Diffusivity of Gas Into Bitumen: Part II—Data Set and Correlation

SPE Journal ◽  
2019 ◽  
Vol 24 (04) ◽  
pp. 1667-1680 ◽  
Author(s):  
W. D. Richardson ◽  
F. F. Schoeggl ◽  
S. D. Taylor ◽  
B.. Maini ◽  
H. W. Yarranton

Summary The oil-production rate of in-situ heavy-oil-recovery processes involving the injection of gaseous hydrocarbons partly depends on the diffusivity of the gas in the bitumen. Data for gas diffusivities, particularly above ambient temperature, are relatively scarce because they are time consuming to measure. In this study, the diffusion and solubilities of gaseous methane, ethane, propane, and n-butane in a Western Canadian bitumen were measured from 40 to 90°C and pressures from 300 to 2300 kPa, using a pressure-decay method. The diffusivities were determined from a numerical model of the experiments that accounted for the swelling of the oil. In Part I of this study (Richardson et al. 2019), it was found that both constant and viscosity-dependent diffusivities could be used to model the mass of gas diffused and the gas-concentration profile in the bitumen; however, the constant diffusivity was different for each experiment and mainly depended on the oil viscosity. In this study, a correlation for the constant diffusivity to the oil viscosity is developed as a tool to quickly estimate the gas diffusivity. A correlation of diffusivity to the mixture viscosity is also developed for use in more-rigorous diffusion models. The maximum deviations in the mass diffused over time predicted with the constant and viscosity-dependent (mixture viscosity) correlations at each condition are on average 7.4 and 8.7%, respectively.

SPE Journal ◽  
2019 ◽  
Vol 24 (04) ◽  
pp. 1645-1666 ◽  
Author(s):  
W. D. Richardson ◽  
F. F. Schoeggl ◽  
B.. Maini ◽  
A.. Kantzas ◽  
S. D. Taylor ◽  
...  

Summary The oil-production rate of in-situ heavy-oil-recovery processes involving the injection of gaseous hydrocarbons partly depends on the diffusivity of the gas in the bitumen. The gas diffusivities required to model these processes are determined indirectly from models of mass-transfer experiments. However, the data in the literature are scattered partly because different methods and model assumptions are used in each case. In this work, the pressure-decay method is examined with a focus on accounting for swelling and the dependence of the diffusivity on the solvent content. To assess these issues, the diffusion of gaseous propane into bitumen is measured at conditions where significant swelling occurs. A numerical model is developed for the pressure-decay experiment that accounts for swelling (including excess volumes of mixing) and variable diffusivity. For gases, such as propane, with a relatively high solubility in bitumen, the error in the calculated diffusivity reached 25% when swelling was not included in the model. The error in the height of the gas/oil interface reached 15%. Nonideal mixing had no effect on the calculated diffusivity and only a small effect on the height of the interface. It was found that the diffusion data from a single experiment could be modeled equally well with a constant or a solvent-concentration-dependent (or viscosity-dependent) diffusivity. However, the apparent constant diffusivities for each experiment were different, confirming their dependence on the solvent content. The constant diffusivity approximately correlated to the viscosity of the oil. A larger data set is required to fully develop and test a correlation, and this work will be presented in Part II of this study (Richardson et al. 2019).


2021 ◽  
Vol 143 (7) ◽  
Author(s):  
Ali Alarbah ◽  
Ezeddin Shirif ◽  
Na Jia ◽  
Hamdi Bumraiwha

Abstract Chemical-assisted enhanced oil recovery (EOR) has recently received a great deal of attention as a means of improving the efficiency of oil recovery processes. Producing heavy oil is technically difficult due to its high viscosity and high asphaltene content; therefore, novel recovery techniques are frequently tested and developed. This study contributes to general progress in this area by synthesizing an acidic Ni-Mo-based liquid catalyst (LC) and employing it to improve heavy oil recovery from sand-pack columns for the first time. To understand the mechanisms responsible for improved recovery, the effect of the LC on oil viscosity, density, interfacial tension (IFT), and saturates, aromatics, resin, and asphaltenes (SARA) were assessed. The results show that heavy oil treated with an acidic Ni-Mo-based LC has reduced viscosity and density and that the IFT of oil–water decreased by 7.69 mN/m, from 24.80 mN/m to 17.11 mN/m. These results are specific to the LC employed. The results also indicate that the presence of the LC partially upgrades the structure and group composition of the heavy oil, and sand-pack flooding results show that the LC increased the heavy oil recovery factor by 60.50% of the original oil in place (OOIP). Together, these findings demonstrate that acidic Ni-Mo-based LCs are an effective form of chemical-enhanced EOR and should be considered for wider testing and/or commercial use.


SPE Journal ◽  
2019 ◽  
Vol 25 (01) ◽  
pp. 185-196 ◽  
Author(s):  
Ram R. Ratnakar ◽  
Birol Dindoruk

Summary Molecular diffusion plays a dominant role in various reservoir processes, especially in the absence of convective mixing. In general, gas diffusion in oils depends on several factors such as pressure, temperature, oil viscosity, and gas/oil ratio (GOR). Out of these factors, the effects of GOR and live-oil-compositional changes on diffusivity are rare or not available in the literature. The current work fills this gap and presents the experimental observations on the effect of GOR on gas diffusivity in reservoir-fluid systems. Synthetic live oils were created by combining stock-tank oil (STO) and methane in various ratios. Constant-composition-expansion (CCE) experiments were performed with these oils to obtain their bubblepoints and liquid densities in relation to GOR. Methane diffusivity in these oils was obtained from pressure-decay (PD) tests at high-pressure/high-temperature (HP/HT) conditions. The diffusion and solubility parameters were estimated from PD data using the diffusion model and integral-based linear regression presented in previous work (Ratnakar and Dindoruk 2015, 2018). The experimental and modeling methodologies are presented here in sufficient detail to allow readers to replicate and evaluate the results. In this work, we experimentally investigated the effect of GOR on methane diffusivity in oils at HP/HT conditions using PD tests. In particular, We present experimental data for bubblepoints and liquid density of synthetic oils with various GOR values. For the range of GORs considered, these measurements show that the bubblepoint pressure increases linearly with GOR. Late-transient solution (LTS) of the PD model was used to obtain diffusivity parameters by regressing against experimental data. It is found that as the GOR value increases (that is, when oil becomes lighter), the diffusivity value increases, which is in accordance with the Stokes-Einstein relation. Most importantly, an empirical correlation is developed on the basis of a limited data set to describe the variation in diffusivity values with GOR. This can be important when experimental data are available for the STO but not for the live oils. It can also be extremely useful in gas-injection processes where the amount of gas dissolved in the oil varies, leading to variations in diffusivity.


1972 ◽  
Vol 12 (02) ◽  
pp. 143-155 ◽  
Author(s):  
E.L. Claridge

Abstract A new correlation bas been developed for estimating oil recovery in unstable miscible five-spot pattern floods. It combines existing methods of predicting areal coverage and linear displacement efficiency and was used to calculate oil recovery for a series of assumed slug sizes in a live-spot CO2 slug-waterflood pilot test. The economic optimum slug size varies with CO2 cost; at anticipated CO2 costs the pilot would generate an attractive profit if performance is as predicted Introduction Selection of good field prospects for application of oil recovery processes other than waterflooding is often difficult. The principal reason is that other proposed displacing agents are far more costly proposed displacing agents are far more costly than water and usually sweep a lesser fraction of the volume of an oil reservoir (while displacing oil more efficiently from this fraction). Such agents must be used in limited amounts as compared with water; and this amount must achieve an appreciable additional oil recovery above waterflooding recovery. For these reasons, there is in general much less economic margin for engineering error in processes other than waterflooding. The general characteristics of the various types of supplemental recovery processes are well known, and adequate choices can be made of processes to be considered in more detail with respect to a given field. Comparative estimates must then be made of process performance and costs in order to narrow the choice. A much more detailed, definitive process-and-economic evaluation is eventually process-and-economic evaluation is eventually required of the chosen process before an executive decision can be made to commit large amounts of money to such projects. It is in the area between first choice and final engineering evaluation that this work applies. A areal cusping and vertical coning into producing wells. These effects can be seated by existing "desk-drawer" correlation which can confirm or deny the engineer's surmise that he has an appropriate match of recovery process and oil reservoir characteristics is of considerable value in determining when to undertake the costly and often manpower-consuming task of a definitive process-and-economic evaluation. process-and-economic evaluation. An examination of the nature of the developed crude oil resources in the U.S. indicates that the majority of the crude oil being produced is above 35 degrees API gravity and exists in reservoirs deeper than 4,000 ft. The combination of hydrostatic pressure on these oil reservoirs, the natural gas usually present in the crude oil in proportion to this pressure, the reservoir temperatures typically found, and the distribution of molecular sizes and types in the crude oil corresponding to the API gravity results in the fact that, in the majority of cases, the in-place crude oil viscosity was originally no more than twice that of water. A large proportion of these oil reservoirs have undergone pressure decline, gas evolution and consequent increase in crude oil viscosity. However, an appreciable proportion are still at such a pressure and proportion are still at such a pressure and temperature that miscibility can be readily attained with miscible drive agents such as propane or carbon dioxide, and the viscosity of the crude oil is such that the mobility of these miscible drive agents is no more than 50 time s that of the crude oil. Under these circumstances, a possible candidate situation for the miscible-drive type of process may exist. process may exist. Supposing that such a situation is under consideration, the next question is: what specific miscible drive process, and how should it be designed to operate? In some cases, the answer is clear: when the reservoir has a high degree of vertical communication (high permeability and continuity of the permeable, oil-bearing pore space in the vertical direction), then a gravity-stabilized miscible flood is the preferred mode of operation; and the particular drive agent or agents can be chosen on the basis of miscibility requirements, availability and cost. SPEJ P. 143


2006 ◽  
Vol 73 (4) ◽  
pp. 1239-1247 ◽  
Author(s):  
N. Youssef ◽  
D. R. Simpson ◽  
K. E. Duncan ◽  
M. J. McInerney ◽  
M. Folmsbee ◽  
...  

ABSTRACT Biosurfactant-mediated oil recovery may be an economic approach for recovery of significant amounts of oil entrapped in reservoirs, but evidence that biosurfactants can be produced in situ at concentrations needed to mobilize oil is lacking. We tested whether two Bacillus strains that produce lipopeptide biosurfactants can metabolize and produce their biosurfactants in an oil reservoir. Five wells that produce from the same Viola limestone formation were used. Two wells received an inoculum (a mixture of Bacillus strain RS-1 and Bacillus subtilis subsp. spizizenii NRRL B-23049) and nutrients (glucose, sodium nitrate, and trace metals), two wells received just nutrients, and one well received only formation water. Results showed in situ metabolism and biosurfactant production. The average concentration of lipopeptide biosurfactant in the produced fluids of the inoculated wells was about 90 mg/liter. This concentration is approximately nine times the minimum concentration required to mobilize entrapped oil from sandstone cores. Carbon dioxide, acetate, lactate, ethanol, and 2,3-butanediol were detected in the produced fluids of the inoculated wells. Only CO2 and ethanol were detected in the produced fluids of the nutrient-only-treated wells. Microbiological and molecular data showed that the microorganisms injected into the formation were retrieved in the produced fluids of the inoculated wells. We provide essential data for modeling microbial oil recovery processes in situ, including growth rates (0.06 � 0.01 h−1), carbon balances (107% � 34%), biosurfactant production rates (0.02 � 0.001 h−1), and biosurfactant yields (0.015 � 0.001 mol biosurfactant/mol glucose). The data demonstrate the technical feasibility of microbial processes for oil recovery.


2018 ◽  
Vol 40 (2) ◽  
pp. 85-90
Author(s):  
Yani Faozani Alli ◽  
Edward ML Tobing ◽  
Usman Usman

The formation of microemulsion in the injection of surfactant at chemical flooding is crucial for the effectiveness of injection. Microemulsion can be obtained either by mixing the surfactant and oil at the surface or injecting surfactant into the reservoir to form in situ microemulsion. Its translucent homogeneous mixtures of oil and water in the presence of surfactant is believed to displace the remaining oil in the reservoir. Previously, we showed the effect of microemulsion-based surfactant formulation to reduce the interfacial tension (IFT) of oil and water to the ultralow level that suffi cient enough to overcome the capillary pressure in the pore throat and mobilize the residual oil. However, the effectiveness of microemulsion flooding to enhance the oil recovery in the targeted representative core has not been investigated.In this article, the performance of microemulsion-based surfactant formulation to improve the oil recovery in the reservoir condition was investigated in the laboratory scale through the core flooding experiment. Microemulsion-based formulation consist of 2% surfactant A and 0.85% of alkaline sodium carbonate (Na2CO3) were prepared by mixing with synthetic soften brine (SSB) in the presence of various concentration of polymer for improving the mobility control. The viscosity of surfactant-polymer in the presence of alkaline (ASP) and polymer drive that used for chemical injection slug were measured. The tertiary oil recovery experiment was carried out using core flooding apparatus to study the ability of microemulsion-based formulation to recover the oil production. The results showed that polymer at 2200 ppm in the ASP mixtures can generate 12.16 cP solution which is twice higher than the oil viscosity to prevent the fi ngering occurrence. Whereas single polymer drive at 1300 ppm was able to produce 15.15 cP polymer solution due to the absence of alkaline. Core flooding experiment result with design injection of 0.15 PV ASP followed by 1.5 PV polymer showed that the additional oil recovery after waterflood can be obtained as high as 93.41% of remaining oil saturation after waterflood (Sor), or 57.71% of initial oil saturation (Soi). Those results conclude that the microemulsion-based surfactant flooding is the most effective mechanism to achieve the optimum oil recovery in the targeted reservoir.


2012 ◽  
Vol 502 ◽  
pp. 179-183
Author(s):  
Hong Jing Zhang ◽  
Shuang Bo Dong ◽  
Zhe Kui Zheng

Aiming at the source and corrosiveness of carbon dioxide, the in-situ carbon dioxide generation technology to enhance oil recovery was proposed。This paper presents the in-situ carbon dioxide generation technology mechanism, the expansion, viscosity reduction; oil-displacement efficiency and foamy oil of this technology were experimentally evaluated by using microscopic models and physical models. The experimental results indicated that the in-situ carbon dioxide generation technology could be used to produce enough carbon dioxide and get good efficiencies of oil expansion, reduction of viscosity and enhancement of oil displacement. Under the conditions of 2010mPa•s in oil viscosity, 60°C and 10MPa, the volume of oil could be expanded by25%, and the viscosity of oil can reduced to 52.7% , and the CO2 can displacement,restraining viscous fingering and changing liquid flow direction and carrying the residual oil.


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