Seawater Fracturing Fluid Development Challenges: A Comparison Between Seawater-Based and Freshwater-Based Fracturing Fluids Using Two Types of Guar Gum Polymers

Author(s):  
Maryam Alohaly ◽  
Ahmed BinGhanim ◽  
Raed Rahal ◽  
Sabiq Rahim
Energies ◽  
2021 ◽  
Vol 14 (6) ◽  
pp. 1783
Author(s):  
Klaudia Wilk-Zajdel ◽  
Piotr Kasza ◽  
Mateusz Masłowski

In the case of fracturing of the reservoirs using fracturing fluids, the size of damage to the proppant conductivity caused by treatment fluids is significant, which greatly influence the effective execution of hydraulic fracturing operations. The fracturing fluid should be characterized by the minimum damage to the conductivity of a fracture filled with proppant. A laboratory research procedure has been developed to study the damage effect caused by foamed and non-foamed fracturing fluids in the fractures filled with proppant material. The paper discusses the results for high quality foamed guar-based linear gels, which is an innovative aspect of the work compared to the non-foamed frac described in most of the studies and simulations. The tests were performed for the fracturing fluid based on a linear polymer (HPG—hydroxypropyl guar, in liquid and powder form). The rheology of nitrogen foamed-based fracturing fluids (FF) with a quality of 70% was investigated. The quartz sand and ceramic light proppant LCP proppant was placed between two Ohio sandstone rock slabs and subjected to a given compressive stress of 4000–6000 psi, at a temperature of 60 °C for 5 h. A significant reduction in damage to the quartz proppant was observed for the foamed fluid compared to that damaged by the 7.5 L/m3 natural polymer-based non-foamed linear fluid. The damage was 72.3% for the non-foamed fluid and 31.5% for the 70% foamed fluid, which are superior to the guar gum non-foamed fracturing fluid system. For tests based on a polymer concentration of 4.88 g/L, the damage to the fracture conductivity by the non-foamed fluid was 64.8%, and 26.3% for the foamed fluid. These results lead to the conclusion that foamed fluids could damage the fracture filled with proppant much less during hydraulic fracturing treatment. At the same time, when using foamed fluids, the viscosity coefficient increases a few times compared to the use of non-foamed fluids, which is necessary for proppant carrying capacities and properly conducted stimulation treatment. The research results can be beneficial for optimizing the type and performance of fracturing fluid for hydraulic fracturing in tight gas formations.


RSC Advances ◽  
2017 ◽  
Vol 7 (84) ◽  
pp. 53290-53300 ◽  
Author(s):  
Haiming Fan ◽  
Zheng Gong ◽  
Zhiyi Wei ◽  
Haolin Chen ◽  
Haijian Fan ◽  
...  

A facile procedure has been proposed to evaluate the temperature–resistance performance of fracturing fluids, which was used to understand the temperature–tolerance performance of a borate cross-linked hydroxypropyl guar gum fracturing fluid.


Energies ◽  
2019 ◽  
Vol 12 (23) ◽  
pp. 4465
Author(s):  
Klaudia Wilk

The use of water-based fracturing fluids during fracturing treatment can be a problem in water-sensitive formations due to the permeability damage hazard caused by clay minerals swelling. The article includes laboratory tests, analyses and simulations for nitrogen foamed fracturing fluids. The rheology and filtration coefficients of foamed fracturing fluids were examined and compared to the properties of conventional water-based fracturing fluid. Laboratory results provided the input for numerical simulation of the fractures geometry for water-based fracturing fluids and 50% N2 foamed fluids, with addition of natural, fast hydrating guar gum. The results show that the foamed fluids were able to create shorter and thinner fractures compared to the fractures induced by the non-foamed fluid. The simulation proved that the concentration of proppant in the fracture and its conductivity are similar or slightly higher when using the foamed fluid. The foamed fluids, when injected to the reservoir, provide additional energy that allows for more effective flowback, and maintain the proper fracture geometry and proppant placing. The results of laboratory work in combination with the 3D simulation showed that the foamed fluids have suitable viscosity which allows opening the fracture, and transport the proppant into the fracture, providing successful fracturing operation. The analysis of laboratory data and the performed computer simulations indicated that fracturing fluids foamed by nitrogen are a good alternative to non-foamed fluids. The N2-foamed fluids exhibit good rheological parameters and proppant-carrying capacity. Simulated fracture of water-based fracturing fluid is slightly longer and higher compared to foamed fluid. At the same time, when using a fluid with a gas additive, the water content in fracturing fluid is reduced which means the minimization of the negative results of the clay minerals swelling.


2021 ◽  
Vol 2076 (1) ◽  
pp. 012039
Author(s):  
Ke Xu ◽  
Yongjun Lu ◽  
Jin Chang ◽  
Yang Li

Abstract China has made significant progress in the efficient exploration and development of deep-seated oil and gas wells. Reservoir reformation, as the core tool of high-temperature deep-seated exploration and development, puts forward a strong demand for fracturing fluids. The ultra-high temperature fracturing fluid system developed in my country is mainly divided into two types: ultra-high temperature guar gum fracturing fluid and ultra-high temperature synthetic polyacrylamide fracturing fluid. The high temperature resistant fracturing fluid system is mainly composed of high temperature resistant thickener, high temperature resistant crosslinking agent and temperature stabilizing additives and other additives. Based on indoor research and a large amount of literature, this article summarizes the research and application of high temperature resistant fracturing fluid system, high temperature resistant thickener, high temperature resistant crosslinking agent and temperature stabilizing additives in my country in recent years, and pointed out the shortcomings and limitations of the high-temperature fracturing fluid, the technical direction of the development of high-temperature resistant fracturing fluid technology is proposed.


2021 ◽  
Author(s):  
Kaiyu Zhang ◽  
Jirui Hou ◽  
Zhuojing Li

Abstract The low and ultra-low permeability reservoirs in China, such as the Changqing, Jidong, and Daqing peripheral oil fields, often apply CO2 as a flooding medium to enhance oil recovery. A serial of water-rock interactions will be occurred among the CO2, formation rock, and formation water under the HT/HP conditions. The pH value of the formation will be converted to acidity accordingly. As a side effect, the traditional guar-based fracturing fluids in an alkaline range, such as the borate cross-linked hydroxypropyl guar gum (HPG), cannot result in an effective hydrofracturing operation due to the incompatibility. Consequently, developing an acidic fracturing fluid system with a satisfactory performance is an imperative. Acidic fracturing fluids, such as the zirconium cross-linked carboxymethyl hydroxypropyl guar gum (CMHPG), can protect the formation during the hydrofracturing process from the damage arising from the swelling and migration of the clay particles. However, the shortcomings of the uncontrollable viscosity growth and the irreversible shear-thinning behavior limit the large-scale use of the acidic fracturing fluids. In this work, a novel organic zirconium cross-linker synthesized in the laboratory was applied to control and delay the cross-link reaction under the acidic condition. The ligands coordinated to the zirconium center were the L-lactate and ethylene glycol. The thickener used was the CMHPG at a low loading of 0.3% (approximately 25 pptg). Meanwhile, the surface functionalized metallic phase (1T-phase) molybdenum disulfide (MoS2) nanosheets were employed to improve the rheological performance of the zirconium cross-linked CMHPG fracturing fluid. The modification reagent utilized was the L-cysteine. The morphology, structure, and property of the fabricated functionalized 1T-MoS2 (Cys-1T-MoS2) nanosheets were systematically characterized using the transmission electron microscopy (TEM), scanning electron microscopy (SEM), Raman spectroscopy, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Fourier transform infrared spectroscopy (FTIR), and thermogravimetric analysis (TGA) measurements. The results of the characterization tests demonstrated a successful functionalization of the 1T-MoS2 nanosheets with L-cysteine. Then, the effects of this new nanosheet-enhanced zirconium cross-linked CMHPG fracturing fluid systems with different cross-linker and nanosheet loadings on gelation performance were systematically assessed employing the Sydansk bottle testing method combined with a rheometer under the controlled-stress or controlled-rate modes. The results indicated that the nanosheet-enhanced fracturing fluid had a desirable delayed property. Compared with the blank fracturing fluid (without nanosheets), the nanosheet-enhanced fracturing fluid had a much better shear-tolerant and shear-recovery performance.


1985 ◽  
Vol 25 (05) ◽  
pp. 623-628 ◽  
Author(s):  
C.C. LaGrone ◽  
S.A. Baumgartner ◽  
R.A. Woodroof

Abstract Reservoirs with bottomhole temperatures (BHT's) in excess of 250 deg. F [121 deg. C] and permeabilities of less than 1.0 md are commonly encountered in drilling and completing geothermal and deep gas wells. Successful stimulation of these wells often requires the use of massive hydraulic fracturing (MHF) treatments. Fracturing fluids chosen for these large treatments must possess shear and thermal stability at high BHT'S. The use of conventional fracturing fluids has been limited traditionally to wells with BHT's of 250 deg. F [121 deg. C] or less. Above 250 deg. F [121 deg. C], high polymer concentrations and/or large fluid volumes are required to maintain effective fluid viscosities in the fracture. However, high polymer concentrations lead to high friction pressures, high costs, and high gel residue levels. The large fluid volumes also increase significantly the cost of the treatment. Greater understanding of fracturing fluid properties has led to the development of a crosslinked fracturing fluid designed specifically for wells with BHT's above 250 deg F [121 deg C). The specialized chemistry of this fluid combines a high-ph hydroxypropyl guar gum (HPG) solution with a high-temperature gel stabilizer and a proprietary crosslinker. The fluid remains stable at 250 to proprietary crosslinker. The fluid remains stable at 250 to 350 deg. F [121 to 177 deg. C] for extended periods of time under shear. This paper describes the rheologial evaluations used in the systematic development of this fracturing fluid. In field applications, this fracturing fluid has been used to stimulate successfully wells with BHT's ranging from 250 to 540 deg. F [121 to 282 deg C). Case histories that include pretreatment and posttreatment production data are presented. Introduction Temperatures exceeding 250 deg F [121 deg C) and permeabilities less than 1.0 md are frequently encountered in permeabilities less than 1.0 md are frequently encountered in deep gas and geothermal wells. Successful economic completion of these wells requires that long, conductive fractures with optimal proppant distribution be created. Ultimately, the amount of production from these formations depends on the propped fracture length created. One successful stimulation technique used to create these long fractures is MHF. In these treatments, the fracturing fluids are often exposed to shear in the fracture for prolonged periods of time at high temperatures. Thus the fracturing fluids must exhibit extended shear and thermal stability at the high BHT'S. In addition, the fracturing fluid must not leak off rapidly into the formation, or the fracture may not be extended to the desired length. Many early treatments were limited by fracturing fluids that lost viscosity rapidly at high BHT's because of excessive thermal and/or shear degradation. Creation of a narrow fracture width, excessive fluid loss to the formation, and insufficient proppant transport resulted from the use of these low viscosity fluids. The solution to conventional fracturing fluid deficiencies was to develop a more efficient fracturing fluid (low polymer concentrations) with greater viscosity retention under shear at high temperatures, better fluid-loss control, and lower friction pressures. Generally, the components that make up crosslinked fracturing fluids include a polymer, buffer, gel stabilizer, and crosslinker. Each of these components is critical to the development of the desired fracturing fluid properties. The role of polymers in fracturing fluids is to properties. The role of polymers in fracturing fluids is to provide fracture width, to suspend proppants, to help provide fracture width, to suspend proppants, to help control fluid loss to the formation, and to reduce friction pressure in the tubular goods. Guar gum and cellulosic pressure in the tubular goods. Guar gum and cellulosic derivatives are the most common types of polymers used in fracturing fluids. The cellulosic derivatives are residue-free and thus help minimize fracturing fluid damage to the formation. However, the cellulosic derivatives are difficult to disperse because of their rapid rate of hydration. Guar gum and its derivatives are easily dispersed but produce some residue when broken. Buffers are used in conjunction with polymers so that the optimal pH for polymer hydration can be attained. When the optimal pH is reached, the maximal viscosity yield from the polymer is more likely to be obtained. The most common example of fracturing fluid buffers is a weak-acid/weak-base blend, whose ratios can be adjusted to that the desired ph is reached. However, some of these buffers dissolve slowly, particularly at cooler temperatures. Gel stabilizers are added to polymer solutions to inhibit chemical degradation. Examples of gel stabilizers used in fracturing fluids include methanol and various inorganic sulfur compounds. Other stabilizers are useful in inhibiting the chemical degradation process, but many interfere with the mechanism of crosslinking. The sulfur containing stabilizers possess an advantage over methanol, which is flammable, toxic, and expensive. SPEJ P. 623


2021 ◽  
Author(s):  
Amro Othman ◽  
Murtada Saleh Aljawad ◽  
Muhammad Shahzad Kamal ◽  
Mohamed Mahmoud ◽  
Shirish Patil

Abstract Due to the scarcity and high cost of freshwater, especially in the Gulf region, utilization of seawater as a fracturing fluid gained noticeable interest. However, seawater contains high total dissolved solids (TDS) that may damage the formation and degrade the performance of the fracturing fluids. Numerous additives are required to reduce the damaging effect and improve the viscosity resulting in an expensive and non-eco-friendly fracturing fluid system. Chelating agents, which are environmentally benign, are proposed in this study as the replacement of many additives for seawater fracturing fluids. This study focuses on optimizing chelating agents to achieve high viscosity employing the standard industry rheometers. Carboxymethyl Hydroxypropyl Guar Gum (CMHPG) polymer, which is effective in hydraulic fracturing, was used in this research with 0.5 and 1.0 wt% in deionized water (DW) as well as seawater (SW). It was first tested as a standalone additive at different conditions to provide a benchmark then combined with different concentrations, and pH level chelating agents. In this study the hydration test was conducted through different conditions. It was observed that CMHPG, when tested as a standalone additive, provided slightly higher viscosity in SW compared to DW. Also, increasing polymer concentration from 0.5 to 1.0 wt% provided three folds of viscosity. The viscosity did not show time dependence behavior at room temperature for the aforementioned experiments where all hydration tests were run at 511 1/s shear rate. Temperature, however, had a significant impact on both viscosity magnitude and behavior. At 70 °C, the fluid viscosity increased with time where low viscosity was achieved early on but kept increasing with shearing time. Similarly, high pH chelating agents provided time dependant viscosity behavior when mixed with CMHPG. This behavior is important as low viscosity is favorable during pumping but high viscosity when the fluids hit the formation. The study investigates the possibility of utilizing chelating agents with seawater to replace numerous additives. It acts as a crosslinker at early shearing times, where a gradual increase in viscosity was observed and a breaker in the reservoir harsh conditions. It also captures the divalent ions that are common in seawater, which replaces the need for scale inhibitors. The viscosity increase behavior can be controlled by adjusting the pH level, which could be desirable during operations.


2018 ◽  
Vol 140 (7) ◽  
Author(s):  
Tiankui Guo ◽  
Facheng Gong ◽  
Xin Lin ◽  
Qiang Lin ◽  
Xiaozhi Wang

The damage mechanism of fracturing fluids has always been the hot research topic in the development of low-permeability reservoir with hydraulic fracturing. At present, the research in this area is conducted mostly by the conventional core fluid flow test designed with industrial standards, less in the experiment operated from a microperspective. Against the reservoir cores with different permeability, and based on the results of SEM, mercury injection experiment, and core fluid flow test, this paper uses the technology of nuclear magnetic resonance (NMR) to systematically analyze the degree and rule of water-sensitivity, water-block, and solid-phase adsorption damage resulted from hydroxypropyl guar gum (HPG) and carboxymethyl guar gum (CMG) fracturing fluids, and proposes a comprehensive test method for evaluating the fracturing fluids damage to the reservoir. The test results show that fracturing fluid infiltrating into the core causes the increase of bound water, mobile water retention, and solid-phase macromolecule substance absorption inside the core in varying degrees, decreasing the reservoir permeability. The extent of reservoir water-sensitivity damage is positively correlated with the increment of bound water, and the extent of water-block damage is positively correlated with mobile water retention volume. The adsorption and retention of solid-phase macromolecule substance causes largest loss of core permeability, averaging about 20%, and it is main damage factor of fracturing fluids, the water-sensitivity damage causes 11% of core permeability loss, and the water-block damage causes 7% of loss. As the reservoir permeability doubles, the comprehensive damage resulted from guar gum fracturing fluid decreases by 14%. The comprehensive damage of CMG fracturing fluid to reservoir is 6.6% lower than that of HPG fracturing fluid, and the lower the reservoir permeability, the larger the gap between damage of CMG and HPG fracturing fluids. With the technology of NMR, the objective and accurate evaluation of various damages to reservoir resulted from fracturing fluids is realized, and the corresponding relation between damage mechanism and damage extent is established, which provides reference for research on improvement of fracturing fluid properties and reservoir protection measures.


PLoS ONE ◽  
2021 ◽  
Vol 16 (3) ◽  
pp. e0247948
Author(s):  
Shiliang Xu ◽  
Mengke Cui ◽  
Renjie Chen ◽  
Qiaoqing Qiu ◽  
Jiacai Xie ◽  
...  

With the increasing demand for energy, fracturing technology is widely used in oilfield operations over the last decades. Typically, fracturing fluids contain various additives such as cross linkers, thickeners and proppants, and so forth, which makes it possess the properties of considerably complicated components and difficult processing procedure. There are still some difficult points needing to be explored and resolved in the hydroxypropyl guar gum (HPG) removal process, e.g., high viscosity and removal of macromolecular organic compounds. Our works provided a facile and economical HPG removal technology for fracturing fluids by designing a series of processes including gel-breaking, coagulation and precipitation according to the diffusion double layer theory. After this treatment process, the fracturing fluid can meet the requirements of reinjection, and the whole process was environment friendly without secondary pollution characteristics. In this work, the fracturing fluid were characterized by scanning electron microscopy (SEM), Energy dispersive X-ray (EDX), X-ray diffraction (XRD) and Fourier transformed infrared (FTIR) spectroscopy technologies, etc. Further, the micro-stabilization and destabilization mechanisms of HPG in fracturing fluid were carefully investigated. This study maybe opens up new perspective for HPG removal technologies, exhibiting a low cost and strong applicability in both fundamental research and practical applications.


2016 ◽  
Vol 6 (1) ◽  
pp. 31 ◽  
Author(s):  
Dayanand Saini ◽  
Timea Mezei

 Even though water consumption per hydraulic fracturing (or fracturing) job is relatively low; nearly all of the fresh water used for fracturing in California is in the regions of high water stress such as San Jouquin and Los Angeles Basins. However, water availability should not be a concern as huge volumes of water are being produced along with oil and gas from conventional formations (i.e. associated water) in the Kern County of California, a region where most of the fracturing activities take place. This associated water can potentially be used for preparing fracturing fluids in stimulating the unconventional formations. The present study reports on the relevant investigation done in this area of interest.The results suggest that associated water chemistry has limited effect on the viscosity of cross-linked formulations. However, guar gum concentration was found to affect the breaking behaviors of cross-linked fracturing fluid formulations. The new type of commercially available biodegradable breaker was found to be effective in breaking the tested cross-linked formulations at elevated temperature which was as high as 85°C (185°F). Both crosslinking and breaking behaviors of fracturing fluid formulations evaluated in this study were found comparable to the behaviors of commonly used cross-linked formulation (guar gum + 2% potassium chloride). These results suggest that both the associated water (i.e. water resulting from regional conventional oil production activites) and sea water (offshore oil fields) could serve as alternative sources of base fluid for use in fracturing jobs without putting significant burden on precious regional fresh water resources.


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