A New Approach Utilizing Liquid Catalyst for Improving Heavy Oil Recovery

2021 ◽  
Vol 143 (7) ◽  
Author(s):  
Ali Alarbah ◽  
Ezeddin Shirif ◽  
Na Jia ◽  
Hamdi Bumraiwha

Abstract Chemical-assisted enhanced oil recovery (EOR) has recently received a great deal of attention as a means of improving the efficiency of oil recovery processes. Producing heavy oil is technically difficult due to its high viscosity and high asphaltene content; therefore, novel recovery techniques are frequently tested and developed. This study contributes to general progress in this area by synthesizing an acidic Ni-Mo-based liquid catalyst (LC) and employing it to improve heavy oil recovery from sand-pack columns for the first time. To understand the mechanisms responsible for improved recovery, the effect of the LC on oil viscosity, density, interfacial tension (IFT), and saturates, aromatics, resin, and asphaltenes (SARA) were assessed. The results show that heavy oil treated with an acidic Ni-Mo-based LC has reduced viscosity and density and that the IFT of oil–water decreased by 7.69 mN/m, from 24.80 mN/m to 17.11 mN/m. These results are specific to the LC employed. The results also indicate that the presence of the LC partially upgrades the structure and group composition of the heavy oil, and sand-pack flooding results show that the LC increased the heavy oil recovery factor by 60.50% of the original oil in place (OOIP). Together, these findings demonstrate that acidic Ni-Mo-based LCs are an effective form of chemical-enhanced EOR and should be considered for wider testing and/or commercial use.

2012 ◽  
Vol 268-270 ◽  
pp. 547-550
Author(s):  
Qing Wang Liu ◽  
Xin Wang ◽  
Zhen Zhong Fan ◽  
Jiao Wang ◽  
Rui Gao ◽  
...  

Liaohe oil field block 58 for Huancai, the efficiency of production of thickened oil is low, and the efficiency of displacement is worse, likely to cause other issues. Researching and developing an type of Heavy Oil Viscosity Reducer for exploiting. The high viscosity of W/O emulsion changed into low viscosity O/W emulsion to facilitate recovery, enhanced oil recovery. Through the experiment determine the viscosity properties of Heavy Oil Viscosity Reducer. The oil/water interfacial tension is lower than 0.0031mN•m-1, salt-resisting is good. The efficiency of viscosity reduction is higher than 90%, and also good at 180°C.


2013 ◽  
Vol 2013 ◽  
pp. 1-8 ◽  
Author(s):  
Yong Du ◽  
Guicai Zhang ◽  
Jijiang Ge ◽  
Guanghui Li ◽  
Anzhou Feng

Oil viscosity was studied as an important factor for alkaline flooding based on the mechanism of “water drops” flow. Alkaline flooding for two oil samples with different viscosities but similar acid numbers was compared. Besides, series flooding tests for the same oil sample were conducted at different temperatures and permeabilities. The results of flooding tests indicated that a high tertiary oil recovery could be achieved only in the low-permeability (approximately 500 mD) sandpacks for the low-viscosity heavy oil (Zhuangxi, 390 mPa·s); however, the high-viscosity heavy oil (Chenzhuang, 3450 mPa·s) performed well in both the low- and medium-permeability (approximately 1000 mD) sandpacks. In addition, the results of flooding tests for the same oil at different temperatures also indicated that the oil viscosity put a similar effect on alkaline flooding. Therefore, oil with a high-viscosity is favorable for alkaline flooding. The microscopic flooding test indicated that the water drops produced during alkaline flooding for oils with different viscosities differed significantly in their sizes, which might influence the flow behaviors and therefore the sweep efficiencies of alkaline fluids. This study provides an evidence for the feasibility of the development of high-viscosity heavy oil using alkaline flooding.


Energies ◽  
2020 ◽  
Vol 13 (21) ◽  
pp. 5735
Author(s):  
Ali Telmadarreie ◽  
Japan J Trivedi

Enhanced oil recovery (EOR) from heavy oil reservoirs is challenging. High oil viscosity, high mobility ratio, inadequate sweep, and reservoir heterogeneity adds more challenges and severe difficulties during any EOR method. Foam injection showed potential as an EOR method for challenging and heterogeneous reservoirs containing light oil. However, the foams and especially polymer enhanced foams (PEF) for heavy oil recovery have been less studied. This study aims to evaluate the performance of CO2 foam and CO2 PEF for heavy oil recovery and CO2 storage by analyzing flow through porous media pressure profile, oil recovery, and CO2 gas production. Foam bulk stability tests showed higher stability of PEF compared to that of surfactant-based foam both in the absence and presence of heavy crude oil. The addition of polymer to surfactant-based foam significantly improved its dynamic stability during foam flow experiments. CO2 PEF propagated faster with higher apparent viscosity and resulted in more oil recovery compared to that of CO2 foam injection. The visual observation of glass column demonstrated stable frontal displacement and higher sweep efficiency of PEF compared to that of conventional foam. In the fractured rock sample, additional heavy oil recovery was obtained by liquid diversion into the matrix area rather than gas diversion. Aside from oil production, the higher stability of PEF resulted in more gas storage compared to conventional foam. This study shows that CO2 PEF could significantly improve heavy oil recovery and CO2 storage.


2006 ◽  
Vol 9 (02) ◽  
pp. 154-164 ◽  
Author(s):  
Mingzhe Dong ◽  
S.-S. Sam Huang ◽  
Keith Hutchence

Summary The methane pressure-cycling (MPC) process is an enhanced-oil-recovery (EOR) scheme intended for application in some heavy-oil reservoirs after termination of either primary or waterflood production. The essence of the process is the restoration of the solution-gas-drive mechanism. The restoration is accomplished by reinjecting an appropriate amount of solution gas (mainly methane) and then repressuring the gas back into solution by injecting water until approximate original reservoir pressure is reached. This, aside from the replacement of produced oil by water, recreates the primary-production conditions. This novel recovery technique is being developed to target the considerable portion of heavy-oil resources located in thin reservoirs. Primary and secondary methods have managed to recover at best 10% of the initial oil in place (IOIP). Heat losses to overburden and underburden or bottomwater zones make thermal methods unsuitable for thin reservoirs. Sandpack-flood tests in 30.5-cm (length) × 5.0-cm (diameter) sandpacks were carried out for oils with a range of dead-oil viscosities from 1700 to 5400 mPa.s. The results showed that the pressure-cycling process could create a favorable condition for recharged gas to contact the remaining oil in reservoirs. This restores the situation whereby substantial amounts of gas are in solution for further "primary" production. The effects on the efficiency of the MPC process of cycle termination strategy, oil viscosity, and mobile-water saturation were investigated. Simulations were conducted to investigate the MPC process in three heavy-oil reservoirs in Saskatchewan, Canada. The effects on the process of infill wells, oil viscosity, gas-injection rate, and the presence of wormholes in reservoirs were studied. Introduction Heavy oil in thick-pay reservoirs (i.e., >10 m) is commonly produced with thermal-recovery methods. These methods (steam injection and its variants) are generally not suitable for thin reservoirs because of heat losses to overburden and underburden or bottomwater zones (Fairfield and White 1982; Dyer et al. 1994). The world's large untapped oil resource remaining after recovery by conventional technology offers potential for exploitation by a suitably developed tertiary-recovery technique. For example, Saskatchewan accounts for 62% of Canada's total heavy-oil resources (Bowers and Drummond 1997), including 1.7 billion m3 of proved reserves and 3.7 billion m3 of probable reserves (Saskatchewan Energy and Mines 1998). Of the province's proven initial heavy oil in place, 97% is contained in reservoirs where the pay zone is less than 10 m, and 55% in reservoirs with a pay zone less than 5 m thick (Huang et al. 1987; Srivastava et al. 1993). Primary and secondary methods combined recover, on average, only about 7% of the proven IOIP (Saskatchewan Energy and Mines 1998). The incentive is strong for the development of appropriate EOR techniques that will maximize the recovery potential of and profitability from these thin heavy-oil reservoirs. Extensive literature is available on CO2, flue gas, and produced-gas injection for heavy-oil recovery, including slug displacement, water alternating gas (WAG), and cyclic (huff ‘n’ puff) processes (Huang et al. 1987; Srivastava et al. 1993, 1994, 1999; Srivastava and Huang 1997; Ma and Youngren 1994; Issever et al. 1993; Olenick et al. 1992). A comparative study of the oil-recovery behavior for a 14.1°API heavy oil with different injection gases (CO2, flue gas, and produced gas) showed that CO2 was the best-suited gas for EOR of heavy oils (Srivastava et al. 1999). Cyclic CO2 injection for heavy-oil recovery was tested in the field, and field case histories indicated that oil production was enhanced (Olenick et al. 1992). However, natural CO2 sources are not available to most oil reservoirs. The cost of CO2 capture from flue gas and other sources may range from U.S. $25 to $70/ton (Padamsey and Railton 1993). Produced gas is available in large quantities at a much lower cost. With this consideration, produced gas can be an economically effective agent for heavy-oil recovery by the cyclic-injection process.


2018 ◽  
Vol 80 ◽  
pp. 264-271 ◽  
Author(s):  
J.M. Martínez-Magadán ◽  
A.R. Cartas-Rosado ◽  
R. Oviedo-Roa ◽  
R. Cisneros-Dévora ◽  
M. Pons-Jiménez ◽  
...  

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