Simulation of Residual Oil Saturation in Near-Miscible Gasflooding Through Saturation-Dependent Tuning of the Equilibrium Constants

2015 ◽  
Vol 18 (03) ◽  
pp. 28-302 ◽  
Author(s):  
Leonardo Patacchini ◽  
Sébastien Duchenne ◽  
Marcel Bourgeois ◽  
Arthur Moncorgé ◽  
Quentin Pallotta

Summary Conventional miscible or near-miscible gasflooding simulation often overestimates oil recovery, mostly because it does not capture a series of physical effects tending to limit interphase compositional exchanges. Those can include microscopic bypassing of oil situated in dead-end pores or blocked by water films, as well as macroscopic bypassing caused by subgrid-size heterogeneities or fingering. We here present a new engineering solution to this problem in the near-miscible case, relying on our in-house research reservoir simulator. The principle is, while using a black-oil or an equation-of-state description, to dynamically decrease the K-value of heavy components and possibly increase the K-value of light components as the oil saturation reaches the desired residual limit; this enables changing the phase boundaries when needed while preserving the original fluid behavior during the initial production stages. The benefits of the proposed solution are demonstrated on a reservoir-conditions tertiary-gas-injection experiment, performed in our laboratories, for which residual saturations as well as oil-phase and individual-component production rates have easily and successfully been history matched. Results are then compared with matches obtained by use of saturation exclusion and α-factors methods. As a proof of concept, the suitability of the new method to simulate incomplete revaporization of condensate during gas cycling is also illustrated, on the third SPE comparative-solution-project case.

1979 ◽  
Vol 19 (04) ◽  
pp. 253-262 ◽  
Author(s):  
J.L. Yanosik ◽  
T.A. McCracken

Abstract Reservoir simulators based on five-point difference techniques do not predict the correct recovery performance for unfavorable mobility-ratio, piston-type performance for unfavorable mobility-ratio, piston-type displacements. For a developed five-spot pattern, the predicted performance depends on the grid orientation predicted performance depends on the grid orientation (parallel or diagonal) used. This paper discusses the development and testing of a nine-point, finite-difference reservoir simulator. Developed five-spot-pattern flood predictions are presented for piston-type displacements predictions are presented for piston-type displacements with mobility ratios ranging from 0.5 to 50-0. We show that the predicted fronts are realistic and that very little or no difference exists between the results of parallel and diagonal grids. The maximum difference in the recovery curves is less than 1.5 %. The nine-point-difference method is extended to any grid network composed of rectangular elements. Results for two example problems - a linear flood and a direct line-drive flood - indicate the extension is correct. The techniques discussed here can be applied directly in the development of any reservoir simulator. We anticipate that the greatest utility will be in the development of simulators for the improved oil-recovery processes that involve unfavorable mobility ratio processes that involve unfavorable mobility ratio displacements. Examples are miscible flooding, micellar/ polymer flooding (water displacing polymer), and direct polymer flooding (water displacing polymer), and direct steam drive. Introduction Miscible displacement oil-recovery methods often are characterizedby a large viscosity ratio between the oil and its miscible fluid andby a very low immobile oil saturation behind the displacement front. These conditions represent an unfavorable mobility-ratio, piston-type displacement. They differ from a conventional piston-type displacement. They differ from a conventional gas drive, where a substantial mobile oil saturation remains behind the displacement front. Reservoir simulators based on five-point, finitedifference techniques do not predict the correct performance for unfavorable mobility-ratio, piston-type performance for unfavorable mobility-ratio, piston-type displacements. Results of an areal simulation for a developed five-spot flood depend on the grid orientation (diagonal or parallel, Fig. 1). Grid orientation significantly influences the predicted recovery performance and displacement front positions. performance and displacement front positions. A nine-point, finite-difference reservoir simulator is described. Predictions of piston-type displacements in a developed five-spot pattern are presented for mobility ratios ranging from 0.5 to 50. We show that the predicted fronts are realistic and that very little or no predicted fronts are realistic and that very little or no difference exists between the results of parallel and diagonal grid orientations. A formulation of the nine-point, finite-difference technique applicable to any rectangular grid network is presented. Results for two example two-dimensional presented. Results for two example two-dimensional problems, a linear flood, and a direct line-drive flood problems, a linear flood, and a direct line-drive flood indicate that the formulation is correct for nonsquare grid networks. Background Grid-orientation effects for five-point reservoir simulators were demonstrated by Todd et al. They studied two developed five-spot grid systems - a diagonal grid and a parallel grid. These grid systems are shown in Fig. 1. parallel grid. These grid systems are shown in Fig. 1. The diagonal grid represents a quarter of a five-spot pattern, with grid lines at 45 degrees to a line connecting the pattern, with grid lines at 45 degrees to a line connecting the injector and producer. The parallel grid represents one-half of a five-spot pattern, with grid lines either parallel or perpendicular to the lines connecting the parallel or perpendicular to the lines connecting the injector-producer pads. SPEJ P. 253


2009 ◽  
Vol 12 (03) ◽  
pp. 419-426 ◽  
Author(s):  
Ingebret Fjelde ◽  
John Zuta ◽  
Ingrid Hauge

Summary Injection of carbon dioxide (CO2) is a well-known enhanced-oil-recovery (EOR) technique. Formation of stable foam inside the reservoir can improve macroscopic sweep efficiency. On the other hand, retention of surfactants decreases the cost-efficiency of the EOR process. This paper presents flow-through retention experiments with CO2-foaming agents on outcrop Liege chalk plugs at two different temperatures: 55 and 70°C. Two branched ethoxylated (EO) sulfonates with different ethoxylation degree, S1 (EO=7) and S2 (EO=12), were used. The aim was to investigate the effect of ethoxylation degree on surfactant retention. Furthermore, the effects of temperature and residual oil on surfactant retention were studied. The effect of waterflooding followed by CO2 flooding on surfactant retention at reservoir conditions was also examined. Partitioning of the foaming agents between water and oil phases was studied. Results show that increasing the ethoxylation degree of the surfactant decreases the retention on chalk cores saturated with formation water at 55°C. S2, which was found to give the lowest retention at 55°C, was found to have a higher retention at 70°C. The presence of residual-oil saturation after waterflooding (Sorw) decreased the retention of S1 and increased the retention of S2 in comparison to the absence of residual oil. The retention of S2 after waterflooding followed by CO2 flooding at 340 bar and 55°C was in the same range as retention on 100%-water-saturated core, but significantly lower than retention in residual-oil-saturated cores. The experiments have shown that not only are surfactant structure and temperature important for the retention of surfactants, but also the presence of oil.


Energies ◽  
2021 ◽  
Vol 14 (7) ◽  
pp. 1979
Author(s):  
Omar Chaabi ◽  
Mohammed Al Kobaisi ◽  
Mohamed Haroun

Low salinity waterflooding (LSW) has shown promising results in terms of increasing oil recovery at laboratory scale. In this work, we study the LSW effect, at laboratory scale, and provide a basis for quantifying the effect at field scale by extracting reliable relative permeability curves. These were achieved by experimental and numerical interpretation of laboratory core studies. Carbonate rock samples were used to conduct secondary and tertiary unsteady-state coreflooding experiments at reservoir conditions. A mathematical model was developed as a research tool to interpret and further validate the physical plausibility of the coreflooding experiments. At core scale and a typical field rate of ~1 ft/day, low salinity water (LS) resulted in not only ~20% higher oil recovery compared to formation water (FW) but also recovered oil sooner. LS water also showed capability of reducing the residual oil saturation when flooded in tertiary mode. The greater oil recovery caused by LSW can be attributed to altering the wettability of the rock to less oil-wet as confirmed by the numerically extracted relative permeability curves.


2019 ◽  
Vol 6 (6) ◽  
pp. 181902 ◽  
Author(s):  
Junchen Lv ◽  
Yuan Chi ◽  
Changzhong Zhao ◽  
Yi Zhang ◽  
Hailin Mu

Reliable measurement of the CO 2 diffusion coefficient in consolidated oil-saturated porous media is critical for the design and performance of CO 2 -enhanced oil recovery (EOR) and carbon capture and storage (CCS) projects. A thorough experimental investigation of the supercritical CO 2 diffusion in n -decane-saturated Berea cores with permeabilities of 50 and 100 mD was conducted in this study at elevated pressure (10–25 MPa) and temperature (333.15–373.15 K), which simulated actual reservoir conditions. The supercritical CO 2 diffusion coefficients in the Berea cores were calculated by a model appropriate for diffusion in porous media based on Fick's Law. The results show that the supercritical CO 2 diffusion coefficient increases as the pressure, temperature and permeability increase. The supercritical CO 2 diffusion coefficient first increases slowly at 10 MPa and then grows significantly with increasing pressure. The impact of the pressure decreases at elevated temperature. The effect of permeability remains steady despite the temperature change during the experiments. The effect of gas state and porous media on the supercritical CO 2 diffusion coefficient was further discussed by comparing the results of this study with previous study. Based on the experimental results, an empirical correlation for supercritical CO 2 diffusion coefficient in n -decane-saturated porous media was developed. The experimental results contribute to the study of supercritical CO 2 diffusion in compact porous media.


2020 ◽  
Vol 17 (6) ◽  
pp. 1065-1074
Author(s):  
Abdullah Musa Ali ◽  
Amir Rostami ◽  
Noorhana Yahya

Abstract The need to recover high viscosity heavy oil from the residual phase of reservoirs has raised interest in the use of electromagnetics (EM) for enhanced oil recovery. However, the transformation of EM wave properties must be taken into consideration with respect to the dynamic interaction between fluid and solid phases. Consequently, this study discretises EM wave interaction with heterogeneous porous media (sandstones) under different fluid saturations (oil and water) to aid the monitoring of fluid mobility and activation of magnetic nanofluid in the reservoir. To achieve this aim, this study defined the various EM responses and signatures for brine and oil saturation and fluid saturation levels. A Nanofluid Electromagnetic Injection System (NES) was deployed for a fluid injection/core-flooding experiment. Inductance, resistance and capacitance (LRC) were recorded as the different fluids were injected into a 1.0-m long Berea core, starting from brine imbibition to oil saturation, brine flooding and eventually magnetite nanofluid flooding. The fluid mobility was monitored using a fibre Bragg grating sensor. The experimental measurements of the relative permittivity of the Berea sandstone core (with embedded detectors) saturated with brine, oil and magnetite nanofluid were given in the frequency band of 200 kHz. The behaviour of relative permittivity and attenuation of the EM wave was observed to be convolutedly dependent on the sandstone saturation history. The fibre Bragg Grating (FBG) sensor was able to detect the interaction of the Fe3O4 nanofluid with the magnetic field, which underpins the fluid mobility fundamentals that resulted in an anomalous response.


2021 ◽  
Author(s):  
Baghir Alakbar Suleimanov ◽  
Sabina Jahangir Rzayeva ◽  
Ulviyya Tahir Akhmedova

Abstract Microbial enhanced oil recovery is considered to be one of the most promising methods of stimulating formation, contributing to a higher level of oil production from long-term fields. The injection of bioreagents into a reservoir results in the creation of oil-dicing agents along with significant amount of gases, mainly carbon dioxide. In early, the authors failed to study the preparation of self-gasified biosystems and the implementation of the subcritical region (SR) under reservoir conditions. Gasified systems in the subcritical phase have better oil-displacing properties than non-gasified systems. The slippage effect determines the behavior of gas–liquid systems in the SR under reservoir conditions. Slippage occurs more easily when the pore channel has a smaller average radius. Therefore, in a heterogeneous porous medium, the filtration profile of gasified liquids in the SR should be more uniform than for a degassed liquid. The theoretical and practical foundations for the preparation of single-phase self-gasified biosystems and the implementation of the SR under reservoir conditions have been developedSR under reservoir conditions. Based on experimental studies, the superior efficiency of oil displacement by gasified biosystems compared with degassed ones has been demonstrated. The possibility of efficient use of gasified hybrid biopolymer systems has been shown.


2021 ◽  
Author(s):  
Prakash Purswani ◽  
Russell T. Johns ◽  
Zuleima T. Karpyn

Abstract The relationship between residual saturation and wettability is critical for modeling enhanced oil recovery (EOR) processes. The wetting state of a core is often quantified through Amott indices, which are estimated from the ratio of the saturation fraction that flows spontaneously to the total saturation change that occurs due to spontaneous flow and forced injection. Coreflooding experiments have shown that residual oil saturation trends against wettability indices typically show a minimum around mixed-wet conditions. Amott indices, however, provides an average measure of wettability (contact angle), which are intrinsically dependent on a variety of factors such as the initial oil saturation, aging conditions, etc. Thus, the use of Amott indices could potentially cloud the observed trends of residual saturation with wettability. Using pore network modeling (PNM), we show that residual oil saturation varies monotonically with the contact angle, which is a direct measure of wettability. That is, for fixed initial oil saturation, the residual oil saturation decreases monotonically as the reservoir becomes more water-wet (decreasing contact angle). Further, calculation of Amott indices for the PNM data sets show that a plot of the residual oil saturation versus Amott indices also shows this monotonic trend, but only if the initial oil saturation is kept fixed. Thus, for the cases presented here, we show that there is no minimum residual saturation at mixed-wet conditions as wettability changes. This can have important implications for low salinity waterflooding or other EOR processes where wettability is altered.


2011 ◽  
Vol 12 (1) ◽  
pp. 31-38 ◽  
Author(s):  
Muhammad Taufiq Fathaddin ◽  
Asri Nugrahanti ◽  
Putri Nurizatulshira Buang ◽  
Khaled Abdalla Elraies

In this paper, simulation study was conducted to investigate the effect of spatial heterogeneity of multiple porosity fields on oil recovery, residual oil and microemulsion saturation. The generated porosity fields were applied into UTCHEM for simulating surfactant-polymer flooding in heterogeneous two-layered porous media. From the analysis, surfactant-polymer flooding was more sensitive than water flooding to the spatial distribution of multiple porosity fields. Residual oil saturation in upper and lower layers after water and polymer flooding was about the same with the reservoir heterogeneity. On the other hand, residual oil saturation in the two layers after surfactant-polymer flooding became more unequal as surfactant concentration increased. Surfactant-polymer flooding had higher oil recovery than water and polymer flooding within the range studied. The variation of oil recovery due to the reservoir heterogeneity was under 9.2%.


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