Experimental and Theoretical Study of Water and Solute Transport in Organic-Rich Carbonate Mudrocks

SPE Journal ◽  
2017 ◽  
Vol 23 (03) ◽  
pp. 704-718 ◽  
Author(s):  
A.. Padin ◽  
M. A. Torcuk ◽  
D.. Katsuki ◽  
H.. Kazemi ◽  
A. N. Tutuncu
Keyword(s):  
Mathematical Model ◽  
Mass Transport ◽  
Solute Transport ◽  
Osmotic Pressure ◽  
High Salinity ◽  
Pore Network ◽  
Low Salinity ◽  
The Core ◽  
Core Samples ◽  
Water And Solute Transport

Summary The objective of this research is to determine the physicochemical processes underlying water and solute transport in organic-rich source rocks. To achieve this goal, a custom-designed experimental apparatus was constructed to conduct flow tests, founded on a high-pressure triaxial assembly. The apparatus is capable of maintaining core samples at reservoir pressure, temperature, and confining stress. We conducted several 120-day low-salinity osmotic tests in low-clay, organic-rich Eagle Ford carbonate-shale samples. Test results showed gradual, slow increase of pressure within the samples. Because this pressure behavior could not be explained properly with classical models, we formulated a mass-transport mathematical model that relies on fundamental chemical osmosis principles driving low-salinity brine into high-salinity core samples. Our mathematical model was articulated to simulate flow into the core as a 3D porous medium rather than transport across a thin, molecule-selective membrane. The model is dependent on the following principles: The low-salinity brine selectively enters the pores by diffusion mass transport, and the pre-existing, ionized dissolved salt molecules within the core are restrained by internal electrostatic forces to counterdiffuse in the direction opposite to that of the low-salinity-brine molecules entering the pore network. Critical model input data, such as permeability, porosity, and rock compressibility, were obtained from flow experiments on twin cores, and the diffusion coefficient was chosen by history matching. The strengths of the numerical simulation include reliance on mass-transport fundamental principles; not requiring the use of an ambiguously defined membrane-efficiency term; and relying on chemical-potential gradient as the driving force for the low-salinity brine to enter the high-salinity core, generating osmotic pressure within the pore network. The latter implies that osmotic pressure is the consequence of water entering the cores, not the cause. Results of this research have provided a more plausible explanation of pore-scale mass transport in organic-rich shales, and provide useful insights for design of effective enhanced-oil-recovery (EOR) processes.

Profiles of water and solute transport along long-loop descending limb: analysis by mathematical model

1987 ◽  
Vol 252 (3) ◽  
pp. F393-F402 ◽  
Author(s):  
J. Taniguchi ◽  
K. Tabei ◽  
M. Imai
Keyword(s):  
Mathematical Model ◽  
Solute Transport ◽  
Mass Flow Rate ◽  
Mass Flow ◽  
Flow Rate ◽  
Species Difference ◽  
Transport Processes ◽  
Similar Amount ◽  
Sodium Potassium ◽  
Water And Solute Transport

We simulated profiles of water and solute transport along the descending limb of the long-loop nephron by a mathematical model based on mass balance equations for water, sodium, potassium, and urea, using phenomenological coefficients reported for hamsters. We assumed that interstitial concentration of sodium, potassium, and urea increased linearly along the descending limb from 150 to 350, from 5 to 50, and from 5 to 300 mM, respectively. Under this condition an increase in osmolality at the end-descending limb was mainly accounted for by the absorption of water. Considerable amounts of potassium and urea were secreted along the descending limb. Sodium was reabsorbed rather than secreted along the descending limb by both diffusion and solvent drag. The secreted amounts of urea and potassium were comparable to those observed by micropuncture studies. The sodium concentration in the lumen was higher than in the interstitium, with the transmural sodium gradient being 15 meq/liter at the hairpin turn. The potassium mass flow rate at the end-descending limb increased by 2.4 times. Large variations in potassium concentration of the delivered fluid scarcely changed the potassium mass flow rate at the end-descending limb. The secretion of urea and potassium and the reabsorption of sodium were increased as a function of delivered flow rate. An increase in corticomedullary urea gradient decreased the net potassium secretion along the descending limb. When the transport parameters for rabbits were used, both reabsorption of sodium and addition of urea were decreased, but a similar amount of potassium was secreted. These analyses indicate that the mathematical model that takes the species difference and internephron heterogeneity into consideration is useful in illustrating the transport processes along the descending limb of Henle's loop under various physiological and pathophysiological conditions.

scholarly journals A Comparative Study on Low and High Salinity Tolerance of Two Strains of Pinctada fucata

2021 ◽  
Vol 8 ◽  
Author(s):  
Jing Sun ◽  
Mingqiang Chen ◽  
Zhengyi Fu ◽  
Jingru Yang ◽  
Shengjie Zhou ◽  
...  
Keyword(s):  
Osmotic Pressure ◽  
Salinity Stress ◽  
Salinity Tolerance ◽  
High Salinity ◽  
Pinctada Fucata ◽  
Ion Concentration ◽  
Environmental Salinity ◽  
Low Salinity ◽  
Inorganic Ion ◽  
Ldh Activity

This study compares salinity tolerance between red and black shell Pinctada fucata salinity stress of 20 and 50‰, while 35‰ was used as a control. The hemolymph osmotic pressure, inorganic ion concentration, the activities of Na+-K+ -ATPase, respiratory metabolism related enzymes and liver tissue antioxidant related enzymes were measured at 12 and 24 h after salinity stress. The osmotic pressure and inorganic ion concentration of hemolymph of two strains P. fucata increased significantly with the increase of salinity. The activity of Na+-K+ -ATPase of red P. fucata only decreased under low salinity at 24 h, and was significantly higher than that the control under low salinity at 12 h and high salinity at 12 and 24 h. The succinate dehydrogenase (SDH) activities of the P. fucata treatment groups were significantly higher than those the control at 12 h. The lactate dehydrogenase (LDH) activity increased significantly with salinity at 12 h. and the black P. fucata LDH activity was significantly higher than the control at 24 h, while the LDH activity of red P. fucata was significantly lower than that the control in 50‰ salinity. The superoxide dismutase (SOD) activity of black P. fucata was significantly lower than that the control, while that of red P. fucata was significantly higher than that the control within 24. At 12 h, the catalase (CAT) activity of red P. fucata increased significantly with salinity, but decreased significantly with salinity at 24 h. The CAT activity of black P. fucata was highest at 24 h under low salinity. Glutathione peroxidase (GSH-Px) and alkaline phosphatase (AKP) activities of red P. fucata were significantly higher than those the control under low or high salinity. At high salinity for 24 h, the GSH-Px activity was lowest in black P. fucata, AKP activity was highest. The present study indicates that the physical responses of P. fucata to the salinity stress vary with shell colors. The red P. fucata can quickly respond positively to the change of environmental salinity and reduce the damage caused by the change of environmental salinity.

Fossil diatoms from the Volga Delta Holocene sediments (Damchik region) as indicators of the paleoecological conditions of sedimentation

2019 ◽  
pp. 270-273
Author(s):  
Yelena I. Shtyrkova ◽  
Yelena I. Polyakova
Keyword(s):  
Nature Reserve ◽  
Diatom Analysis ◽  
Volga Delta ◽  
The Core ◽  
Core Samples ◽  
Holocene Sediments ◽  
Fossil Diatoms

The results of fossil diatoms investigation from the deltaic sediments are presented. Samples were obtained from the core DM-1 and two Holocene outcrops from the Damchik region of the Astrakhan Nature Reserve. In the core samples eight periods of sedimentation based on diatom analysis were identified: the sediments formed in shallow freshwater basins and deltaic channels. The samples from the outcrops were investigated in much greater detail.

Computer Simulation of the Response of Amperometric Biosensors in Stirred and non Stirred Solution

2003 ◽  
Vol 8 (1) ◽  
pp. 3-18 ◽  
Author(s):  
R. Baronas ◽  
F. Ivanauskas ◽  
J. Kulys
Keyword(s):  
Mathematical Model ◽  
Computer Simulation ◽  
Finite Difference ◽  
Mass Transport ◽  
Enzyme Reaction ◽  
Analyte Concentration ◽  
Amperometric Biosensors ◽  
Finite Difference Technique ◽  
Enzyme Layer ◽  
Biosensor Response

A mathematical model of amperometric biosensors has been developed to simulate the biosensor response in stirred as well as non stirred solution. The model involves three regions: the enzyme layer where enzyme reaction as well as mass transport by diffusion takes place, a diffusion limiting region where only the diffusion takes place, and a convective region, where the analyte concentration is maintained constant. Using computer simulation the influence of the thickness of the enzyme layer as well the diffusion one on the biosensor response was investigated. The computer simulation was carried out using the finite difference technique.

Carbon-Isotope, Diatom, and Pollen Evidence for Late Holocene Salinity Change in a Brackish Marsh in the San Francisco Estuary

2001 ◽  
Vol 55 (1) ◽  
pp. 66-76 ◽  
Author(s):  
Roger Byrne ◽  
B. Lynn Ingram ◽  
Scott Starratt ◽  
Frances Malamud-Roam ◽  
Joshua N. Collins ◽  
...  
Keyword(s):  
San Francisco ◽  
High Salinity ◽  
Carbon Isotopic Composition ◽  
Brackish Marsh ◽  
San Francisco Estuary ◽  
Freshwater Inflow ◽  
Water Diversion ◽  
Freshwater Flow ◽  
Low Salinity ◽  
Carbon Isotopic

AbstractAnalysis of diatoms, pollen, and the carbon-isotopic composition of a sediment core from a brackish marsh in the northern part of the San Francisco Estuary has provided a paleosalinity record that covers the past 3000 yr. Changes in marsh composition and diatom frequencies are assumed to represent variations in freshwater inflow to the estuary. Three periods of relatively high salinity (low freshwater inflow) are indicated, 3000 to 2500 cal yr B.P., 1700 to 730 cal yr B.P., and ca. A.D. 1930 to the present. The most recent period of high salinity is primarily due to upstream storage and water diversion within the Sacramento–San Joaquin watershed, although drought may also have been a factor. The two earlier high-salinity periods are likely the result of reduced precipitation. Low salinity (high freshwater flow) is indicated for the period 750 cal yr B.P. to A.D. 1930.

Seasonal Variation in the Physiological Response of Atlantic Cod (Gadus morhua) to Low Salinity

1992 ◽  
Vol 49 (6) ◽  
pp. 1149-1156 ◽  
Author(s):  
J.-D. Dutil ◽  
J. Munro ◽  
C. Audet ◽  
M. Besner
Keyword(s):  
Skeletal Muscle ◽  
Seasonal Variation ◽  
Osmotic Pressure ◽  
Principal Components ◽  
Physiological Response ◽  
Gadus Morhua ◽  
Atlantic Cod ◽  
Low Salinity ◽  
Natural Photoperiod ◽  
Highly Correlated

Plasma Na+, Cl−, K+, osmotic pressure, Cortisol, glucose, and protein, blood hemoglobin and hematocrit, and water content of skeletal muscle were measured at regular intervals during a 28-d period following the transfer of Atlantic cod (Gadus morhua) to waters of 7, 14, 21, and 28‰ (control) salinity. These experiments were repeated four times at 3-mo intervals under natural photoperiod and temperatures (0–10 °C). Exposure to 7‰ salinity caused large decreases in plasma Na+ in winter (25 mmol/L over 14 d) and in spring (32 mmol/L over 7 d) when the lowest value for the year was reached (156 mmol/L). Transfer to 14 and 21‰ salinity resulted in a slight decrease (maximum 4%) in plasma Na+ which was much smaller than the seasonal variation (14%) observed in controls. Hydration of skeletal muscle occurred only at 7‰ (2.3% maximum), but these changes were small compared with the seasonal variation (3.9%) observed in the controls. Principal components and clustering analyses showed that all ionic and osmotic variables measured were highly correlated while being only weakly associated with the condition or reproductive status of the fish. There were no indications that acclimation to low salinity was stressful for cod.

Enhanced and Rock Typing-Based Reservoir Characterization of the Palaeocene Harash Carbonate Reservoir-Zelten Field-Sirte Basin-Libya

2021 ◽  
Author(s):  
Mohamed Masoud ◽  
W. Scott Meddaugh ◽  
Masoud Eljaroshi ◽  
Khaled Elghanduri
Keyword(s):  
Rock Type ◽  
Carbonate Reservoir ◽  
Classification Model ◽  
Reservoir Rocks ◽  
The Core ◽  
Core Samples ◽  
Rock Types ◽  
Rock Typing ◽  
Open Hole ◽  
Type Classification

Abstract The Harash Formation was previously known as the Ruaga A and is considered to be one of the most productive reservoirs in the Zelten field in terms of reservoir quality, areal extent, and hydrocarbon quantity. To date, nearly 70 wells were drilled targeting the Harash reservoir. A few wells initially naturally produced but most had to be stimulated which reflected the field drilling and development plan. The Harash reservoir rock typing identification was essential in understanding the reservoir geology implementation of reservoir development drilling program, the construction of representative reservoir models, hydrocarbons volumetric calculations, and historical pressure-production matching in the flow modelling processes. The objectives of this study are to predict the permeability at un-cored wells and unsampled locations, to classify the reservoir rocks into main rock typing, and to build robust reservoir properties models in which static petrophysical properties and fluid properties are assigned for identified rock type and assessed the existed vertical and lateral heterogeneity within the Palaeocene Harash carbonate reservoir. Initially, an objective-based workflow was developed by generating a training dataset from open hole logs and core samples which were conventionally and specially analyzed of six wells. The developed dataset was used to predict permeability at cored wells through a K-mod model that applies Neural Network Analysis (NNA) and Declustring (DC) algorithms to generate representative permeability and electro-facies. Equal statistical weights were given to log responses without analytical supervision taking into account the significant log response variations. The core data was grouped on petrophysical basis to compute pore throat size aiming at deriving and enlarging the interpretation process from the core to log domain using Indexation and Probabilities of Self-Organized Maps (IPSOM) classification model to develop a reliable representation of rock type classification at the well scale. Permeability and rock typing derived from the open-hole logs and core samples analysis are the main K-mod and IPSOM classification model outputs. The results were propagated to more than 70 un-cored wells. Rock typing techniques were also conducted to classify the Harash reservoir rocks in a consistent manner. Depositional rock typing using a stratigraphic modified Lorenz plot and electro-facies suggest three different rock types that are probably linked to three flow zones. The defined rock types are dominated by specifc reservoir parameters. Electro-facies enables subdivision of the formation into petrophysical groups in which properties were assigned to and were characterized by dynamic behavior and the rock-fluid interaction. Capillary pressure and relative permeability data proved the complexity in rock capillarity. Subsequently, Swc is really rock typing dependent. The use of a consistent representative petrophysical rock type classification led to a significant improvement of geological and flow models.

Spatial and seasonal variability of emergent aquatic insects and nearshore spiders in a subtropical estuary

2019 ◽  
Vol 70 (4) ◽  
pp. 541 ◽  
Author(s):  
Martha J. Zapata ◽  
S. Mažeika P. Sullivan
Keyword(s):  
Aquatic Insects ◽  
High Salinity ◽  
Aquatic Insect ◽  
Freshwater Ecosystems ◽  
Dispersal Ability ◽  
Insect Community ◽  
Insect Communities ◽  
Low Salinity ◽  
Subtropical Estuary ◽  
Adult Aquatic Insects

Variability in the density and distribution of adult aquatic insects is an important factor mediating aquatic-to-terrestrial nutritional subsidies in freshwater ecosystems, yet less is understood about insect-facilitated subsidy dynamics in estuaries. We surveyed emergent (i.e. adult) aquatic insects and nearshore orb-weaving spiders of the families Tetragnathidae and Araneidae in a subtropical estuary of Florida (USA). Emergent insect community composition varied seasonally and spatially; densities were lower at high- than low-salinity sites. At high-salinity sites, emergent insects exhibited lower dispersal ability and a higher prevalence of univoltinism than low- and mid-salinity assemblages. Orb-weaving spider density most strongly tracked emergent insect density rates at low- and mid-salinity sites. Tetragnatha body condition was 96% higher at high-salinity sites than at low-salinity sites. Our findings contribute to our understanding of aquatic insect communities in estuarine ecosystems and indicate that aquatic insects may provide important nutritional subsidies to riparian consumers despite their depressed abundance and diversity compared with freshwater ecosystems.

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