The Differentiation Method in Rheology: IV. Characteristic Derivatives of Ideal Models in Couette Flow
Abstract The dual differentiation-integration method of rheological analysis is applied to Couette flow. Using machine processing techniques, a spectrum of characteristic derivative functions for a variety of ideal Generalized Newtonian and viscoplastic models has been developed: As for the case of Poiseuille flow the functions for Generalized Newtonian models as a class are strikingly different from the corresponding functions for the class of viscoplastic models. It is shown that this dual scheme of analysis is a highly sensitive analytic method for determining the applicable range of a rheological model. The unique characteristics of this function in the case of viscoplastics may lead to a more precise detection and evaluation of the yield point or yield stress in these materials. Introduction It has been shown that the dual differentiation- integration method of analysis is a discriminating and flexible method for interpreting flow behavior and determining the applicable range of a particular model from Poiseuille flow experiments. In the preceding paper the basic equations governing the Couette flow experiment were reviewed and the significance of changes in boundary conditions on data analysis in the case of the viscoplastic discussed. In this paper the dual method of analysis is applied to Couette flow using the suites of rheological models considered previously. THEORETICAL CONSIDERATIONS NEWTONIAN LIQUID f (p) = p......................(1) Substituting Eq. 1 in Eq. 4 of Ref. 3 and integrating yields Dv = p1........................(2) where Dv is the nominal shear rate at R1, viz:R2, and B is the radii ratio. Here R1 ............(3) ...................(4) ....................(5) GENERALIZED NEWTONIAN SYSTEMS Odd Power ..........(6) Integration after substitution of Eq. 6 in Eq. 4 of Ref. 3 yields ......(7) and hence, ...(8) ........(9) = .............(10) Series (General) ............(11) SPEJ P. 177^