriched-gas injection is to obtain low interfacial tensions between the in-place oil and injected gas. During the displacement of gas in oil-bearing formations, multiple exchanges may take place between the liquid and vapor phases so that complete miscibility may be achieved. This phenomenon generally is called thermodynamic miscibility. During this process the interfacial tension is reduced progressively to zero. The resulting reduction in capillary forces makes it possible to decrease the residual oil saturation considerably. The same goal also is sought by other enhanced recovery techniques not examined here i.e., surfactant flooding or microemulsion flooding. The purpose of this study is to examine the influence of the thermodynamic conditions on the relative permeabilities in displacements of a liquid phase by a vapor phase when both phases are at equilibrium. The Problem The general equations describing the flows of two phases are the relative permeability equations. They show, for each phase, that the flow rate in a porous medium is a function of the absolute permeability, relative permeability to the fluid involved, fluid viscosity, pressure gradient in this phase, and gravity. In fact, relative permeabilities depend on a greater number of parameters.1 Some of them are the ratio of viscosities, µ2/µ1; the ratio of gravity to capillary forces (Bond number), (?2-?1)gk]/s; the ratio of the inertia forces to the viscosity forces (Reynolds number), (?1·u·k)/µ1; the ratio of the viscosity forces to the capillary forces (capillary number), (µ1·u)/s; and wettability. When they exist, exchanges between the phases can modify the physical and chemical properties of the fluids, especially at the interfaces. Under such conditions the influence of the capillary number (µ1·u)/s is by no means negligible, with the decrease in interfacial tension causing an increase in oil recovery.2 It may be thought that relative permeability to oil is closely dependent on this capillary number,3 especially when the value of s is small, and that this influence is principally apparent with low oil-saturation levels.


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