Anisotropic Nano-Platelets to Develop Gel Strength at High Temperature in Aqueous Fluids

2021 ◽  
Author(s):  
Hasmukh Patel ◽  
Gadam Myratgeldiyev

Abstract Aqueous fluids also refer as water-based drilling muds (WBMs) have considered as the most favorable WBMs, owing to their inherent advantages such as economically viability and environmentally benign characteristics. The major problems WBMs encountered is thinning of drilling fluids while drilling under high pressure high temperature. The detrimental rheological properties of WBMs under HPHT result into pipe sticking, low rate of penetration of the drill bit and requirement of high torque for drilling operations. The hydrophilic clays have been employed as viscosifiers in WBMs to maintain the rheological properties, albeit, their viscosifying characteristics have hindered in the presence of ionic species in the aqueous system at high temperature. These shortcomings can be tackled by developing an additive that can exhibit neutral surface changes and ability to undergo gelation at higher temperature. We have developed an additive functionalized with polar groups on anisotropic nano-platelets (LMS) through sol-gel technique. Spectroscopic and crystallographic characterization of LMS have proved the formation of layered structures with covalently linked polar functionalities. The viscoelastic studies were conducted on aqueous dispersion of these nano-platelets at different temperature, which revealed an unprecedented phenomenon -increase in gel strength at higher temperature, a key property required for ideal WBMs. LMS nano-platelet has shown formation of network structure in aqueous medium to boost storage modulus of the fluid. This additive can overcome the demerits associated with natural hydrophilic layered silicates and improve the rheological properties under challenging well conditions.

Author(s):  
Abdul Razak Ismail ◽  
W. R. W Sulaiman ◽  
M. Z. Jaafar ◽  
A. Aftab ◽  
A. A. Razi ◽  
...  

Drilling fluid is the key component to drill oil and gas wells. The rheological behavior of drilling fluid will be affected when drilling deep wells especially at high temperature and high pressure reservoir. This research was conducted to study the effect of the nanoparticles over the rheological properties of the drilling fluid when aging at high temperature condition. Several drilling fluids were prepared using synthetic based fluids (Sarapar and Saraline) to study the effect of multi-walled carbon nanotube (MWCNT) at different concentrations. The rheological properties of drilling fluid were analyzed after aging at 250 °F and 350 °F for 16 hours. The results revealed that the addition of MWCNT improved the 10-sec gel strength by 33% and filtrate loss volume was reduced to 10% after aging at 250°F in Saraline drilling fluid. Moreover, the plastic viscosity of Saraline and Sarapar drilling fluid after addition of MWCNT was enhanced by 6% and 27% at 350 °F. Filtrate loss volume of Sarapar drilling fluid was reduced by 19 % after aging at 250 °F for 16 hours. The overall results showed that the addition of MWCNT into the drilling fluid have slightly improved the rheological properties of drilling fluids under high temperature conditions.


2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Jinliang Liu ◽  
Fengshan Zhou ◽  
Fengyi Deng ◽  
Hongxing Zhao ◽  
Zhongjin Wei ◽  
...  

Abstract Most of bentonite used in modern drilling engineering is physically and chemically modified calcium bentonite. However, with the increase of drilling depth, the bottom hole temperature may reach 180 °C, thus a large amount of calcium bentonite used in the drilling fluid will be unstable. This paper covers three kinds of calcium bentonite with poor rheological properties at high temperature, such as apparent viscosity is greater than 45 mPa·s or less than 10 mPa·s, API filtration loss is greater than 25 mL/30 min, which are diluted type, shear thickening type and low-shear type, these defects will make the rheological properties of drilling fluid worse. The difference is attributed to bentonite mineral composition, such as montmorillonite with good hydration expansion performance. By adding three kinds of heat-resistant water-soluble copolymers Na-HPAN (hydrolyzed polyacrylonitrile sodium), PAS (polycarboxylate salt) and SMP (sulfomethyl phenolic resin), the rheological properties of calcium bentonite drilling fluids can be significantly improved. For example, the addition of 0.1 wt% Na-HPAN and 0.1 wt% PAS increased the apparent viscosity of the XZJ calcium bentonite suspension from 4.5 to 19.5 mPa·s at 180 °C, and the filtration loss also decreased from 20.2 to 17.8 mL.


Author(s):  
Khalil Rehman Memon ◽  
Aftab Ahmed Mahesar ◽  
Shahzad Ali Baladi ◽  
Muhannad Talib Sukar

The experimental study was conducted on rheological properties in laboratory to measure the integrity of cement slurry. Three samples were used and analyzed at different parameters to check the elasticity of cement slurry. Additives with various concentrations, i.e. silica fume % BWOC (Present by Weight on Cement) (15, 17, 19 and 21), dispersant % Wt (Percent Weight) (0.21, 0.26 and 0.31) and additional 1; % Wt of fluid losscontrol were used to improve the performance of the cement slurry at the temperature of 123oC. The results have shown that increase in the concentration of dispersants that have caused to decrease in the Plastic Viscosity (PV), Yield Point (YP) and GS (Gel Strength). The rheological properties of cement were improved with the addition of fluid loss control additive in 21 % BWOC (Present by Weight on Cement) silica fume increase the water quantity in cement slurry that improve its durability and to reduce the strength retrogression in High Temperature High Pressure (HTHP) environment. Results were achieved through HTHP OFITE Viscometer (Model 1100).


2012 ◽  
Vol 9 (3) ◽  
pp. 354-362 ◽  
Author(s):  
Fuhua Wang ◽  
Xuechao Tan ◽  
Ruihe Wang ◽  
Mingbo Sun ◽  
Li Wang ◽  
...  

2021 ◽  
Author(s):  
Wenxi Zhu ◽  
Xiuhua Zheng

Colloidal gas aphron (CGA) drilling fluids are a kind of environmentally-friendly underbalanced drilling technique, which has attracted more attention in depleted reservoirs and other low-pressure areas. With the shortage of global oil/gas resources, drilling has gradually shifted to high-temperature and deep wells. Hence, a study on the ultra-high temperature rheology properties of CGA fluids is lacking and urgently needed. In this study, a novel CGA drilling fluid system was prepared by modified starch and amino acid surfactant, and rheological properties after 120-300°C aged was investigate. Results show that: (1) Herschel-Bulkley model is the preferred model to predict CGA drilling fluid at ultra-high temperatures; (2) It was proved that CGA drilling fluid is a high-quality drilling fluid with extremely high value of LSRV and shear thinning property within 280°C. Compared to the traditional XG-based CGA drilling fluid, the improvement of LSRV at ultra-high temperatures is a significant advantage of EST-based CGA drilling fluid which is conducive to carrying cuttings and sealing formation pores.


2016 ◽  
Vol 4 (Special-Issue-October) ◽  
pp. 18-25 ◽  
Author(s):  
A.E Labropoulos ◽  
T. H Varzakas

Many naturally-occuring gels exists in the biological systems such as foods. Because of their biodiversibily and delicate nature, their properties can be used by the food industry to achieve a variety of physicochemical functions. The gel utilized in this study, soy protein isolates (SPI) and concentrates (SPC), all have unique rheological properties which play an important role in their strength function of foods. The objective of this study is to gain insights as to how the rheological properties of these bio-gels are designed to control the gel-strength of these materials. The concentration dependence of dynamic moduli G’ and G” of soy protein isolates (SPI) and soy protein concentrates were studied in solutions prepared under different conditions. Three-level preliminary fractional experiments were undertaken to study effects of temperature, pH, and concentration on the gel-strength of these products. Protein concentration, pH and temperature appear to have an impact on the strength of these bio-gels. An investigation of the viscoelastic behavior of SPI solution at the sol-gel transition point was mainly considered by applying a rheological testing procedure. The data demonstrated a power law frequency dependence of the viscoelastic functions G΄(ω) and n*(ω) at the gel point. At low temperatures and high concentrations we get weaker gel-strengths than at high temperatures and low concentrations. Lowering the concentration and keeping the temperature constant seem to have little effect on the gel strength but points towards to becoming stronger gels.


2018 ◽  
Author(s):  
Dongmei Pan ◽  
C. Vipulanandan ◽  
Niousha Amani ◽  
Sai Anudeep Reddy ◽  
Chella Ganapathy Chockalingam

Author(s):  
Tariq Ahmed ◽  
Nura Makwashi

The selection and control of a suitable drilling fluid is necessary to successfully drill an oil and gas well. The rheological properties of drilling fluids vary with changes in conditions such as time and temperature. Slight changes in these conditions can cause unpredictable and significant changes in the mud’s properties. This makes it necessary to study the rheology of drilling fluids and how it is affected by these changes. At the rig sites, tests are carried out by the mud engineers to ensure that the properties of the drilling fluids are within the required limits. Similar tests were carried out at the laboratory in this work to determine the plastic viscosity, yield point, gel strength of mud samples at different conditions of ageing time, temperature and concentration of Xanthan gum (X.G) used as an additive. The Experiments carried out were grouped into three. The first was done with the aim to further explain how the Bentonite and Sepiolite water-based drilling fluids behaves after been aged for certain period. The second sets of experiments were conducted to investigate how the rheological properties of water-based Bentonite muds are affected by different concentration of xanthan gum added as an additive to improve the muds properties and the last sets of experiments were done to investigate the ageing effect on Bentonite mud treated with 250mg/L xanthan gum. Effects of temperature were also considered in these experiments with a 10℃ variation in the first group and 20℃ in the other two groups between readings from 20℃ to 60℃ . Results obtained indicated that Sepiolite water-based drilling fluid offers better plastic viscosity and yield point as compared to Bentonite water-based drilling fluids. It was also found that the viscosity and yield point of Sepiolite, Bentonite and treated Bentonite muds decreases with increase ageing time and temperature while the gel strength increases with ageing time but similarly decreases with increase in temperature. In the second group, results obtained indicated that plastic viscosity, yield point and gel strength increases as concentration of xanthan gum increases, all of which decreases with increase in temperature.


Sign in / Sign up

Export Citation Format

Share Document