Inertial Effect on Spontaneous Oil-Water Imbibition by Molecular Kinetic Theory

2021 ◽  
Author(s):  
Weibing Tian Tian ◽  
Keliu Wu ◽  
Zhangxin Chen ◽  
Yanling Gao ◽  
Yin Gao ◽  
...  

Abstract Imbibition is one of the most common physical phenomena in nature, and it plays an important role in enhanced oil recovery, hydrology, and environmental engineering. For the tight reservoirs, the imbibition method has an obvious advantage in fracturing, shut-in, and huff-puff development. Although the current imbibition studies focus on oil recovery, and the inertial effect in imbibition is neglected and its mechanism is also unclear. In this paper, the inertial effect on spontaneous oil-water imbibition at micron-scale is studied by molecular kinetic theory (MKT). The frictional coefficient in the model is a fitted parameter to match the experimental data during the total imbibition process. Then, the simulation of the initial imbibition stage is conducted and the inertial effect on imbibition is identified by the difference between the model considering the inertial effect (CI) and the model neglecting the inertial effect (NI), or by the proportion of inertial force to the total resistance. Results show that (i) with an increase in the water phase viscosity, the inertial effect time shortens, maximum imbibition height and rate decrease, and thus the inertial effect on imbibition weakens; (ii) with an increase in the oil phase viscosity, the inertial effect time changes little, the maximum imbibition height and rate decrease slightly, namely, the inertial effect depends slightly on the oil phase. (iii) with an increase in the capillary wettability (hydrophilicity), the inertial effect time shortens, the maximum imbibition rate first increases and then decreases, and the inertial effect on imbibition weakens. This work sheds light on the inertial effect on oil-water imbibition by MKT, considering the effects of dynamic contact angle, water phase viscosity, oil phase viscosity, and wettabilities, which is helpful to understand the role of inertia in the oil-water or oil-fracturing fluid imbibition process.

SPE Journal ◽  
2021 ◽  
pp. 1-16
Author(s):  
Weibing Tian ◽  
Keliu Wu ◽  
Zhangxin Chen ◽  
Lingbin Lai ◽  
Yanling Gao ◽  
...  

Summary Imbibition is one of the most common physical phenomena in nature, and it plays an important role in enhanced oil recovery, hydrology, and environmental engineering. The imbibition in a capillary is one of the fluid transports in porous media, and the effect of a dynamic contact angle that changes with the imbibition rate on liquid-liquid imbibition is not clear. In this paper, the molecular kinetic theory (MKT) is used to study the effect of a dynamic contact angle on spontaneous capillary-liquid-liquid imbibition at a micrometer scale. The results show that: Using a scaling time, the effects of various forces in different imbibition systems can be compared, the influence of a dynamic contact angle on imbibition can be characterized by a frictional effect of the three-phase contact line, and the proposed model considering the effect of a dynamic contact angle is better than the model neglecting the effect of a dynamic contact angle. As the displacing phase viscosity increases, the influence of a dynamic contact angle on imbibition strengthens, which is attributed to a decrease in the viscous effect and an increase in the frictional effect during the imbibition process; as the displaced phase viscosity increases, the influence of a dynamic contact angle on imbibition weakens, which is attributed to an increase in the viscous effect and a decrease in the frictional effect during the imbibition process. As the interfacial tension increases, the frictional effect increases, with the result that the effect of a dynamic contact angle on imbibition increases. As the capillary becomes more hydrophilic, the effect of a dynamic contact angle on imbibition becomes stronger because of a decreasing viscous effect and an increasing frictional effect. As the capillary length increases, the viscous effect increases, whereas the frictional effect decreases, leading to a decrease in the dynamic contact angle effect. As the capillary radius increases, the frictional force decreases, whereas its proportion in total resistance or the frictional effect increases, resulting in an increase in the effect of a dynamic contact angle. This work sheds light on the effect of a dynamic contact angle on capillary-liquid-liquid imbibition, including displacing phase viscosity, displaced phase viscosity, interfacial tension, capillary wettability, length, and radius. It will provide new insights into manipulating a capillary imbibition process and provide a fundamental theory for enhanced oil recovery by imbibition in conventional or unconventional reservoirs. Supplementary materials are available in support of this paper and have been published online under Supplementary Data at https://doi.org/10.2118/205490-PA. SPE is not responsible for the content or functionality of supplementary materials supplied by the authors.


2021 ◽  
Author(s):  
Xu-Guang Song ◽  
Ming-Wei Zhao ◽  
Cai-Li Dai ◽  
Xin-Ke Wang ◽  
Wen-Jiao Lv

AbstractThe ultra-low permeability reservoir is regarded as an important energy source for oil and gas resource development and is attracting more and more attention. In this work, the active silica nanofluids were prepared by modified active silica nanoparticles and surfactant BSSB-12. The dispersion stability tests showed that the hydraulic radius of nanofluids was 58.59 nm and the zeta potential was − 48.39 mV. The active nanofluids can simultaneously regulate liquid–liquid interface and solid–liquid interface. The nanofluids can reduce the oil/water interfacial tension (IFT) from 23.5 to 6.7 mN/m, and the oil/water/solid contact angle was altered from 42° to 145°. The spontaneous imbibition tests showed that the oil recovery of 0.1 wt% active nanofluids was 20.5% and 8.5% higher than that of 3 wt% NaCl solution and 0.1 wt% BSSB-12 solution. Finally, the effects of nanofluids on dynamic contact angle, dynamic interfacial tension and moduli were studied from the adsorption behavior of nanofluids at solid–liquid and liquid–liquid interface. The oil detaching and transporting are completed by synergistic effect of wettability alteration and interfacial tension reduction. The findings of this study can help in better understanding of active nanofluids for EOR in ultra-low permeability reservoirs.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Jian Hou ◽  
Ming Han ◽  
Jinxun Wang

AbstractThis work investigates the effect of the surface charges of oil droplets and carbonate rocks in brine and in surfactant solutions on oil production. The influences of the cations in brine and the surfactant types on the zeta-potentials of both oil droplets and carbonate rock particles are studied. It is found that the addition of anionic and cationic surfactants in brine result in both negative or positive zeta-potentials of rock particles and oil droplets respectively, while the zwitterionic surfactant induces a positive charge on rock particles and a negative charge on oil droplets. Micromodels with a CaCO3 nanocrystal layer coated on the flow channels were used in the oil displacement tests. The results show that when the oil-water interfacial tension (IFT) was at 10−1 mN/m, the injection of an anionic surfactant (SDS-R1) solution achieved 21.0% incremental oil recovery, higher than the 12.6% increment by the injection of a zwitterionic surfactant (SB-A2) solution. When the IFT was lowered to 10−3 mM/m, the injection of anionic/non-ionic surfactant SMAN-l1 solution with higher absolute zeta potential value (ζoil + ζrock) of 34 mV has achieved higher incremental oil recovery (39.4%) than the application of an anionic/cationic surfactant SMAC-l1 solution with a lower absolute zeta-potential value of 22 mV (30.6%). This indicates that the same charge of rocks and oil droplets improves the transportation of charged oil/water emulsion in the porous media. This work reveals that the surface charge in surfactant flooding plays an important role in addition to the oil/water interfacial tension reduction and the rock wettability alteration.


2014 ◽  
Vol 936 ◽  
pp. 1553-1555
Author(s):  
Meng Zheng

The technology was used for handling heavy aging oil by demulsifier and three phases horizontal scrow centrifuge. Through laboratory and field test, it showed that the water content of the processed aging oil dropped from 50% to 5% below, purity oil recovery rate reached more than 95%, meeting export quality requirements. The technology improved the effective storage capacity of flow station, is of great significance to the safe and steady operation of flow station.


2010 ◽  
Vol 49 (24) ◽  
pp. 12756-12761 ◽  
Author(s):  
Ajay Mandal ◽  
Abhijit Samanta ◽  
Achinta Bera ◽  
Keka Ojha

2018 ◽  
Vol 33 (1) ◽  
pp. 81-88 ◽  
Author(s):  
Zhe Li ◽  
Baojun Bai ◽  
Derong Xu ◽  
Ziyu Meng ◽  
Tao Ma ◽  
...  

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