An Extended Viscoelastic Model for Predicting Polymer Apparent Viscosity at Different Shear Rates

2021 ◽  
Author(s):  
Mursal Zeynalli ◽  
Emad W. Al-Shalabi ◽  
Waleed AlAmeri

Abstract Polymer flooding is one of the most commonly used chemical EOR methods. Conventionally, this technique was believed to improve macroscopic sweep efficiency by sweeping only bypassed oil. Nevertheless, recently it has been found that polymers exhibiting viscoelastic behavior in the porous medium can also improve microscopic displacement efficiency resulting in higher additional oil recovery. Therefore, an accurate prediction of the complex rheological response of polymers is crucial to obtain a proper estimation of incremental oil to polymer flooding. In this paper, a novel viscoelastic model is proposed to comprehensively analyze the polymer rheological behavior in porous media. The proposed viscoelastic model is considered an extension of the unified apparent viscosity model provided in the literature and is termed as extended unified viscosity model (E-UVM). The main advantage of the proposed model is its ability to capture the polymer mechanical degradation at ultimate shear rates primarily observed near wellbores. Furthermore, the fitting parameters used in the model were correlated to rock and polymer properties, significantly reducing the need for time-consuming coreflooding tests for future polymer screening works. Moreover, the extended viscoelastic model was implemented in MATLAB Reservoir Simulation Toolbox (MRST) and verified against the original shear model existing in the simulator. It was found that implementing the viscosity model in MRST might be more accurate and practical than the original method. In addition, the comparison between various viscosity models proposed earlier and E-UVM in the reservoir simulator revealed that the latter model could yield more reliable oil recovery predictions since it accommodates the mechanical degradation of polymers. This study presents a novel viscoelastic model that is more comprehensive and representative as opposed to other models in the literature.

2021 ◽  
Author(s):  
Mursal Zeynalli ◽  
Emad W. Al-Shalabi ◽  
Waleed AlAmeri

Abstract Being one of the most commonly used chemical EOR methods, polymer flooding can substantially improve both macroscopic and microscopic recovery efficiencies by sweeping bypassed oil and mobilizing residual oil, respectively. However, a proper estimation of incremental oil to polymer flooding requires an accurate prediction of the complex rheological response of polymers. In this paper, a novel viscoelastic model that comprehensively analyzes the polymer rheology in porous media is used in a reservoir simulator to predict the recovery efficiency to polymer flooding at both core- and field-scales. The extended viscoelastic model can capture polymer Newtonian and non-Newtonian behavior, as well as mechanical degradation that may take place at ultimate shear rates. The rheological model was implemented in an open- source reservoir simulator. In addition, the effect of polymer viscoelasticity on displacement efficiency was also captured through trapping number. The calculation of trapping number and corresponding residual-phase saturation was verified against a commercial simulator. Core-scale tertiary polymer flooding predictions revealed the positive effect of injection rate and polymer concentration on oil displacement efficiency. It was found that high polymer concentration (>2000 ppm) is needed to displace residual oil at reservoir rate as opposed to near injector well rate. On the other hand, field-scale predictions of polymer flooding were performed in a quarter 5-spot well pattern, using rock and fluid properties representing the Middle East carbonate reservoirs. The field-simulation studies showed that tertiary polymer flooding might improve both volumetric sweep efficiency and displacement efficiency. For this case study, incremental oil recovery by polymer flooding is estimated at around 11 %OOIP, which includes about 4 %OOIP residual oil mobilized by viscoelastic polymers. Furthermore, the effect of different parameters on the polymer flooding efficiency was investigated through sensitivity analysis. This study provides more insight into the robustness of the extended viscoelastic model as well as its effect on polymer injectivity and related oil recovery at both core- and field-scales. The proposed polymer viscoelastic model can be easily implemented into any commercial reservoir simulator for representative field-scale predictions of polymer flooding.


2017 ◽  
Vol 10 (1) ◽  
pp. 94-107 ◽  
Author(s):  
Kaoping Song ◽  
Ning Sun ◽  
Yanfu Pi

Background: Polymer flooding is the most commonly applied chemical enhanced-oil-recovery technique in offshore oilfields. However, there are challenges and risks in applying the technology of polymer flooding to offshore heavy oil development. Objective: This paper compared the spread law and the displacement effect of different injection modes and validated the feasibility of enhancing oil recovery by variable concentrations polymer flooding. Method: Two types of laboratory experiments were designed by using micro etching glass models and heterogeneous artificial cores. Furthermore, in order to determine a better polymer flooding mode, the displacement results, displacement characteristic curves and oil saturation distribution of heterogeneous artificial cores were also compared, respectively. Results: The experimental results showed that the recovery of variable concentrations polymer flooding was higher than that of constant concentration polymer flooding, under conditions of same total amount of polymer and similar water flooding recovery. Its sweep efficiency and displacement efficiency were also significantly higher than those of constant concentration polymer flooding. Moreover, variable concentrations polymer flooding had lower peak pressure and was at lower risk for reaching the formation fracture pressure. Conclusion: As a consequence, variable concentrations polymer flooding has certain feasibility for heterogeneous reservoir in offshore oilfields, and can improve interlayer heterogeneity to further tapping remaining oil in medium and low permeability layer. Conclusions of this paper can provide reference for the field application of polymer flooding in offshore oilfields.


Energies ◽  
2018 ◽  
Vol 11 (8) ◽  
pp. 1950 ◽  
Author(s):  
Hong He ◽  
Jingyu Fu ◽  
Baofeng Hou ◽  
Fuqing Yuan ◽  
Lanlei Guo ◽  
...  

The heterogeneous phase combination flooding (HPCF) system which is composed of a branched-preformed particle gel (B-PPG), polymer, and surfactant has been proposed to enhance oil recovery after polymer flooding in heterogeneous reservoirs by mobility control and reducing oil–water interfacial tension. However, the high cost of chemicals can make this process economically challenging in an era of low oil prices. Thus, in an era of low oil prices, it is becoming even more essential to optimize the heterogeneous phase combination flooding design. In order to optimize the HPCF process, the injection strategy has been designed such that the incremental oil recovery can be maximized using the corresponding combination of the B-PPG, polymer, and surfactant, thereby ensuring a more economically-viable recovery process. Different HPCF injection strategies including simultaneous injection and alternation injection were investigated by conducting parallel sand pack flooding experiments and large-scale plate sand pack flooding experiments. Results show that based on the flow rate ratio, the pressure rising area and the incremental oil recovery, no matter whether the injection strategy is simultaneous injection or alternation injection of HPCF, the HPCF can significantly block high permeability zone, increase the sweep efficiency and oil displacement efficiency, and effectively improve oil recovery. Compared with the simultaneous injection mode, the alternation injection of HPCF can show better sweep efficiency and oil displacement efficiency. Moreover, when the slug of HPCF and polymer/surfactant with the equivalent economical cost is injected by alternation injection mode, as the alternating cycle increases, the incremental oil recovery increases. The remaining oil distribution at different flooding stages investigated by conducting large-scale plate sand pack flooding experiments shows that alternation injection of HPCF can recover more remaining oil in the low permeability zone than simultaneous injection. Hence, these findings could provide the guidance for developing the injection strategy of HPCF to further enhance oil recovery after polymer flooding in heterogeneous reservoirs in the era of low oil prices.


Geofluids ◽  
2018 ◽  
Vol 2018 ◽  
pp. 1-11 ◽  
Author(s):  
Huiying Zhong ◽  
Qiuyuan Zang ◽  
Hongjun Yin ◽  
Huifen Xia

With the growing demand for oil energy and a decrease in the recoverable reserves of conventional oil, the development of viscous oil, bitumen, and shale oil is playing an important role in the oil industry. Bohai Bay in China is an offshore oilfield that was developed through polymer flooding process. This study investigated the pore-scale displacement of medium viscosity oil by hydrophobically associating water-soluble polymers and purely viscous glycerin solutions. The role and contribution of elasticity on medium oil recovery were revealed and determined. Comparing the residual oil distribution after polymer flooding with that after glycerin flooding at a dead end, the results showed that the residual oil interface exhibited an asymmetrical “U” shape owing to the elasticity behavior of the polymer. This phenomenon revealed the key of elasticity enhancing oil recovery. Comparing the results of polymer flooding with that of glycerin flooding at different water flooding sweep efficiency levels, it was shown that the ratio of elastic contribution on the oil displacement efficiency increased as the water flooding sweep efficiency decreased. Additionally, the experiments on polymers, glycerin solutions, and brines displacement medium viscosity oil based on a constant pressure gradient at the core scale were carried out. The results indicated that the elasticity of the polymer can further reduce the saturation of medium viscosity oil with the same number of capillaries. In this study, the elasticity effect on the medium viscosity oil interface and the elasticity contribution on the medium viscosity oil were specified and clarified. The results of this study are promising with regard to the design and optimum polymers applied in an oilfield and to an improvement in the recovery of medium viscosity oil.


SPE Journal ◽  
2016 ◽  
Vol 21 (03) ◽  
pp. 0675-0687 ◽  
Author(s):  
A.. Clarke ◽  
A. M. Howe ◽  
J.. Mitchell ◽  
J.. Staniland ◽  
L. A. Hawkes

Summary Increasing flooding-solution viscosity with polymers provides a favorable mobility ratio compared with brine flooding and hence improves volumetric sweep efficiency. Flooding with a polymer solution exhibiting elastic properties has been reported to increase displacement efficiency, resulting in a sustained doubling of the recovery enhancement compared with the use of conventional viscous-polymer flooding (Wang et al. 2011). Flooding with viscoelastic-polymer solutions is claimed also to increase recovery more than expected from changes in capillary number alone (Wang et al. 2010). This increase in displacement efficiency by viscoelastic polymers is reported to occur because of changes in the steady-state-flow profile and enhancements in oil stripping and thread formation. However, within the industry there are doubts that a genuine effect is observed, or that improvements in displacement efficiency occur with field-applicable flow regimes (Vermolen et al. 2014). In this study, we demonstrate that flooding with viscoelastic-polymer solutions can indeed increase recovery more than expected from changes in capillary number. We show a mechanism of fluctuations in flow at low Reynolds number by which viscoelastic-polymer solutions provide improvements in displacement efficiency. The mechanism, known as elastic turbulence, is an effect previously unrecognized in this context. We demonstrate that the effect may be obtained at field-relevant flow rates. Furthermore, this underlying mechanism explains both the enhanced capillary-desaturation curves and the observation of apparent flow thickening (Delshad et al. 2008; Seright et al. 2011) for these viscoelastic solutions in porous media. The work contrasts experiments on flow and recovery by use of viscous and viscoelastic-polymer solutions. The circumstances under which viscoelasticity is beneficial are demonstrated. The findings are applicable to the design of formulations for enhanced oil recovery (EOR) by polymer flooding. A combination of coreflooding, micromodel flow, and rheometric studies is presented. The results include single-phase and multiphase floods in sandstone cores. Polymer solutions are viscoelastic [partially hydrolyzed polyacrylamide (HPAM)] or viscous (xanthan). The effects of molecular weight, flow rate, and concentration of the HPAMs are described. The data lead us to suggest a mechanism that may be used to explain the observations of improved displacement efficiency and why the improvement is not seen for all viscoelastic-polymer floods.


SPE Journal ◽  
2018 ◽  
Vol 24 (01) ◽  
pp. 129-139 ◽  
Author(s):  
J. L. Juárez-Morejón ◽  
H.. Bertin ◽  
A.. Omari ◽  
G.. Hamon ◽  
C.. Cottin ◽  
...  

Summary An experimental study of polymer flooding is presented here, focusing on the influence of initial core wettability and flood maturity (volume of water injected before polymer injection) on final oil recovery. Experiments were performed using homogeneous Bentheimer Sandstone samples of similar properties. The cores were oilflooded using mineral oil for water-wet conditions and crude oil (after an aging period) for intermediate-wet conditions; the viscosity ratio between oil and polymer was kept constant in all experiments. Polymer, which is a partially hydrolyzed polyacrylamide (HPAM), was used at a concentration of 2,500 ppm in a moderate-salinity brine. The polymer solution was injected in the core at different waterflood-maturity times [breakthrough (BT) and 0, 1, 1.75, 2.5, 4, and 6.5 pore volumes (PV)]. Coreflood results show that the maturity of polymer injection plays an important role in final oil recovery, regardless of wettability. The waterflood-maturity time 0 PV (polymer injection without initial waterflooding) leads to the best sweep efficiency, whereas final oil production decreases when the polymer-flood maturity is high (late polymer injection after waterflooding). A difference of 15% in recovery is observed between early polymer flooding (0 PV) and late maturity (6.5 PV). Concerning the effect of wettability, the recovery factor obtained with water-wet cores is always lower (from 10 to 20%, depending on maturity) than the values obtained with intermediate-wet cores, raising the importance of correctly restoring core wettability to obtain representative values of polymer incremental recovery. The influence of wettability can be explained by the oil-phase distribution at the pore scale. Considering that the waterflooding period leads to different values of the oil saturation at which polymer flooding starts, we measured the core dispersivity using a tracer method at different states. The two-phase dispersivity decreases when water saturation increases, which is favorable for polymer sweep. This study shows that in addition to wettability, the maturity of polymer flooding plays a dominant role in oil-displacement efficiency. Final recovery is correlated to the dispersion value at which polymer flooding starts. The highest oil recovery is obtained when the polymer is injected early.


2013 ◽  
Vol 275-277 ◽  
pp. 496-501
Author(s):  
Fu Qing Yuan ◽  
Zhen Quan Li

According to the geological parameters of Shengli Oilfield, sweep efficiency of chemical flooding was analyzed according to injection volume, injection-production parameters of polymer flooding or surfactant-polymer compound flooding. The orthogonal design method was employed to select the important factors influencing on expanding sweep efficiency by chemical flooding. Numerical simulation method was utilized to analyze oil recovery and sweep efficiency of different flooding methods, such as water flooding, polymer flooding and surfactant-polymer compound flooding. Finally, two easy calculation models were established to calculate the expanding degree of sweep efficiency by polymer flooding or SP compound flooding than water flooding. The models were presented as the relationships between geological parameters, such as effective thickness, oil viscosity, porosity and permeability, and fluid parameters, such as polymer-solution viscosity and oil-water interfacial tension. The precision of the two models was high enough to predict sweep efficiency of polymer flooding or SP compound flooding.


2018 ◽  
Vol 140 (10) ◽  
Author(s):  
Zhanxi Pang ◽  
Peng Qi ◽  
Fengyi Zhang ◽  
Taotao Ge ◽  
Huiqing Liu

Heavy oil is an important hydrocarbon resource that plays a great role in petroleum supply for the world. Co-injection of steam and flue gas can be used to develop deep heavy oil reservoirs. In this paper, a series of gas dissolution experiments were implemented to analyze the properties variation of heavy oil. Then, sand-pack flooding experiments were carried out to optimize injection temperature and injection volume of this mixture. Finally, three-dimensional (3D) flooding experiments were completed to analyze the sweep efficiency and the oil recovery factor of flue gas + steam flooding. The role in enhanced oil recovery (EOR) mechanisms was summarized according to the experimental results. The results show that the dissolution of flue gas in heavy oil can largely reduce oil viscosity and its displacement efficiency is obviously higher than conventional steam injection. Flue gas gradually gathers at the top to displace remaining oil and to decrease heat loss of the reservoir top. The ultimate recovery is 49.49% that is 7.95% higher than steam flooding.


2019 ◽  
Vol 17 (3) ◽  
pp. 722-733 ◽  
Author(s):  
Afaque Ahmed ◽  
Ismail Mohd Saaid ◽  
Abdelazim Abbas Ahmed ◽  
Rashidah M. Pilus ◽  
Mirza Khurram Baig

AbstractRecently, nanoparticles have proven to enhance oil recovery on the core-flood scale in challenging high-pressure high-temperature reservoirs. Nanomaterials generally appear to improve oil production through wettability alteration and reduction in interfacial tension between oil and water phases. Besides, they are environmentally friendly and cost-effective enhanced oil recovery techniques. Studying the rheological properties of nanoparticles is critical for field applications. The instability of nanoparticle dispersion due to aggregation is considered as an unfavorable phenomenon in nanofluid flooding while conducting an EOR process. In this study, wettability behavior and rheological properties of surface-treated silica nanoparticles using internal olefins sulfonates (IOS20–24 and IOS19–23), anionic surfactants were investigated. Surface modification effect on the stability of the colloidal solution in porous media and oil recovery was inspected. The rheology of pure and surface-treated silica nanoparticles was investigated using a HPHT rheometer. Morphology and particle size distributions of pure and coated silica nanoparticles were studied using a field emission scanning electron microscope. A series of core-flood runs was conducted to evaluate the oil recovery factor. The coated silica nanoparticles were found to alter rheological properties and exhibited a shear-thinning behavior as the stability of the coated silica nanoparticles could be improved considerably. At low shear rates, the viscosity slightly increases, and the opposite happens at higher shear rates. Furthermore, the surface-modified silica nanoparticles were found to alter the wettability of the aqueous phase into strongly water-wet by changing the contact angle from 80° to 3° measured against glass slides representing sandstone rocks. Oil–water IFT results showed that the surface treatment by surfactant lowered the oil–water IFT by 30%. Also, the viscosity of brine increased from 0.001 to 0.008 Pa s by introducing SiO2 nanoparticles to the aqueous phase for better displacement efficiency during chemical-assisted EOR. The core-flood experiments revealed that the ultimate oil recovery is increased by approximately 13% with a surfactant-coated silica nanofluid flood after the conventional waterflooding that proves the potential of smart nanofluids for enhancing oil recovery. The experimental results imply that the use of surfactant-coated nanoparticles in tertiary oil recovery could facilitate the displacement efficiency, alter the wettability toward more water-wet and avoid viscous fingering for stable flood front and additional oil recovery.


2020 ◽  
Vol 60 (2) ◽  
pp. 662
Author(s):  
Saira ◽  
Furqan Le-Hussain

Oil recovery and CO2 storage related to CO2 enhance oil recovery are dependent on CO2 miscibility. In case of a depleted oil reservoir, reservoir pressure is not sufficient to achieve miscible or near-miscible condition. This extended abstract presents numerical studies to delineate the effect of alcohol-treated CO2 injection on enhancing miscibility, CO2 storage and oil recovery at immiscible and near-miscible conditions. A compositional reservoir simulator from Computer Modelling Group Ltd. was used to examine the effect of alcohol-treated CO2 on the recovery mechanism. A SPE-5 3D model was used to simulate oil recovery and CO2 storage at field scale for two sets of fluid pairs: (1) pure CO2 and decane and (2) alcohol-treated CO2 and decane. Alcohol-treated CO2 consisted of a mixture of 4 wt% of ethanol and 96 wt% of CO2. All simulations were run at constant temperature (70°C), whereas pressures were determined using a pressure-volume-temperature simulator for immiscible (1400 psi) and near-miscible (1780 psi) conditions. Simulation results reveal that alcohol-treated CO2 injection is found superior to pure CO2 injection in oil recovery (5–9%) and CO2 storage efficiency (4–6%). It shows that alcohol-treated CO2 improves CO2 sweep efficiency. However, improvement in sweep efficiency with alcohol-treated CO2 is more pronounced at higher pressures, whereas improvement in displacement efficiency is more pronounced at lower pressures. The proposed methodology has potential to enhance the feasibility of CO2 sequestration in depleted oil reservoirs and improve both displacement and sweep efficiency of CO2.


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