The Effect of Water Injection on Sustained Combustion in a Porous Medium

1970 ◽  
Vol 10 (02) ◽  
pp. 145-163 ◽  
Author(s):  
H.L. Beckers ◽  
G.J. Harmsen

Abstract This paper gives a theoretical description of the various semisteady states that may develop if in an in-situ combustion process water is injected together with the air. The investigation bas been restricted to cases of one-dimensional flow without heat losses, such as would occur in a narrow, perfectly insulated tube. perfectly insulated tube. Different types of behavior can be distinguished for specific ranges of the water/air injection ratio. At low values of this ratio the injected water evaporates before it reaches the combustion zone, while at high values it passes through the combustion zone without being completely evaporated, but without extinguishing combustion. At intermediate values and at sufficiently high fuel in which all water entering the combustion zone evaporates before leaving it. Formulas are presented that give the combustion zone velocity as a function of water/air injection ratio for each of the possible situations. Introduction In-situ combustion of part of the oil in an oil-bearing formation has become an established thermal-recovery technique, even though its economic prospects are limited by inherent technical drawbacks. The process has been extensively investigated both in the laboratory and in the field, while theoretical studies have also been made. The latter studies showed how performance was affected by various physical and chemical phenomena, such as conduction and convection of phenomena, such as conduction and convection of heat, reaction rate and phase changes. The degree of simplification determined whether these studies were of an analytical or a numerical nature. Recently an improvement of the process has been proposed. This modification involves the proposed. This modification involves the injection of water together with the air. The water serves to recuperate the heat stored in the burned-out sand, which would otherwise be wasted. This heat is now used to evaporate water. The steam thus formed condenses downstream of the combustion zone, where it displaces oil. At sufficiently high water-injection rates unevaporated water is bound to enter the combustion zone because more heat is required for complete evaporation than is available in the hot sand. Experiments showed that even under these conditions combustion is maintained. The improvement consists in a lower oxygen consumption per barrel of oil displaced and lower combustion-zone temperatures. This paper gives a theoretical description of this so-called wet-combustion process as described by Dietz and Weijdema. The prime object is to answer the basic question whether at any water/air injection ratio this process can be steady so that combustion does not die out. This objective justifies a number of assumptions that do not entirely correspond to physical reality, but that owe necessary for a physical reality, but that owe necessary for a tractable analytical treatment. This treatment is limited to the following idealized conditions.The process occurs in a perfectly insulated cylinder of unit cross-sectional area and infinite length.The Hudds are homogeneously distributed over the cross-section of the cylinder.Exchange of heat between the fluid phases and between fluids and matrix is instantaneous, so that in any cross-section the fluid phases are in equilibrium and the temperatures of fluids and porous matrix are the same. porous matrix are the same.Pressure chops over distances of interest are small compared with the pressure itself. (Pressure is taken to be constant.)Injection rates are constant, and a steady state has already been obtained. The second assumption implies that no segregation of liquid and gas occurs. Experimentally this might be achieved by using small-diameter tubes, where segregation is largely compensated by capillarity. SPEJ P. 145

1974 ◽  
Vol 14 (06) ◽  
pp. 537-544 ◽  
Author(s):  
A.M. Garon ◽  
R.J. Wygal

Abstract The results of a systematic investigation of the parameters of fire-water flooding are reported. The parameters of fire-water flooding are reported. The results were obtained from a series of 131 combustion-tube tests. Experimental equipment and procedures were developed to minimize heat-transfer procedures were developed to minimize heat-transfer problems and transient effects at the inlet of the problems and transient effects at the inlet of the tube. The tests were performed with water/air injection ratios from 0 to 13 cu ft/Mscf, using crudes with gravities from 10 degrees to 48 degrees API, in waterflooded and nonwaterflooded sands at pressures of 0, 1,000, and 2,000 psig. The air requirements for fire-water flooding were reduced by more than 50 percent in some cases. Similar results were obtained with various crudes. Introduction The greater demand for crude oil, the increased difficulty of discovering new reservoirs, and the desire to reduce dependence on imports have emphasized the need for enhanced recovery methods capable of economically producing the crude remaining in known reservoirs. Numerous methods have been proposed and tested in laboratories and field pilots, and some have been used in commercial applications. Fire flooding is one enhanced recovery method that has been technically successful in many field applications. Some of these projects have been economically successful, but many are only marginally so. The high cost of air compression for fire flooding is one of the major factors that influence the economics. Large quantities of air are required per unit reservoir volume swept, especially for heavy crude, because all the residual material remaining in the sand immediately ahead of the combustion zone must be consumed. Only a portion of the heat generated is necessary for maintaining the movement of the combustion zone, and the remainder is left behind in the depleted sand. Fire-water flooding is a recovery technique that was conceived to improve the economics of dry fire flooding. In this process, water is injected along with the air to recover some of the heat remaining behind the combustion zone. At low water injection rates, the heat is transported through the combustion zone by superheated steam to where it can be utilized for preheating the reservoir. At higher water injection rates, the water partially quenches the combustion, reducing the maximum temperature to the steam-plateau level, and heat is transferred through the combustion zone as saturated steam. The air requirement is lower with water injection because the amount of hydrocarbonaceous material deposited on the sand grains is less and because all of this fuel is not necessarily consumed. At a constant air injection rate, the oil may be produced faster with water injection than without because of the more rapid combustion-zone movement, the increased utilization of energy, and the increased volume of fluid injected. Fire-water flooding has been investigated in several different laboratories with combustion-tube experiments. The feasibility of partially quenched combustion, the reduced air requirements, and the improved utilization of heat with water injection have been confirmed. However, the results of only a few experiments have been reported by each investigator, and only a limited amount of experimental information is available on the relationships of the fire-waterflooding parameters. in addition, it has been suggested that be results of wet combustion tests may be misleading because of experimental limitations. In this paper, the results of a systematic investigation of the parameters of fire-water flooding are reported. The results were obtained from combustion-tube tests. The equipment was designed to minimize heat-transfer problems, and operating procedures were developed that reduced the procedures were developed that reduced the transient effects at the inlet of the tube. SPEJ P. 537


1979 ◽  
Vol 19 (01) ◽  
pp. 37-58 ◽  
Author(s):  
R.B. Crookston ◽  
W.E. Culham ◽  
W.H. Chen

Abstract This paper describes a model for numerically simulating thermal recovery processes. The primary locus is on the simulation of in-situ combustion, but the formulation also represents fire-and-water flooding, steamflooding, hot water flooding, steam stimulation, and spontaneous ignition as well. The simulator describes the flow of water, oil, and gas, and includes gravity and capillary effects. Heat transfer by conduction, convection, and vaporization-condensation of both water and hydrocarbons are included. The rigorous but general nature of the simulator is obtained by employing conservation balance equations for oxygen, inert gases, a light hydrocarbon pseudocomponent, a heavy hydrocarbon pseudocomponent, water, coke, and energy. pseudocomponent, water, coke, and energy. Vaporization-condensation is governed by vaporliquid equilibrium using temperature and pressure-dependent equilibrium coefficients. Four pressure-dependent equilibrium coefficients. Four chemical reactions are accounted for: formation of coke from the heavy hydrocarbon component and the oxidation of coke and both heavy and light hydrocarbon components. Formulation details, numerical solution procedures, and computational results are presented. procedures, and computational results are presented. The computational results include both one- and two-dimensional cross-sectional studies. The simulator represents a major improvement in the ability to simulate thermal recovery processes under complex conditions. Introduction Considerable progress has been made in numerically simulating thermally enhanced oil-recovery processes during the last few years. This is particularly true for-processes involving steam, where we have seen a continual improvement of our ability to treat the problem. The most recent contributions provide an analysis capability for steam displacement and steam stimulation recovery methods, accounting for all the important physical mechanisms of these processes. Progress in simulating the performance of in-situ combustion processes is not so advanced. Initial simulation attempts were concerned primarily with the heat-transfer aspects of combustion. The most sophisticated heat-transfer model was developed by Chu. His numerical model considers the energy effects of vaporization and condensation on the temperature distribution, but neglects the accompanying phase changes by assuming constant fluid saturations. More recent heat transfer or heat-wave models for the in-situ combustion process were proposed by Kuo in 1969 and by Smith and Farouq-Ali in 1971. Kuo's model allows two temperature fronts-one at the combustion zone and one at a heat front. The heat-front position is predicted by gas flow that is allowed to have a velocity different from the velocity of the combustion front. The simulator proposed by Smith and Farouq-Ali is designed for proposed by Smith and Farouq-Ali is designed for predicting sweep efficiencies in confined well predicting sweep efficiencies in confined well patterns. Their numerical model accounts for heat patterns. Their numerical model accounts for heat generation by a combustion zone (assuming fixed fuel content all through the reservoir), heat transfer by conduction and convection (single-phase gas flow) in the reservoir, heat losses by conduction to adjacent formations, and different permeability-to-gas (air) flow on either side of the combustion zone. Special cases of the in-situ combustion process were studied by Gottfried and Khelil. These authors examine the heat transfer and oxygen use in reservoirs composed of an oil-bearing layer and an overlying "clean" porous zone containing only gas. These models were designed primarily to investigate the various transport mechanisms present when combustion is initiated in a reservoir present when combustion is initiated in a reservoir containing a gas cap. Because of the many assumptions invoked and the specialized geometry to which they apply, they do not satisfy the need for a general purpose simulator. SPEJ P. 37


Processes ◽  
2019 ◽  
Vol 7 (9) ◽  
pp. 621 ◽  
Author(s):  
Yang ◽  
Han ◽  
Liu

An in-situ combustion method is an effective method to enhance oil recovery with high economic recovery rate, low risk, fast promotion and application speed. Currently, in-situ combustion technique is regarded as the last feasible thermal recovery technology to replace steam injection in the exploitation of bitumen sands and heavy oil reservoirs. However, the oil-discharging mechanism during the in-situ combustion process is still not clearly understood. In this paper, the in-situ combustion process has been numerically simulated based on the Du 66 block. The effect of production parameters (huff and puff rounds, air injection speed, and air injection temperature) and geological parameters (bottom water thickness, stratigraphic layering, permeability ratio, and formation thickness) on the heavy oil recovery have been comprehensively analyzed. Results show that the flooding efficiency is positively correlated with the thickness of the bottom water, and negatively correlated with the formation heterogeneity. There exist optimum values for the oil layer thickness, huff and puff rounds, and air injection speed. And the effect of air injection temperature is not significant. The results of this paper can contribute to the understanding of mechanisms during in-situ combustion and the better production design for heavy oil reservoirs.


Author(s):  
Charles W. Allen

With respect to structural consequences within a material, energetic electrons, above a threshold value of energy characteristic of a particular material, produce vacancy-interstial pairs (Frenkel pairs) by displacement of individual atoms, as illustrated for several materials in Table 1. Ion projectiles produce cascades of Frenkel pairs. Such displacement cascades result from high energy primary knock-on atoms which produce many secondary defects. These defects rearrange to form a variety of defect complexes on the time scale of tens of picoseconds following the primary displacement. A convenient measure of the extent of irradiation damage, both for electrons and ions, is the number of displacements per atom (dpa). 1 dpa means, on average, each atom in the irradiated region of material has been displaced once from its original lattice position. Displacement rate (dpa/s) is proportional to particle flux (cm-2s-1), the proportionality factor being the “displacement cross-section” σD (cm2). The cross-section σD depends mainly on the masses of target and projectile and on the kinetic energy of the projectile particle.


Energies ◽  
2021 ◽  
Vol 14 (15) ◽  
pp. 4570
Author(s):  
Aman Turakhanov ◽  
Albina Tsyshkova ◽  
Elena Mukhina ◽  
Evgeny Popov ◽  
Darya Kalacheva ◽  
...  

In situ shale or kerogen oil production is a promising approach to developing vast oil shale resources and increasing world energy demand. In this study, cyclic subcritical water injection in oil shale was investigated in laboratory conditions as a method for in situ oil shale retorting. Fifteen non-extracted oil shale samples from Bazhenov Formation in Russia (98 °C and 23.5 MPa reservoir conditions) were hydrothermally treated at 350 °C and in a 25 MPa semi-open system during 50 h in the cyclic regime. The influence of the artificial maturation on geochemical parameters, elastic and microstructural properties was studied. Rock-Eval pyrolysis of non-extracted and extracted oil shale samples before and after hydrothermal exposure and SARA analysis were employed to analyze bitumen and kerogen transformation to mobile hydrocarbons and immobile char. X-ray computed microtomography (XMT) was performed to characterize the microstructural properties of pore space. The results demonstrated significant porosity, specific pore surface area increase, and the appearance of microfractures in organic-rich layers. Acoustic measurements were carried out to estimate the alteration of elastic properties due to hydrothermal treatment. Both Young’s modulus and Poisson’s ratio decreased due to kerogen transformation to heavy oil and bitumen, which remain trapped before further oil and gas generation, and expulsion occurs. Ultimately, a developed kinetic model was applied to match kerogen and bitumen transformation with liquid and gas hydrocarbons production. The nonlinear least-squares optimization problem was solved during the integration of the system of differential equations to match produced hydrocarbons with pyrolysis derived kerogen and bitumen decomposition.


2021 ◽  
pp. 000370282199044
Author(s):  
Wubin Weng ◽  
Shen Li ◽  
Marcus Aldén ◽  
Zhongshan Li

Ammonia (NH3) is regarded as an important nitrogen oxides (NOx) precursor and also as an effective reductant for NOx removal in energy utilization through combustion, and it has recently become an attractive non-carbon alternative fuel. To have a better understanding of thermochemical properties of NH3, accurate in situ detection of NH3 in high temperature environments is desirable. Ultraviolet (UV) absorption spectroscopy is a feasible technique. To achieve quantitative measurements, spectrally resolved UV absorption cross-sections of NH3 in hot gas environments at different temperatures from 295 K to 590 K were experimentally measured for the first time. Based on the experimental results, vibrational constants of NH3 were determined and used for the calculation of the absorption cross-section of NH3 at high temperatures above 590 K using the PGOPHER software. The investigated UV spectra covered the range of wavelengths from 190 nm to 230 nm, where spectral structures of the [Formula: see text] transition of NH3 in the umbrella bending mode, v2, were recognized. The absorption cross-section was found to decrease at higher temperatures. For example, the absorption cross-section peak of the (6, 0) vibrational band of NH3 decreases from ∼2 × 10−17 to ∼0.5 × 10−17 cm2/molecule with the increase of temperature from 295 K to 1570 K. Using the obtained absorption cross-section, in situ nonintrusive quantification of NH3 in different hot gas environments was achieved with a detection limit varying from below 10 parts per million (ppm) to around 200 ppm as temperature increased from 295 K to 1570 K. The quantitative measurement was applied to an experimental investigation of NH3 combustion process. The concentrations of NH3 and nitric oxide (NO) in the post flame zone of NH3–methane (CH4)–air premixed flames at different equivalence ratios were measured.


Fuel ◽  
2021 ◽  
Vol 284 ◽  
pp. 118972
Author(s):  
Dong Liu ◽  
Junshi Tang ◽  
Ruonan Zheng ◽  
Qiang Song

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