Rapid Prediction of Carbon Dioxide and Nitrogen Adsorption Behavior at Cryogenic Temperatures

2010 ◽  
Author(s):  
Alireza Bahadori ◽  
Hari Vuthaluru
Keyword(s):  
Carbon Dioxide ◽  
Nitrogen Adsorption ◽  
Adsorption Behavior ◽  
Cryogenic Temperatures ◽  
Rapid Prediction

Adsorption Behavior of Toluene on Activated Carbon under Supercritical Carbon Dioxide Conditions

2012 ◽  
Vol 45 (12) ◽  
pp. 931-938 ◽  
Author(s):  
Ikuo Ushiki ◽  
Takashi Asaka ◽  
Yusuke Yoshizawa ◽  
Kazunori Kashiwagi ◽  
Masaki Ota ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Activated Carbon ◽  
Supercritical Carbon Dioxide ◽  
Adsorption Behavior ◽  
Supercritical Carbon

scholarly journals Improved carbon dioxide storage over clay-supported perhydroxylated glucodendrimer

2017 ◽  
Vol 95 (9) ◽  
pp. 999-1007 ◽  
Author(s):  
Saadia Nousir ◽  
Gerlainde Yemelong ◽  
Sameh Bouguedoura ◽  
Yoann M. Chabre ◽  
Tze Chieh Shiao ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Low Cost ◽  
Nitrogen Adsorption ◽  
Interlayer Spacing ◽  
Physical Interaction ◽  
Thermal Regeneration ◽  
Retention Capacity ◽  
Oh Groups ◽  
Carrier Gas ◽  
Surface Basicity

Low-cost biosourced hybrid microporous adsorbents with improved affinity towards carbon dioxyde (CO2) were prepared through the incorporation of various amounts of glucosylated dendrimer into bentonite- and montmorillonite-rich composite materials. Characterization by nitrogen adsorption–desorption isotherms, surface specific and pore size analyses (BET and BJH), thermogravimetric analysis (TGA), Fourier transform infrared spectroscopy (FTIR), and X-ray diffraction (XRD) revealed changes in the interlayer spacing and textural structure of the materials. Thermal programmed desorption measurements (TPD) showed significant improvements of the retention capacity of CO2 (CRC) and water (WRC). This was explained in terms of enhancement of both surface basicity and hydrophilic character due to the incorporation of terminal polyhydroxyl groups. The CRC was found to vary according to the previous saturation time with CO2 and the carrier gas throughput. CO2 was totally released upon temperature not exceeding 80 °C or even at room temperature upon strong carrier gas stream, thus providing evidence that CO2 capture involves almost exclusively physical interaction with the OH groups of the dendrimer. This result opens promising prospects for the reversible capture of carbon dioxide with easy release without thermal regeneration, more particularly when extending this concept to biosourced dendrimers.

Adsorption Behavior of Carbon Dioxide and Methane on AlPO4-14: A Neutral Molecular Sieve

2009 ◽  
Vol 23 (3) ◽  
pp. 1534-1538 ◽  
Author(s):  
Xing-Xiang Zhao ◽  
Xiao-Liang Xu ◽  
Lin-Bing Sun ◽  
Li−Li Zhang ◽  
Xiao-Qin Liu
Keyword(s):  
Carbon Dioxide ◽  
Molecular Sieve ◽  
Adsorption Behavior

scholarly journals Synthesis and use of carvedilol metal complexes as carbon dioxide storage media

2020 ◽  
Vol 10 (3) ◽  
pp. 157-164
Author(s):  
Omar G. Mousa ◽  
Emad Yousif ◽  
Ahmed A. Ahmed ◽  
Gamal A. El‐Hiti ◽  
Mohammad Hayal Alotaibi ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Metal Complexes ◽  
Copper Complexes ◽  
Textural Properties ◽  
Nitrogen Adsorption ◽  
Carbon Dioxide Storage ◽  
Small Surface ◽  
Carbon Dioxide Uptake ◽  
Storage Media ◽  
Adsorption Desorption

Abstract The consequences of increased fossil fuel consumption on the environment presents a challenge. Carbon dioxide capture is a useful technique to reduce global warming. Therefore, three carvedilol metal (nickel, cobalt, and copper) complexes were synthesized as potential carbon dioxide storage media. The structural and textural properties of metal carvedilol complexes have been established using various techniques. The metal complexes have mesoporous structures in which pore size was approximately 3 nm. Particle size ranged from 51.0 to 393.9 nm with a relatively small surface area (6.126–9.073 m2/g). The carvedilol metal complexes have either type-III or IV nitrogen adsorption–desorption isotherm. The complexes showed reasonable capacity towards carbon dioxide uptake (up to 18.21 cm3/g) under the optimized condition (40 bar and 323 K). Graphical Abstract

Rattle-Type Diamine-Functionalized Mesoporous Silica Sphere for Carbon Dioxide Adsorption

2018 ◽  
Vol 53 ◽  
pp. 13-21 ◽  
Author(s):  
Ning Yuan ◽  
Zhi Wei Liu ◽  
Li Yan Wang ◽  
Bao Hang Han
Keyword(s):  
Carbon Dioxide ◽  
Mesoporous Silica ◽  
Nitrogen Adsorption ◽  
Magic Angle Spinning ◽  
Silica Sphere ◽  
Magic Angle ◽  
Templating Method ◽  
Functionalized Mesoporous Silica ◽  
Angle Spinning ◽  
Mesoporous Silica Sphere

A rattle-type diamine-functionalized mesoporous silica sphere (DA-RMSS) was fabricated stepwise using a self-templating method through cationic surfactant assisted selective etching strategy. The rattle-type morphology of the obtained DA-RMSS material was disclosed by transmission electron microscopy, while its chemical composition was characterized by CHN elemental analysis, Fourier transform infrared spectroscopy, and solid-state 29Si cross-polarization/magic-angle-spinning nuclear magnetic resonance spectroscopic measurement, which corroborates the successful formation of siloxane network and the incorporation of organic component. Moreover, nitrogen adsorption–desorption isotherm measurement was conducted to reveal that DA-RMSS possesses large Brunauer–Emmett–Teller (BET) specific surface area of 814 m2g–1, pore volume of 0.78 cm3g–1, and narrow pore size distribution centered at 3.0 nm. Furthermore, its uptake property on carbon dioxide was also investigated in this contribution.

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