Formation water saturation is a critical target property for any comprehensive well log analysis program. Most techniques for computing saturation depend heavily on an analyst’s ability to accurately model resistivity measurements for the effects of formation water resistivity and rock texture. However, the pre-requisite knowledge of formation water properties, particularly salinity, is often either unknown, varying with depth or lateral extent, or is difficult to derive from traditional methods. A high degree of variability may be present due to fluid migration from production, water injection, or various geological mechanisms. In unconventional reservoirs, the complexity of the rocks and pore structure further complicates traditional interpretation of the available well logs. These factors introduce significant uncertainties in the computed fluid saturations and therefore can substantially affect final reserves estimates. A novel technique in geochemical spectroscopy has recently been introduced to distinguish the chlorine signals of the formation and borehole. The new, quantitative measurement of formation chlorine enables a direct calculation of bulk water volume for a given formation water salinity. When integrated into a multi-physics log analysis workflow, the chlorine-derived water volume can provide critical information on fluid saturations, hydrocarbon-in-place, and producibility indicators. This additional information is especially useful for characterizing challenging and complex unconventional reservoirs. We present the new technique through several full petrophysical evaluation case studies in organic shale formations across the U.S., including the Midland, Delaware, Marcellus, and DJ basins. We solve for formation-specific water salinity and bulk water volume through an optimization that combines chlorine concentration with resistivity and dielectric measurements. These outputs are integrated into comprehensive petrophysical evaluations, leveraging a suite of advanced well log measurements to compute final fluid and rock properties and volumetrics. The evaluations include geochemical mineralogy logs, 2D NMR analyses, dielectric dispersion analyses, basic log measurements, and multi-mineral models. The results underscore the utility of the new spectroscopy chlorine log to reduce petrophysical model uncertainties in an integrated workflow. While this workflow has been demonstrated here in several U.S. organic shale case studies, the fundamental challenges it addresses will make it a valuable solution for a range of unconventional reservoirs globally.
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