Scale Inhibitor Consumption in Long-Term Static Barium Sulphate Inhibition Efficiency Tests

Author(s):  
Scott Stewart Shaw ◽  
Kenneth Stuart Sorbie
RSC Advances ◽  
2016 ◽  
Vol 6 (95) ◽  
pp. 92943-92952 ◽  
Author(s):  
Henghui Huang ◽  
Qi Yao ◽  
Hualin Chen ◽  
Bailing Liu

In order to improve the scale inhibition efficiency of existing scale inhibitors for industrial water and to reduce the phosphorus pollution of water bodies, a new type of scale inhibitor with a hyper-branched structure has been developed.


2014 ◽  
Author(s):  
D.. Patterson ◽  
W.. Williams ◽  
M.. Jordan ◽  
R.. Douglas

Abstract The injection of seawater into oil-bearing reservoirs in order to maintain reservoir pressure and improve secondary recovery is a well-established, mature operation. Moreover, the degree of risk posed by deposition of mineral scales (carbonate/sulphate) to the injection and production wells during such operations has been much studied. The current deep-water subsea developments offshore West Africa and Brazil have brought into sharp focus the need to manage scale in an effective way. In a deepwater West African field the relatively small number of high-cost, highly productive wells, coupled with a high barium sulphate scaling tendency upon breakthrough of injection seawater meant not only was effective scale management critical to achieve high hydrocarbon recovery, but even wells at low water cuts have proven to be at sufficient risk to require early squeeze application. To provide effective scale control in these wells at low water cuts, phosphonate-based inhibitors were applied as part of the acid perforation wash and overflush stages prior to frac packing operations. The deployment of this inhibitor proved effective in controlling barium sulphate scale formation during initial water production eliminating the need to scale squeeze the wells at low water cuts (<10% BS&W). To increase the volumes of scale inhibitor being deployed in the pre-production treatments and so extend the treatment lifetimes scale inhibitor was also added to the frac gel used to carry the frac sand. This paper outlines the selection methods for the inhibitor chemical for application in frac fluids in terms of rheology, retention/release, formation damage and presents the chemical returns profile from the 5 wells treated (some treatments lasting > 300 days) along with monitoring methods utilized to confirm scale control in the wells treated. Many similar fields are currently being developed in the Campos basin, Gulf of Mexico, and West Africa, and this paper is a good example of best-practice sharing from another oil basin.


2015 ◽  
Vol 814 ◽  
pp. 278-285
Author(s):  
Ming Zhu ◽  
Cheng Qiang Ren ◽  
Yuan Yuan Meng ◽  
Li Liu ◽  
Yun Ping Zheng

The deposition of BaSO4scale is always found in the oilfield. It is difficult to be removed. Therefore, it plays a negative role to the production. The effects of temperature and water chemistry on BaSO4scale have been investigated by using the conductivity method in this work. An environment-friendly copolymer was prepared to control the scaling of BaSO4. The copolymer was proved by static scale inhibition method, and weight-loss test that it has excellent scale inhibition performance and corrosion inhibition efficiency. Furthermore, FTIR spectra was used to prove that the scale inhibitor was polyepoxysuccinic acid (PESA).


2014 ◽  
Vol 968 ◽  
pp. 206-210
Author(s):  
Tao Ping Chen ◽  
Xian Xi Su

The experiment study effect of injection different kinds of water on extra low permeability reservoir of Yushulin Oilfield. In the condition of actual temperature and pressure of the reservoir, through the experimental study the effect of injection different kinds of water on extra low permeability core. Experiments include injecting clean water, injecting clean water with scale inhibitor, injecting traditional treated sewage, injecting deep treated sewage, injecting deep treated sewage with scale inhibitor. The experimental results show that: Long term injecting clean water and clean water with scale inhibitor are harmless to core; Injecting traditional treated sewage, high content of oil and impurity bring injection pressure go up, the permeability of core down sharply; Injecting deep treated (aeration + flotation (PAC+PAM) + filtration + ultra filtration (FeCl3)) sewage must be added scale inhibitor, otherwise injection pressure continuously increase, permeability of the core continuously decrease, which seriously affect injection water.


Author(s):  
Xiaoxian Gu ◽  
Fengxian Qiu ◽  
Xin Zhou ◽  
Jing Qi ◽  
Yang Zhou ◽  
...  

2019 ◽  
Author(s):  
Erin Temple ◽  
Myles Jordan ◽  
Helen Williams ◽  
Sigrid Kjelstrup ◽  
Marija Kilibarda ◽  
...  

2019 ◽  
Vol 19 (5) ◽  
pp. 1463-1472 ◽  
Author(s):  
Wenlin Zhang ◽  
Gongwei Li ◽  
Fei Jin ◽  
Yu Huo ◽  
Tengfei Sun ◽  
...  

Abstract A phosphorus-free scale inhibitor (ionic liquid–carboxylic acid copolymer) was successfully synthesized by the reaction of 1-sulfobutyl-3-vinylimidazolium hydrogen sulfate (SVIS) and acrylic acid (AA). The structure of the product was characterized by Fourier transform infrared spectroscopy (FTIR), hydrogen nuclear magnetic resonance (1H NMR) and carbon-13 nuclear magnetic resonance (13C NMR). Then the scale inhibition efficiency of 1-sulfobutyl-3-vinylimidazolium hydrogen sulfate-acrylic acid (SVIS-AA) copolymer against CaCO3 and CaSO4 was determined. The results indicated that SVIS-AA copolymer showed better scale inhibition efficiency than poly (acrylic acid) (PAA). After that, the effects of temperature and Ca2+ concentration on the scale inhibition efficiency against CaCO3 were studied. Results showed that when the temperature reached 90 °C, the scale inhibition efficiency could still remain 91% at a concentration of 18 mg L−1. When the concentration of Ca2+ reached 1,200 mg L−1, the scale inhibition efficiency could remain 70% at a concentration of 20 mg L−1. At last, the effect of SVIS-AA copolymer on the morphologies of CaCO3 and CaSO4 scale was studied by scanning electron microscopy (SEM) and X-ray diffraction (XRD).


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