Impact of Reservoir Mixing on Recovery in Enriched-Gas Drives Above the Minimum Miscibility Enrichment

2001 ◽  
Vol 4 (05) ◽  
pp. 358-365 ◽  
Author(s):  
R. Solano ◽  
R.T. Johns ◽  
L.W. Lake

Summary Gas enrichment is an important variable used to optimize oil recovery in enriched-gas drives. For slimtube experiments, oil recoveries do not increase significantly with enrichments greater than the minimum miscibility enrichment (MME). For field projects, however, the optimum enrichment required to maximize recovery on a pattern scale may be different from the MME. The optimum enrichment is likely the result of greater mixing in reservoirs than in slimtubes. In addition, 2D effects, such as channeling, gravity tonguing, and crossflow, can impact the enrichment selected. Numerical simulation is often used to model the effect of physical mixing on oil recovery in miscible gasfloods. Unfortunately, numerical dispersion can cloud the interpretation of the results by artificially increasing the level of mixing in the reservoir. This paper investigates the interplay among various mixing mechanisms, enrichment levels, and numerical dispersion. The mixing mechanisms examined are mechanical dispersion, gravity crossflow, and viscous crossflow. The U. of Texas Compositional Simulator (UTCOMP) is used to evaluate the effect of these mechanisms on recovery for different grid refinements, reservoir heterogeneities, injection boundary conditions, relative permeabilities, and numerical weighting methods, including higher-order methods. The reservoir fluid used for all simulations is a 12-component oil displaced by gases enriched above the MME. The results show that for 1D enriched gasfloods, the recovery difference between displacements above the MME and those at or near the MME increases significantly with dispersion. The trend, however, is not monotonic and shows a maximum at a dispersivity of approximately 4 ft. The trend is independent of relative permeabilities and gas trapping for dispersivities of less than approximately 4 ft. For 2D enriched gasfloods with slug injection, the difference in recovery generally increases as dispersion and crossflow increase. The magnitude of the recovery differences is less than that observed for the 1D displacements. Recovery differences for 2D models are highly dependent on relative permeabilities and gas trapping. For water alternating gas (WAG) injection, the differences in recovery increase slightly as dispersion decreases. That is, the recovery difference is significantly greater with WAG at low levels of dispersion than with slug injection. For the cases examined, the magnitude of recovery difference varies from approximately 1 to 8% of the original oil in place (OOIP). Introduction Gas enrichment is an important optimization variable in enriched-gas drives. Recoveries from slimtube experiments often give a sharp bend at the MME. Above the MME, slimtube recoveries do not increase significantly with enrichment. The optimum enrichment required to maximize recovery on a pattern scale in the field, however, is likely different from the MME. The difference in the optimum enrichment may largely be the result of greater mixing in the reservoir than exists in slimtubes. In addition, enrichment may impact sweep efficiency in 2D displacements. Oil and gas mixing in a reservoir can include mechanisms such as molecular diffusion, mechanical dispersion, gravity crossflow, viscous crossflow, and capillary crossflow. There are several reasons why recovery could increase for enrichments beyond the MME. First, the density and viscosity of the gas will increase with enrichment, which may improve sweep efficiency. Second, mixing can cause an otherwise multicontact miscible (MCM) flood to develop some two-phase flow.1–4 Richer gases mix closer to the critical locus in the two-phase zone, which causes a smaller and slower lean-gas bank. A smaller lean-gas bank could improve sweep efficiency. Last, richer gases, which mix near the critical locus, decrease miscible residual oil by increasing the velocity of the trailing evaporation fronts. Several authors have examined the effect of mixing and enrichment above the MME on oil recovery. Johns et al.5,6 recently considered the effect of dispersion on recovery in 1D displacements. They showed that the "knee" in the recovery curve from slimtube experiments depends on the level of dispersion. For small dispersivities typical of slimtubes, the knee occurs at the MME. For greater levels of mixing, they showed that the knee in recovery could occur at enrichments much greater than the MME. Chang et al.7 matched coreflood displacements with reservoir simulations at different enrichments and showed that recovery increased sharply for enrichments above the MME. Chang concluded that the increased recoveries were caused by higher displacement and sweep efficiencies as the enrichment level increased. The better sweep efficiency was attributed to increased gas density with enrichment. Jerauld8 also observed an increase in recovery above the MME. Giraud et al.9 observed that the highest recovery occurred at pressures above the minimum miscibility pressure (MMP). Stalkup10 showed that significant additional recovery might be obtained by injecting enriched gases above the MME. A significant increase in recovery occurred for longitudinal dispersivities of as low as 0.3 ft when the solvent and water were injected in slugs. He also concluded that mixing solvent and oil by viscous crossflow during WAG might dominate other mixing mechanisms in the reservoir (i.e., dispersion). Thus, he suggested that predictions of oil recovery from coarse gridblocks might be accurate as long as the vertical gridding is sufficient to capture the effect of viscous crossflow during WAG. Stalkup also showed that simultaneous grid refinement in horizontal and vertical directions caused numerical dispersion to overestimate the recovery with gas enrichment beyond the MME.11–13 Other papers have also examined the effect of viscous crossflow, capillary pressure, diffusion, gravity, heterogeneities, and numerical gridding on recovery.14–16 Pande17 obtained contradictory results from Stalkup. For the 2D cases considered, she showed that the optimal enrichment might be below the MME, not above it. Pande, however, did not examine the effect of gridding or gas trapping on the results. She also used a fluid characterization that exhibited a small sensitivity of displacement efficiency to dispersion, making her results sensitive only to sweep efficiency. Nevertheless, her results indicate that the optimal enrichment is highly problem-dependent.

SPE Journal ◽  
2007 ◽  
Vol 12 (02) ◽  
pp. 224-234 ◽  
Author(s):  
Leonardo Bermudez ◽  
Russell Taylor Johns ◽  
Harshad Champaklal Parakh

Summary Water-alternating-gas floods (WAG) are commonly used to improve sweep efficiency in heterogeneous reservoirs. There has been little reported in the literature, however, on the effectiveness of WAG processes where the gas is enriched above the minimum miscibility enrichment composition (MME). This paper examines how to optimize WAG processes for enriched gasfloods above the MME, particularly as a primary recovery method. Compositional simulations of x-z cross-sections are used to quantify the effects of WAG parameters, numerical dispersion, level of enrichment, and heterogeneity on local displacement efficiency and sweep efficiency. The main conclusions of this research show that the richer the gas above the MME, the fewer the number of WAG cycles required for maximum oil recovery at a given WAG ratio. Another significant observation is that overenrichment above the MME improves recovery the most when the largest permeability layers are at the bottom of the reservoir. Continuous slug injection performs better than WAG when the largest permeability layers are at the bottom of the aquifer, richer gases are used, and the vertical to horizontal permeability ratio is small. Introduction Gas enrichment is one of the important optimization variables in WAG enriched-gas floods. Recoveries from slimtube experiments with continuous gas injection often give a sharp bend at the minimum enrichment for miscibility (MME). Above the MME, slimtube recoveries do not increase significantly with enrichment. The optimum enrichment required to maximize recovery on a pattern scale in the field, however, is likely different from the MME. The difference in the optimum enrichment may be largely the result of greater mixing in the reservoir than exists in slimtubes. In addition, enrichment may impact sweep efficiency in 2D displacements. Oil and gas mixing in a reservoir can include mechanisms such as molecular diffusion, mechanical dispersion, gravity crossflow, viscous crossflow, and capillary crossflow. WAG in particular causes significant mixing of reservoir and injected fluids, depending on the total volume of the gas injected (slug volume), the WAG ratio, and the number of gas cycles or WAG frequency. There are several reasons why recovery could increase for gas enrichments above the MME. First, the density and viscosity of the gas will increase with enrichment, which may improve sweep efficiency. Second, mixing can cause an otherwise multicontact miscible flood (MCM) to develop some two-phase flow (Johns et al. 1993; Walsh and Orr 1990; Pande and Orr 1989; Lake 1989). Richer gases mix closer to the critical locus in the two-phase zone, which causes a smaller and slower lean gas bank. A smaller lean gas bank could improve sweep efficiency. Last, richer gases, which mix near the critical locus, decrease "miscible residual oil" by increasing the velocity of the trailing evaporation fronts.


Energies ◽  
2020 ◽  
Vol 13 (24) ◽  
pp. 6520
Author(s):  
Pablo Druetta ◽  
Francesco Picchioni

The traditional Enhanced Oil Recovery (EOR) processes allow improving the performance of mature oilfields after waterflooding projects. Chemical EOR processes modify different physical properties of the fluids and/or the rock in order to mobilize the oil that remains trapped. Furthermore, combined processes have been proposed to improve the performance, using the properties and synergy of the chemical agents. This paper presents a novel simulator developed for a combined surfactant/polymer flooding in EOR processes. It studies the flow of a two-phase, five-component system (aqueous and organic phases with water, petroleum, surfactant, polymer and salt) in porous media. Polymer and surfactant together affect each other’s interfacial and rheological properties as well as the adsorption rates. This is known in the industry as Surfactant-Polymer Interaction (SPI). The simulations showed that optimum results occur when both chemical agents are injected overlapped, with the polymer in the first place. This procedure decreases the surfactant’s adsorption rates, rendering higher recovery factors. The presence of the salt as fifth component slightly modifies the adsorption rates of both polymer and surfactant, but its influence on the phase behavior allows increasing the surfactant’s sweep efficiency.


SPE Journal ◽  
2010 ◽  
Vol 16 (01) ◽  
pp. 24-34 ◽  
Author(s):  
R.A.. A. Kil ◽  
Q.P.. P. Nguyen ◽  
W.R.. R. Rossen

Summary Gas trapping by foam is a key mechanism of foam mobility and foam effectiveness in applications such as acid diversion in well stimulation, enhanced oil recovery (EOR), and aquifer remediation. Previous studies have attempted to quantify the extent of gas trapping by injecting a tracer gas within the foam and then fitting the effluent profile to a 1D capacitance model. In this model, at any given axial position along the core, all flowing gas and all trapped gas are each characterized by a single tracer concentration. Computed-tomography (CT) images of experiments using xenon (Xe) tracer show that this characterization is not accurate: Trapped gas near flowing gas comes rapidly to equilibrium with flowing gas long before tracer diffuses into trapped gas farther away. We introduce a method that uses the CT images directly to estimate flowing-gas fraction. In the CT images, tracer advances in many small channels and diffuses outward into surrounding regions of trapped gas a few millimeters in diameter. The difference between the higher tracer concentration at the center of these channels and the lower concentration at the edge can be related to the diffusion coefficient of the tracer and the flowing-gas fraction within the channel. For the CT images of Xe tracer in one experiment, this method gives flowing-gas fractions one or two orders of magnitude smaller than what is estimated using the 1D capacitance model. The model can be used to estimate flowing-gas fraction in different regions of a core in spite of different average gas velocities in the different regions.


2016 ◽  
Vol 19 (04) ◽  
pp. 673-682 ◽  
Author(s):  
Amir Jahanbakhsh ◽  
Hamidreza Shahverdi ◽  
Mehran Sohrabi

Summary Relative permeabilities (kr) are crucial flow functions governing the fluid distribution within and production from petroleum reservoirs under various oil-recovery methods. To obtain these important reservoir parameters, conventionally, it is required to take rock samples from the reservoir and perform appropriate laboratory measurements. Although kr is expressed as a function of fluid saturation, it is now well-known that kr values are affected by pore structure and distribution, absolute permeability, wettability, interfacial tension (IFT), and saturation history. These rock/fluid properties often change from one region of the reservoir to another, but it would be impossible to perform kr measurements for all regions of a reservoir. Generally, performing experiments on a core with higher permeability is faster and easier than a low-permeability rock. Therefore, assuming all other parameters such as wettability, IFT, and displacement direction are the same for two rocks with different permeabilities, the question becomes how do we estimate the kr of a rock with lower permeability from available (measured) kr of a higher-permeability rock? How do we account for wettability and IFT differences? A normalization technique has been proposed to remove the effect of irreducible water and trapped saturations, which would be different under different conditions. The relative permeabilities can then be denormalized and assigned to different regions (rock types) of the reservoir on the basis of their own irreducible water and trapped saturations. The objective of this study is to introduce a methodology to predict the gas/oil kr for new rock/fluid conditions (such as permeability, wettability, and IFT) by use of existing gas/oil kr data measured at different conditions. By use of measured data from coreflood experiments, we show that by applying an appropriate normalization technique one can adequately predict kr of rocks with different permeability and wettability conditions in two-phase gas/oil flow. However, the results show that the effect of IFT change cannot be captured by normalization techniques. To improve the methodology, a new hypothesis is introduced and proposed here on the basis of dynamic trap saturation. Finally, by use of our experimental data, we evaluate the validity of the Coats (1980) IFT scaling method. We demonstrate the shortcomings of the method and offer an improvement to its prediction.


SPE Journal ◽  
2018 ◽  
Vol 24 (01) ◽  
pp. 129-139 ◽  
Author(s):  
J. L. Juárez-Morejón ◽  
H.. Bertin ◽  
A.. Omari ◽  
G.. Hamon ◽  
C.. Cottin ◽  
...  

Summary An experimental study of polymer flooding is presented here, focusing on the influence of initial core wettability and flood maturity (volume of water injected before polymer injection) on final oil recovery. Experiments were performed using homogeneous Bentheimer Sandstone samples of similar properties. The cores were oilflooded using mineral oil for water-wet conditions and crude oil (after an aging period) for intermediate-wet conditions; the viscosity ratio between oil and polymer was kept constant in all experiments. Polymer, which is a partially hydrolyzed polyacrylamide (HPAM), was used at a concentration of 2,500 ppm in a moderate-salinity brine. The polymer solution was injected in the core at different waterflood-maturity times [breakthrough (BT) and 0, 1, 1.75, 2.5, 4, and 6.5 pore volumes (PV)]. Coreflood results show that the maturity of polymer injection plays an important role in final oil recovery, regardless of wettability. The waterflood-maturity time 0 PV (polymer injection without initial waterflooding) leads to the best sweep efficiency, whereas final oil production decreases when the polymer-flood maturity is high (late polymer injection after waterflooding). A difference of 15% in recovery is observed between early polymer flooding (0 PV) and late maturity (6.5 PV). Concerning the effect of wettability, the recovery factor obtained with water-wet cores is always lower (from 10 to 20%, depending on maturity) than the values obtained with intermediate-wet cores, raising the importance of correctly restoring core wettability to obtain representative values of polymer incremental recovery. The influence of wettability can be explained by the oil-phase distribution at the pore scale. Considering that the waterflooding period leads to different values of the oil saturation at which polymer flooding starts, we measured the core dispersivity using a tracer method at different states. The two-phase dispersivity decreases when water saturation increases, which is favorable for polymer sweep. This study shows that in addition to wettability, the maturity of polymer flooding plays a dominant role in oil-displacement efficiency. Final recovery is correlated to the dispersion value at which polymer flooding starts. The highest oil recovery is obtained when the polymer is injected early.


Nanomaterials ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 1818 ◽  
Author(s):  
Afshin Davarpanah

Among a wide range of enhanced oil-recovery techniques, polymer flooding has been selected by petroleum industries due to the simplicity and lower cost of operational performances. The reason for this selection is due to the mobility-reduction of the water phase, facilitating the forward-movement of oil. The objective of this comprehensive study is to develop a mathematical model for simultaneous injection of polymer-assisted nanoparticles migration to calculate an oil-recovery factor. Then, a sensitivity analysis is provided to consider the significant influence of formation rheological characteristics as type curves. To achieve this, we concentrated on the driving mathematical equations for the recovery factor and compare each parameter significantly to nurture the differences explicitly. Consequently, due to the results of this extensive study, it is evident that a higher value of mobility ratio, higher polymer concentration and higher formation-damage coefficient leads to a higher recovery factor. The reason for this is that the external filter cake is being made in this period and the subsequent injection of polymer solution administered a higher sweep efficiency and higher recovery factor.


2021 ◽  
Vol 11 (9) ◽  
pp. 4251
Author(s):  
Jinsong Zhang ◽  
Shuai Zhang ◽  
Jianhua Zhang ◽  
Zhiliang Wang

In the digital microfluidic experiments, the droplet characteristics and flow patterns are generally identified and predicted by the empirical methods, which are difficult to process a large amount of data mining. In addition, due to the existence of inevitable human invention, the inconsistent judgment standards make the comparison between different experiments cumbersome and almost impossible. In this paper, we tried to use machine learning to build algorithms that could automatically identify, judge, and predict flow patterns and droplet characteristics, so that the empirical judgment was transferred to be an intelligent process. The difference on the usual machine learning algorithms, a generalized variable system was introduced to describe the different geometry configurations of the digital microfluidics. Specifically, Buckingham’s theorem had been adopted to obtain multiple groups of dimensionless numbers as the input variables of machine learning algorithms. Through the verification of the algorithms, the SVM and BPNN algorithms had classified and predicted the different flow patterns and droplet characteristics (the length and frequency) successfully. By comparing with the primitive parameters system, the dimensionless numbers system was superior in the predictive capability. The traditional dimensionless numbers selected for the machine learning algorithms should have physical meanings strongly rather than mathematical meanings. The machine learning algorithms applying the dimensionless numbers had declined the dimensionality of the system and the amount of computation and not lose the information of primitive parameters.


e-Polymers ◽  
2020 ◽  
Vol 20 (1) ◽  
pp. 61-68
Author(s):  
Dong Zhang ◽  
Jian Guang Wei ◽  
Run Nan Zhou

AbstractActive-polymer attracted increasing interest as an enhancing oil recovery technology in oilfield development owing to the characteristics of polymer and surfactant. Different types of active functional groups, which grafted on the polymer branched chain, have different effects on the oil displacement performance of the active-polymers. In this article, the determination of molecular size and viscosity of active-polymers were characterized by Scatterer and Rheometer to detect the expanded swept volume ability. And the Leica microscope was used to evaluate the emulsifying property of the active-polymers, which confirmed the oil sweep efficiency. Results show that the Type I active-polymer have a greater molecular size and stronger viscosity, which is a profile control system for expanding the swept volume. The emulsification performance of Type III active-polymer is more stable, which is suitable for improving the oil cleaning efficiency. The results obtained in this paper reveal the application prospect of the active-polymer to enhance oil recovery in the development of oilfields.


2021 ◽  
pp. 014459872098020
Author(s):  
Ruizhi Hu ◽  
Shanfa Tang ◽  
Musa Mpelwa ◽  
Zhaowen Jiang ◽  
Shuyun Feng

Although new energy has been widely used in our lives, oil is still one of the main energy sources in the world. After the application of traditional oil recovery methods, there are still a large number of oil layers that have not been exploited, and there is still a need to further increase oil recovery to meet the urgent need for oil in the world economic development. Chemically enhanced oil recovery (CEOR) is considered to be a kind of effective enhanced oil recovery technology, which has achieved good results in the field, but these technologies cannot simultaneously effectively improve oil sweep efficiency, oil washing efficiency, good injectability, and reservoir environment adaptability. Viscoelastic surfactants (VES) have unique micelle structure and aggregation behavior, high efficiency in reducing the interfacial tension of oil and water, and the most important and unique viscoelasticity, etc., which has attracted the attention of academics and field experts and introduced into the technical research of enhanced oil recovery. In this paper, the mechanism and research status of viscoelastic surfactant flooding are discussed in detail and focused, and the results of viscoelastic surfactant flooding experiments under different conditions are summarized. Finally, the problems to be solved by viscoelastic surfactant flooding are introduced, and the countermeasures to solve the problems are put forward. This overview presents extensive information about viscoelastic surfactant flooding used for EOR, and is intended to help researchers and professionals in this field understand the current situation.


1985 ◽  
Vol 25 (06) ◽  
pp. 945-953 ◽  
Author(s):  
Mark A. Miller ◽  
H.J. Ramey

Abstract Over the past 20 years, a number of studies have reported temperature effects on two-phase relative permeabilities in porous media. Some of the reported results, however, have been contradictory. Also, observed effects have not been explained in terms of fundamental properties known to govern two-phase flow. The purpose of this study was to attempt to isolate the fundamental properties affecting two-phase relative permeabilities at elevated temperatures. Laboratory dynamic-displacement relative permeability measurements were made on unconsolidated and consolidated sand cores with water and a refined white mineral oil. Experiments were run on 2-in. [5.1-cm] -diameter, 20-in. [52.-cm] -long cores from room temperature to 300F [149C]. Unlike previous researchers, we observed essentially no changes with temperature in either residual saturations or relative permeability relationships. We concluded that previous results may have been affected by viscous previous results may have been affected by viscous instabilities, capillary end effects, and/or difficulties in maintaining material balances. Introduction Interest in measuring relative permeabilities at elevated temperatures began in the 1960's with petroleum industry interest in thermal oil recovery. Early thermal oil recovery field operations (well heaters, steam injection, in-situ combustion) indicated oil flow rate increases far in excess of what was predicted by viscosity reductions resulting from heating. This suggested that temperature affects relative permeabilities. One of the early studies of temperature effects on relative permeabilities was presented by Edmondson, who performed dynamic displacement measurements with crude performed dynamic displacement measurements with crude and white oils and distilled water in Berea sandstone cores. Edmondson reported that residual oil saturations (ROS's) (at the end of 10 PV's of water injected) decreased with increasing temperature. Relative permeability ratios decreased with temperature at high water saturations but increased with temperature at low water saturations. A series of elevated-temperature, dynamic-displacement relative permeability measurements on clean quartz and "natural" unconsolidated sands were reported by Poston et al. Like Edmondson, Poston et al. reported a decrease in the "practical" ROS (at less than 1 % oil cut) as temperature increased. Poston et al. also reported an increase in irreducible water saturation. Although irreducible water saturations decreased with decreasing temperature, they did not revert to the original room temperature values. It was assumed that the cores became increasingly water-wet with an increase in both temperature and time; measured changes of the IFT and the contact angle with temperature increase, however, were not sufficient to explain observed effects. Davidson measured dynamic-displacement relative permeability ratios on a coarse sand and gravel core with permeability ratios on a coarse sand and gravel core with white oil displaced by distilled water, nitrogen, and superheated steam at temperatures up to 540F [282C]. Starting from irreducible water saturation, relative permeability ratio curves were similar to Edmondson's. permeability ratio curves were similar to Edmondson's. Starting from 100% oil saturation, however, the curves changed significantly only at low water saturations. A troublesome aspect of Davidson's work was that he used a hydrocarbon solvent to clean the core between experiments. No mention was made of any consideration of wettability changes, which could explain large increases in irreducible water saturations observed in some runs. Sinnokrot et al. followed Poston et al.'s suggestion of increasing water-wetness and performed water/oil capillary pressure measurements on consolidated sandstone and limestone cores from room temperature up to 325F [163C]. Sinnokrot et al confirmed that, for sandstones, irreducible water saturation appeared to increase with temperature. Capillary pressures increased with temperature, and the hysteresis between drainage and imbibition curves reduced to essentially zero at 300F [149C]. With limestone cores, however, irreducible water saturations remained constant with increase in temperature, as did capillary pressure curves. Weinbrandt et al. performed dynamic displacement experiments on small (0.24 to 0.49 cu in. [4 to 8 cm3] PV) consolidated Boise sandstone cores to 175F [75C] PV) consolidated Boise sandstone cores to 175F [75C] with distilled water and white oil. Oil relative permeabilities shifted toward high water saturations with permeabilities shifted toward high water saturations with increasing temperature, while water relative permeabilities exhibited little change. Weinbrandt et al. confirmed the findings of previous studies that irreducible water saturation increases and ROS decreases with increasing temperature. SPEJ P. 945


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